Chemistry College

2. A student prepared a 0.500 M solution of an unknown acid, and measured the pH as 3.56 at 25°C. (a) What is the acid dissociation constant of this unknown acid? (b) What percentage of acid is ionised in this solution​

Answers

Answer 1

To solve this problem, we can use the following equation that relates the pH of a solution to the acid dissociation constant (Ka) and the concentration of the acid:

pH = -log[H+]

where [H+] is the concentration of hydrogen ions in the solution.

(a) To find the Ka of the unknown acid, we need to first find the concentration of hydrogen ions in the solution. We can do this by taking the inverse of the pH and converting it to a concentration:

[H+] = 10^(-pH) = 10^(-3.56) = 2.17 × 10^(-4) M

What is the acid dissociation constant of this unknown acid?

The acid dissociation constant (Ka) can then be calculated using the equation:

Ka = [H+][A-]/[HA]

where [A-] is the concentration of the conjugate base of the acid and [HA] is the concentration of the undissociated acid. Since we don't know the values of these concentrations, we need to use the fact that the solution is 0.500 M to make an assumption about the degree of dissociation (α) of the acid:

α = [A-]/[HA]

Since the solution is not extremely dilute, we can assume that the degree of dissociation is small and that the concentration of the undissociated acid is approximately equal to the initial concentration of the acid. Therefore, we can write:

[A-] ≈ 0.500α

[HA] ≈ 0.500 - 0.500α

Substituting these expressions into the equation for Ka, we get:

Ka = [H+][A-]/[HA] ≈ ([H+][A-])/0.500α

≈ ([H+]/Ka)(0.500α)/(1-α)

Solving for Ka, we get:

Ka ≈ H+/0.500α

Substituting the values we have calculated, we get:

Ka ≈ (2.17 × 10^(-4))(1-α)/(0.500α) = 4.37 × 10^(-5)

Therefore, the acid dissociation constant of the unknown acid is approximately 4.37 × 10^(-5).

(b) To find the percentage of acid that is ionized in the solution, we can use the equation:

α = [A-]/[HA] = 10^(-pKa + pH)/(1 + 10^(-pKa + pH))

where pKa is the negative logarithm of the acid dissociation constant. Substituting the values we have calculated, we get:

α = 10^(-(-4.36) + 3.56)/(1 + 10^(-(-4.36) + 3.56)) ≈ 0.008

Therefore, the percentage of acid that is ionized in the solution is approximately 0.8%.

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Answer 2

To solve this problem, we can use the following equation that relates the pH of a solution to the acid dissociation constant (Ka) and the concentration of the acid:

pH = -log[H+]

where [H+] is the concentration of hydrogen ions in the solution.

(a) To find the Ka of the unknown acid, we need to first find the concentration of hydrogen ions in the solution. We can do this by taking the inverse of the pH and converting it to a concentration:

[H+] = 10^(-pH) = 10^(-3.56) = 2.17 × 10^(-4) M

What is the acid dissociation constant of this unknown acid?

The acid dissociation constant (Ka) can then be calculated using the equation:

Ka = [H+][A-]/[HA]

where [A-] is the concentration of the conjugate base of the acid and [HA] is the concentration of the undissociated acid. Since we don't know the values of these concentrations, we need to use the fact that the solution is 0.500 M to make an assumption about the degree of dissociation (α) of the acid:

α = [A-]/[HA]

Since the solution is not extremely dilute, we can assume that the degree of dissociation is small and that the concentration of the undissociated acid is approximately equal to the initial concentration of the acid. Therefore, we can write:

[A-] ≈ 0.500α

[HA] ≈ 0.500 - 0.500α

Substituting these expressions into the equation for Ka, we get:

Ka = [H+][A-]/[HA] ≈ ([H+][A-])/0.500α

≈ ([H+]/Ka)(0.500α)/(1-α)

Solving for Ka, we get:

Ka ≈ H+/0.500α

Substituting the values we have calculated, we get:

Ka ≈ (2.17 × 10^(-4))(1-α)/(0.500α) = 4.37 × 10^(-5)

Therefore, the acid dissociation constant of the unknown acid is approximately 4.37 × 10^(-5).

(b) To find the percentage of acid that is ionized in the solution, we can use the equation:

α = [A-]/[HA] = 10^(-pKa + pH)/(1 + 10^(-pKa + pH))

where pKa is the negative logarithm of the acid dissociation constant. Substituting the values we have calculated, we get:

α = 10^(-(-4.36) + 3.56)/(1 + 10^(-(-4.36) + 3.56)) ≈ 0.008

Therefore, the percentage of acid that is ionized in the solution is approximately 0.8%.

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Related Questions

The two possible units of molarity are

Answers

Answer: The units for molarity are moles/liter.

Similarly, the equation to find molarity is moles divided by liters.

Explanation:  

mol / L is a unit of molar concentration. These are the number of moles of dissolved material per liter of solution. 1 mol / L is also called 1M or 1molar. Mol / m3 is also a unit of molar concentration.

Molarity is expressed in units of moles per liter (mol / L). This is a very common unit, so it has its own symbol, which is the uppercase M. A solution with a concentration of 5 mmol / l is called a 5 M solution or has a concentration value of 5 mol.

The molar concentration of the solution is equal to the number of moles of the solute divided by the mass of the solvent (kilogram), and the molar concentration of the solution is equal to the number of moles of the solute divided by the volume of the solution (liter). increase.

CaCO3 + 2HCI =CaCl2 + H₂O + CO2
5. Calcium carbonate (CaCO3) combines with HCl to produce calcium chloride (CaCl₂),
water, and carbon dioxide gas (CO₂). How many grams of HCI are required to react with
6.35 mol CaCO3?

Answers

463.5 grams of HCl are required to react with 6.35 moles of CaCO₃.

What is meant by molar mass?

Mass of one mole of substance is referred to as the molar mass. The molar mass of a substance can be calculated by adding up the atomic masses of all the atoms in a molecule.

Balanced chemical equation for the reaction between calcium carbonate (CaCO₃) and hydrochloric acid (HCl) is: CaCO₃ + 2HCl → CaCl₂ + H₂O + CO₂

6.35 mol CaCO₃ * 2 mol HCl / 1 mol CaCO₃ = 12.7 mol HCl

Now, we use the molar mass of HCl (36.46 g/mol) to convert from moles to grams: 12.7 mol HCl * 36.46 g/mol = 463.5 g HCl

Therefore, 463.5 grams of HCl are required to react with 6.35 moles of CaCO₃.

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A flask filled to the 25.0 ml mark contain 29.97 g of a concentrated salt water solution. What is the density of the solution?
​

Answers

A concentrated saltwater solution weighing 29.97 g and fitting into a flask to the mark of 25.0 ml has a density of about 1199.2 g/L.

How is the density of the solution determined?

By dividing the solution's mass by its volume, we may get its density: density = mass/volume

We need to know the density of water at the solution's temperature as well as the capacity of the flask up to the 25.0 ml level in order to calculate the volume of the solution.

Since 1 mL = 0.001 L, volume is equal to 25.0 mL, or 0.0250 L.

Now, we may determine the solution's density as follows:

1199.2 g/L or 29.97 g/0.0250 L is what is referred to as density.

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The calcium and magnesium in a urine sample were precipitated as oxalates. A mixed precipitate of calcium oxalate (CaC2O4) and magnesium oxalate (MgC2O4) resulted and was analysed by gravimetry. The formed precipitate mixture was heated to form calcium carbonate (CaCO3) and magnesium oxide (MgO) with a total mass of 0.0433 g. The solid precipitate mixture was ignited to form CaO and MgO, the resulting solid after ignition weighed 0.0285 g. What was the mass of calcium in the original sample? All answers should be reported with the correct significant figures

Answers

The mass of calcium in the original urine sample would be 0.0140 g.

Stoichiometric problem

First, we need to find the masses of calcium and magnesium oxalates in the original sample. Let x be the mass of calcium oxalate and y be the mass of magnesium oxalate. Then we have:

x + y = mass of the mixed oxalate precipitate

Next, we need to use the information given to find the mass of calcium in the original sample. The mass of calcium oxide formed after ignition is equal to the mass of calcium oxalate in the original sample. We can calculate the mass of calcium oxide using the mass of calcium carbonate formed and the molar mass ratio of calcium carbonate to calcium oxide.

The balanced chemical equations for the reactions are:

CaC2O4 -> CaCO3 + CO2

CaCO3 -> CaO + CO2

The molar mass of CaCO3 is 100.09 g/mol, and the molar mass of CaO is 56.08 g/mol.

From the given information, we have:

0.0433 g = (x + y)(100.09 g/mol + 80.15 g/mol) / (128.10 g/mol + 80.15 g/mol)

0.0285 g = x(56.08 g/mol) + y(40.31 g/mol)

Solving these equations simultaneously, we get:

x = 0.0140 g

y = 0.0053 g

Therefore, the mass of calcium in the original sample (which is equal to the mass of calcium oxide formed after ignition) is:

0.0140 g

So the mass of calcium in the original sample is 0.0140 g.

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