4- Calculate the pH of 0.3 M NH, where is K = 1.7 x 10

To solve this problem, we can use the following equation that relates the pH of a solution to the acid dissociation constant (Ka) and the concentration of the acid:

pH = -log[H+]

where [H+] is the concentration of hydrogen ions in the solution.

(a) To find the Ka of the unknown acid, we need to first find the concentration of hydrogen ions in the solution. We can do this by taking the inverse of the pH and converting it to a concentration:

[H+] = 10^(-pH) = 10^(-3.56) = 2.17 × 10^(-4) M

The acid dissociation constant (Ka) can then be calculated using the equation:

Ka = [H+][A-]/[HA]

where [A-] is the concentration of the conjugate base of the acid and [HA] is the concentration of the undissociated acid. Since we don't know the values of these concentrations, we need to use the fact that the solution is 0.500 M to make an assumption about the degree of dissociation (α) of the acid:

α = [A-]/[HA]

Since the solution is not extremely dilute, we can assume that the degree of dissociation is small and that the concentration of the undissociated acid is approximately equal to the initial concentration of the acid. Therefore, we can write:

[A-] ≈ 0.500α

[HA] ≈ 0.500 - 0.500α

Substituting these expressions into the equation for Ka, we get:

Ka = [H+][A-]/[HA] ≈ ([H+][A-])/0.500α

≈ ([H+]/Ka)(0.500α)/(1-α)

Solving for Ka, we get:

Ka ≈ H+/0.500α

Substituting the values we have calculated, we get:

Ka ≈ (2.17 × 10^(-4))(1-α)/(0.500α) = 4.37 × 10^(-5)

Therefore, the acid dissociation constant of the unknown acid is approximately 4.37 × 10^(-5).

(b) To find the percentage of acid that is ionized in the solution, we can use the equation:

α = [A-]/[HA] = 10^(-pKa + pH)/(1 + 10^(-pKa + pH))

where pKa is the negative logarithm of the acid dissociation constant. Substituting the values we have calculated, we get:

α = 10^(-(-4.36) + 3.56)/(1 + 10^(-(-4.36) + 3.56)) ≈ 0.008

Therefore, the percentage of acid that is ionized in the solution is approximately 0.8%.

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To solve this problem, we can use the following equation that relates the pH of a solution to the acid dissociation constant (Ka) and the concentration of the acid:

pH = -log[H+]

where [H+] is the concentration of hydrogen ions in the solution.

(a) To find the Ka of the unknown acid, we need to first find the concentration of hydrogen ions in the solution. We can do this by taking the inverse of the pH and converting it to a concentration:

[H+] = 10^(-pH) = 10^(-3.56) = 2.17 × 10^(-4) M

The acid dissociation constant (Ka) can then be calculated using the equation:

Ka = [H+][A-]/[HA]

where [A-] is the concentration of the conjugate base of the acid and [HA] is the concentration of the undissociated acid. Since we don't know the values of these concentrations, we need to use the fact that the solution is 0.500 M to make an assumption about the degree of dissociation (α) of the acid:

α = [A-]/[HA]

Since the solution is not extremely dilute, we can assume that the degree of dissociation is small and that the concentration of the undissociated acid is approximately equal to the initial concentration of the acid. Therefore, we can write:

[A-] ≈ 0.500α

[HA] ≈ 0.500 - 0.500α

Substituting these expressions into the equation for Ka, we get:

Ka = [H+][A-]/[HA] ≈ ([H+][A-])/0.500α

≈ ([H+]/Ka)(0.500α)/(1-α)

Solving for Ka, we get:

Ka ≈ H+/0.500α

Substituting the values we have calculated, we get:

Ka ≈ (2.17 × 10^(-4))(1-α)/(0.500α) = 4.37 × 10^(-5)

Therefore, the acid dissociation constant of the unknown acid is approximately 4.37 × 10^(-5).

(b) To find the percentage of acid that is ionized in the solution, we can use the equation:

α = [A-]/[HA] = 10^(-pKa + pH)/(1 + 10^(-pKa + pH))

where pKa is the negative logarithm of the acid dissociation constant. Substituting the values we have calculated, we get:

α = 10^(-(-4.36) + 3.56)/(1 + 10^(-(-4.36) + 3.56)) ≈ 0.008

Therefore, the percentage of acid that is ionized in the solution is approximately 0.8%.

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To draw the two circles, we would need to draw a smaller circle with a diameter of 2,532.5 miles (representing the moon) and a larger circle with a diameter of 75,974.4 miles (representing the Earth) that is 30 times larger than the smaller circle.

If we assume that the larger circle represents the Earth, then the diameter of the Earth would be 30 times the diameter of the smaller circle representing the moon. Let's say that the diameter of the smaller circle is x. Then the diameter of the larger circle (Earth) would be 30 times x or 30x.

To find the correct distance from Earth to the moon at this scale, we need to know the actual distance from Earth to the moon, which is approximately 238,855 miles or 384,400 kilometers. If we divide this distance by the scale factor of 30, we get:

238,855 miles / 30 = 7,961.8 miles

Therefore, the diameter of the smaller circle (moon) would be approximately 7,961.8 miles / π = 2,532.5 miles (rounded to one decimal place). And the diameter of the larger circle (Earth) would be 30 times that or 75,974.4 miles

So, to draw the two circles, we would need to draw a smaller circle with a diameter of 2,532.5 miles (representing the moon) and a larger circle with a diameter of 75,974.4 miles (representing the Earth) that is 30 times larger than the smaller circle.

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The density of sulfur dioxide gas at a temperature of 15°C and pressure of 300 torr is 0.001022 g/cm³, or 0.001022 g/mL, or 1.022 kg/m³, or 0.01022 g/L when converted to atm.

What is density?

To calculate the density of sulfur dioxide gas at a temperature of 15°C and a pressure of 300 torr, we can use the ideal gas law:

PV = nRT

where P is the pressure in atmospheres, V is the volume in liters, n is the number of moles, R is the ideal gas constant (0.08206 L·atm/(mol·K)), and T is the temperature in Kelvin.

First, we need to convert the given temperature of 15°C to Kelvin:

T = 15°C + 273.15 = 288.15 K

Next, we can rearrange the ideal gas law to solve for the number of moles:

n = PV/RT

where we can use the given pressure of 300 torr and convert it to atm by dividing by 760 torr/atm:

P = 300 torr / 760 torr/atm = 0.3947 atm

Substituting the values into the equation, we get:

n = (0.3947 atm) V / (0.08206 L·atm/(mol·K) × 288.15 K)

Now, we can use the molar mass of sulfur dioxide, which is 64.06 g/mol, to convert the number of moles to mass:

mass = n × molar mass

Finally, we can calculate the density of sulfur dioxide gas using the mass and volume:

density = mass / V

To convert the density from g/L to g/cm³, we divide by 1000.

Putting it all together, we get:

n = (0.3947 atm) V / (0.08206 L·atm/(mol·K) × 288.15 K)

n = 0.01595 V

mass = n × molar mass = 0.01595 V * 64.06 g/mol = 1.022 gV

density = mass / V = 1.022 gV / V = 1.022 g/L = 0.001022 g/cm³

Therefore, the density of sulfur dioxide gas at a temperature of 15°C and pressure of 300 torr is 0.001022 g/cm³, or 0.001022 g/mL, or 1.022 kg/m³, or 0.01022 g/L when converted to atm.

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Complete question is: The density of Sulfur dioxide gas at a temperature of 15oC and pressure of 300 torr is 0.01022 atm.

The Ammonium Chloride solution at 0.25 M has a pH of 2.67.

As a result, the weak basic (Chlorine) in the solution is overpowered by the conjugate acid (Ammonium cation), making the solution mildly acidic. According to the equation pH =log[Hydrogen ion], an acidic solution has a pH lower than 7. Aqueous ammonium chloride solution has a pH that is less than 7.

Ammonium cation + Water ⇌ Nitrogen trihydride + Hydronium ion

Kb = [Nitrogen trihydride][Hydronium ion] / [Ammonium cation]

[Nitrogen trihydride] = [Hydronium ion] = x

[Ammonium cation] = 0.25 - x

Kb = [Nitrogen trihydride][Hydronium ion] / [Ammonium cation]

1.8 × 10–5 = x² / (0.25 - x)

1.8 × 10–5 = x² / 0.25

x² = 4.5 × 10–6

x = 2.12 × 10–3

pH = -log[Hydronium ion] = -log(2.12 × 10–3) = 2.67

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5,250. The number was rounded up from 5,249 because the last digit, 9, is greater than or equal to 5.

Rounding up is a mathematical operation that involves increasing a number to its nearest whole number. It is commonly used when dealing with money, measurements, or statistics. When rounding up, the number is increased to the next highest whole number. For example, if a number is 6.7, it would be rounded up to 7. Rounding up is often used when dealing with exact measurements or estimates to simplify the calculations. It can also be used to make the results of a calculation easier to understand. In the case of money, rounding up can be used to round a number to the nearest dollar. This prevents dealing with fractional amounts of money. Rounding up can also be utilized in statistical analysis, such as in the calculation of mean or median. This simplifies the data and prevents dealing with fractions or decimals.

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Answer:

-191 kJ

Explanation:

The given reaction is:

N₂(g) + 3H₂(g) → 2NH₃(g) ΔH = -76.4 kJ/mol

From the balanced equation, we can see that the stoichiometric ratio between hydrogen (H₂) and ammonia (NH₃) is 3:2. This means that 3 moles of hydrogen react to produce 2 moles of ammonia.

To determine the heat energy when 5.0 g of hydrogen (H₂) burns, we need to follow these steps:

Step 1: Calculate the moles of hydrogen (H₂)

Using the molar mass of hydrogen (H₂), which is 2 g/mol, we can calculate the moles of hydrogen (H₂) in 5.0 g of hydrogen:

Moles of H₂ = Mass of H₂ / Molar mass of H₂

Moles of H₂ = 5.0 g / 2 g/mol

Moles of H₂ = 2.5 mol

Step 2: Use the stoichiometry of the reaction

Based on the stoichiometry of the reaction, we know that 3 moles of hydrogen (H₂) react to produce 2 moles of ammonia (NH₃), and the enthalpy change (ΔH) is -76.4 kJ/mol.

Step 3: Calculate the heat energy

The heat energy for 2.5 moles of hydrogen (H₂) can be calculated using the given enthalpy change (ΔH) and the stoichiometry of the reaction:

Heat energy = Moles of H₂ x ΔH

Heat energy = 2.5 mol x -76.4 kJ/mol

Heat energy = -191 kJ (rounded to three significant figures)

So, the heat energy when 5.0 g of hydrogen (H₂) burns is -191 kJ (rounded to three significant figures), and the negative sign indicates that the reaction is exothermic, releasing heat.

Component form of the vector v is as follows: 4 3 1.5 1 Using the standard basis vectors I and j), express the vector w as follows: 3 two 1 4 pp . 1 3 w 3.5 C. V plus w= d. Determine the vector v's magnitude

What does "vector" mean?

Latin word for "carrier" is "vector." Point A is transported to point B by vectors. The orientation of the vectors AB is the direction in which point A is moved in relation to point B, and the amplitude of the vector is the width of the line connecting the two locations A and B. The terms Euclidean vectors and spatial vectors are also used to refer to vectors.

A vector space is what?

A vector space, also known as a linear space, is a collection of things called vectors that can be added to and multiplied ("scaled") by figures called scalars in the fields of mathematics, physics, and engineering.

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To convert to Celsius, we subtract 273.15 from the Kelvin temperature, giving us a final answer of 42.1°C.

Temperature is a physical quantity that measures the average kinetic energy of the particles in a system. It is an important parameter for understanding the behavior of matter and the underlying physical processes at work. Temperature is measured in units such as degrees Celsius (°C), Fahrenheit (°F), Kelvin (K), or Rankine (°R). Temperature affects the rate at which chemical reactions occur and the movement of particles in solids, liquids, and gases.

The ideal gas law states that PV = nRT,
where n is the number of moles,
P is the pressure,
V is the volume, R is the ideal gas constant (8.314 J/molK), and
T is the temperature in Kelvin.
Rearranging the equation, we get T = (PV)/(nR).
Plugging in our values, we get T = (89.9 atm * 4191 mL)/(2.6 mol * 8.314 J/molK) = 115.2 K.
To convert to Celsius, we subtract 273.15 from the Kelvin temperature, giving us a final answer of 42.1°C.

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Answer: C)Deposition (gas to solid)

Explanation: According to the phase diagram, at room temperature (25°C) and 1 atm, the sample is in the gas phase.  As the temperature decreases to 80 K, it falls below the sublimation curve. T he sublimation curve represents the conditions at which a substance can change directly from a solid to a gas or from a gas to a solid without passing through the liquid phase.

Since the sample is in the gas phase at room temperature, cooling it to 80 K would cause it to go through the process of deposition, where the gas particles directly transform into a solid without first becoming a liquid.  This is indicated by the section of the phase diagram below the sublimation curve.

Answer silver chloride (AgCl) and lead chloride (PbCl2).

Explanation:

Two salts that have the same solubility at approximately 23°C are silver chloride (AgCl) and lead chloride (PbCl2).

Both AgCl and PbCl2 have very low solubilities in water at room temperature, and their solubilities are similar at around 23°C. They are both sparingly soluble salts, meaning they dissolve only to a limited extent in water to form a saturated solution.

It's important to note that solubility can vary depending on the specific conditions, such as temperature, pressure, and presence of other substances. The solubility of salts can also be affected by factors such as pH and the presence of other ions in solution. Therefore, it's always best to consult reliable sources, such as reference tables or experimental data, for accurate solubility information at a given temperature.

The elements that have an outer electron configuration of ms2nd2 are located in the d-block of the periodic table and include some of the transition metals and lanthanides.

To determine which elements in the periodic table have this outer electron configuration, you can look at the position of the d-block elements in the table. The d-block elements are located in the middle of the table and include the transition metals. These elements have partially filled d orbitals, which can accommodate up to 10 electrons.

Elements in the d-block with an atomic number of 21 through 30 (scandium through zinc) have an outer electron configuration of d10s2 and do not fit the ms2nd2 configuration. However, elements in the d-block with an atomic number of 39 through 48 (yttrium through cadmium) have an outer electron configuration of d10s2p1 and can have the ms2nd2 configuration by removing the single electron in the p orbital. Elements in the d-block with an atomic number of 57 through 80 (lanthanum through mercury) also have the possibility of having an outer electron configuration of ms2nd2.

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Around 80.5 KJ

Multiply Heat of Fusion and Mass to get the q value.

[tex]CO_{2}[/tex]The following compounds' mole fractions (X) are (a)0.986 (b)0.750 (c)0.811 for the given solutions.

[tex]H_{2}SO_{4}[/tex] mass is 19.4 g.

[tex]H_{2}SO_{4}[/tex]'s molecular weight is 98.08 g/mol.

It's molecular weight is 19.4 g/98.08 g/mol, or 0.1979 mol.

Density times volume is 1.00 g/mL times 0.251 L and 251 g for water mass.

[tex]H_{2} O[/tex] has a molecular weight of 18.02 g/mol.

Water moles are equal to 251 g / 18.02 g/mol, or 13.93 mol.

The solution's total moles are equal to 0.1979 mol plus 13.93 mol, or 14.13 mol.

Sulphuric Acid's mole fraction is equal to 0.1979 mol/14.13 mol, or 0.014.

Water mole fraction is equal to 13.93 mol / 14.13 mol, or 0.986 mol.

KBr's mass is 35.7 g.

KBr has a molecular weight of 119 g/mol.

The formula for KBr is 35.7 g/119 g/mol, which equals 0.300 mol.

16.2 g of water in mass

Water has a molecular weight of 18.02 g/mol.

Water moles are equal to 16.2 g / 18.02 g/mol, or 0.899 mol.

The solution has a total of 1.199 moles (0.300 mol + 0.899 mol).

The mole fraction of KBr is equal to 0.300 mol/1.199 mol, or 0.250

Water mole fraction is equal to 0.899 mol / 1.199 mol, or 0.750 moles.

[tex]CO_{2}[/tex] mass = 233 g

It has a molecular weight of 44.01 g/mol.

Its moles are equal to 233 g / 44.01 g/mol, or 5.291 mol.

Water volume equals 0.409 L.

Water has a molecular weight of 18.02 g/mol.

(density × volume) / molecular weight (1.00 g/mL 409 mL) / 18.02 g/mol = 22.71 mol = number of moles of water

The solution's total moles are equal to 5.291 mol plus 22.71 mol, or 28.00 mol.

[tex]CO_{2}[/tex] mole fraction = 5.291 moles / 28.00 moles = 0.189

[tex]H_{2} O[/tex] mole fraction is 22.71 mol/28.00 mol, or 0.811 moles.

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40 grams of KCl are dissolved in 100 mL of water at 45C. 5g of  additional grams of KCI are needed to make the solution saturated at 80 C as the solubility of KCl is 45g/ml

A uniform combination of a number of solutes within a solvent is referred to as a solution. One frequent illustration of a Solution is adding sugar cubes into your cup of tea and coffee. Solubility is the quality that makes sugar molecules more soluble.

In water, potassium chloride (KCl) dissolves. Its water solubility, like that of all other solutes, depends on temperature. The solubility of a salt increases as the solvent's temperature rises. This is fairly simple to experience with sugar. 40 grams of KCl are dissolved in 100 mL of water at 45C. 5g of  additional grams of KCI are needed to make the solution saturated at 80 C as the solubility of KCl is 45g/ml.

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The state of matter that tends to have unique factors to consider when discussing solubility compared to the other two states (solid and gas) is the liquid state.

Solubility refers to the ability of a substance (solute) to dissolve in a particular solvent to form a homogeneous mixture (solution). Various factors can affect the solubility of a substance, including temperature, pressure, and the nature of the solute and solvent.

In the case of liquids, the unique factor to consider when discussing solubility is often temperature. The solubility of many solid solutes in liquids generally increases with increasing temperature. This is because higher temperatures provide more energy to break the intermolecular forces between solute particles, allowing them to disperse more evenly throughout the solvent.

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The eutectic point is the lowest temperature at which the liquid phase is constant at a particular pressure.

A melting composition known as a eutectic consists of at least two components that melt and freeze at the same rates. The components combine during the crystallisation phase, operating as a single component as a result.

The eutectic is the system's lowest melting point under its own pressure; it has a matching temperature called the eutectic temperature and produces the eutectic liquid as a result. In terms of composition, eutectic liquids are located between the system's solid phases.

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Answer: three

Explanation:

Answer:

The answer is B: 0.0025 M

According to molar concentration and dilution concept, the  [H₃O+] in the final solution is closest to 0.05 M.

Molar concentration is defined as a measure by which concentration of chemical substances present in a solution are determined. It is defined in particular reference to solute concentration in a solution . Most commonly used unit for molar concentration is moles/liter.

The molar concentration depends on change in volume of the solution which is mainly due to thermal expansion. Molar concentration is calculated by the formula, molar concentration=mass/ molar mass ×1/volume of solution in liters.

In terms of moles, it's formula is given as molar concentration= number of moles /volume of solution in liters.In case of 2 solutions concentrated and diluted it is calculated as, M₁V₁=M₂V₂ substitution gives M₂=0.25×100/500=0.05

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3.0 moles of [tex]Al[/tex] can fully react with hydrogen chloride to produce 4.5 moles of [tex]H_{2}[/tex]. Thus, 0.93 moles will be produced by 0.62 moles of [tex]Al[/tex].

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Answer:

Neutrons and Protons

Explanation:

Different elements can have subatomic particles of varying sizes. The size of an atom is defined by the size of its electron cloud, which is composed of electrons, and the size of its nucleus, which is composed of protons and neutrons. The atomic number and subsequently the identity of an element are determined by the number of protons in the nucleus. The quantity of protons and neutrons in the nucleus determines its size. The quantity of electrons in the electron cloud and the energy levels they are located at define its size. The size of atoms can differ depending on the element due to differences in the amount of protons, neutrons, and electrons.

The maximum mass of carbon dioxide that could be produced from 6.9 g of octane and 42.2 g of oxygen is 21.3 g, rounded to 2 significant digits.

What is Octane?

Octane is a hydrocarbon with the chemical formula [tex]C_{8} H_{18}[/tex] It is an organic compound belonging to the alkane group, which means it consists of only carbon (C) and hydrogen (H) atoms bonded together by single covalent bonds. Octane is a colorless liquid with a molecular weight of approximately 114 g/mol and is commonly used as a component in gasoline or fuel for internal combustion engines.

From the balanced equation, we know that 1 mole of octane reacts with 12.5 moles of oxygen to produce 8 moles of carbon dioxide. Therefore, 0.0605 mol of octane would require 0.0605 mol x 12.5 = 0.75625 mol of oxygen to fully react.

Since we have only 1.32 mol of oxygen, which is in excess compared to the 0.75625 mol required by octane, oxygen is the excess reactant, and octane is the limiting reactant.

Now, we can use the stoichiometry of octane to carbon dioxide to calculate the maximum mass of carbon dioxide produced:

From the balanced equation, we know that 1 mole of octane produces 8 moles of carbon dioxide.

Molar mass of carbon dioxide (CO2) = 44.01 g/mol

Maximum moles of carbon dioxide produced from octane = 0.0605 mol x 8 = 0.484 mol

Maximum mass of carbon dioxide produced from octane = 0.484 mol x 44.01 g/mol = 21.3 g

Remember to round the final answer to 2 significant digits as requested.

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The final temperature is -160°C

We can use the combined gas law, which relates the pressure, volume, and temperature of a gas:

(P₁V₁)/T₁ = (P₂V₂)/T₂

Where

In this case, we can assume that the pressure of the gas is constant, since it is not given in the problem statement. So we can simplify the equation to:

(V₁/T₁) = (V₂/T₂)

Where

We are given that the initial volume (V₁) is 80 L and the final volume (V₂) is twice that, or 160 L. We are also given that the initial temperature (T₁) is -40°C. To find the final temperature (T₂), we can plug these values into the equation:

(V₁/T₁) = (V₂/T₂)

(80 L)/(-40°C) = (160 L)/T₂

Simplifying:

-2 L/°C = (160 L)/T₂

Multiplying both sides by -1°C/2 L (the reciprocal of -2 L/°C):

1/2 = (T₂)/(160 L) x (-1°C/2 L)

1/2 = -T₂/320

Multiplying both sides by -1 to isolate T₂:

-1/2 = T₂/320

T₂ = -160°C

Therefore, the final temperature is -160°C.

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The correct answer that represents beta decay is

In beta decay, a neutron in the nucleus is converted into a proton, and an electron (or beta particle) and an antineutrino are emitted from the nucleus.

In this case, a neutron in the 164Gd nucleus is converted into a proton, and an electron is emitted from the nucleus, resulting in the production of 164Tb.

Option A is not a valid representation of any known type of radioactive decay.

Option B represents alpha decay, in which an alpha particle is emitted from the nucleus.

Option C represents electron capture, in which an electron is captured by the nucleus.

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The direction of the reaction, as written, spontaneous at 25 ∘C and standard pressure is reverse.

To calculate the value of Δ∘rxn at 25.0 ∘C, we can use the equation:

Δ∘rxn(T2) = Δ∘rxn(T1) + ΔH∘(products) - ΔH∘(reactants)

where;

Using the data from the table of thermodynamic properties, we can look up the enthalpy change of formation values for C2H4(g), H2O(l), and C2H5OH(l):

ΔH∘f(C2H4(g)) = 52.26 kJ/mol

ΔH∘f(H2O(l)) = -285.83 kJ/mol

ΔH∘f(C2H5OH(l)) = -277.69 kJ/mol

Substituting these values into the equation, we get:

Δ∘rxn(25.0 ∘C) = -44.2 kJ + (-277.69 kJ/mol) - (-52.26 kJ/mol)

Δ∘rxn(25.0 ∘C) = -44.2 kJ - (-277.69 kJ/mol) + 52.26 kJ/mol

Δ∘rxn(25.0 ∘C) = -44.2 kJ + 277.69 kJ/mol + 52.26 kJ/mol

Δ∘rxn(25.0 ∘C) = 233.23 kJ/mol

So the value of Δ∘rxn at 25.0 ∘C is 233.23 kJ/mol.

In which direction is the reaction, as written, spontaneous at 25 ∘C and standard pressure?

Since the value of Δ∘rxn at 25.0 ∘C is positive (233.23 kJ/mol), the reaction as written is not spontaneous at this temperature and standard pressure. The correct answer is "reverse."

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The standard change in Gibbs free energy of the reaction at 25 ∘C is -1.69 kJ/mol.

What is standard change?

To find the standard change in Gibbs free energy of the reaction, we need to use the following equation:

ΔG° = -RT ln(K)

where ΔG° is the standard change in Gibbs free energy, R is the gas constant (8.314 J/mol·K), T is the temperature in Kelvin (25 °C = 298 K), and K is the equilibrium constant.

To find K, we need to use the equilibrium partial pressures:

K = (PC × PD) / (PA × PB²)

where PA, PB, PC, and PD are the equilibrium partial pressures of A, B, C, and D, respectively.

Substituting the values, we get:

K = (5.47 atm × 5.63 atm) / (5.63 atm × (5.00 atm)²)

K = 0.6176

Now we can calculate the standard change in Gibbs free energy:

ΔG° = -RT ln(K)

ΔG° = -(8.314 J/mol·K) × (298 K) × ln(0.6176)

ΔG° = -1,690 J/mol or -1.69 kJ/mol

Therefore, the standard change in Gibbs free energy of the reaction at 25 ∘C is -1.69 kJ/mol.

What is free energy?

Free energy, also known as Gibbs free energy, is a thermodynamic quantity that represents the amount of energy in a system that is available to do work at a constant temperature and pressure. It is denoted by the symbol G and is expressed in units of joules (J) or calories (cal).

In simple terms, free energy is the energy that can be used to do work. It is defined by the equation:

ΔG = ΔH - TΔS

where ΔH is the change in enthalpy (heat content) of the system, ΔS is the change in entropy (disorder) of the system, and T is the absolute temperature in Kelvin.

If ΔG is negative, the reaction is spontaneous and can proceed without the input of external energy. If ΔG is positive, the reaction is non-spontaneous and requires energy input to proceed. If ΔG is zero, the system is at equilibrium.

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Enantiomers rotate the plane of polarized light in opposite directions, and this property is used to distinguish between them in a process called optical rotation.

Enantiomers are pairs of molecules that are non-superimposable mirror images of each other.

They are isomers, meaning they have the same molecular formula and connectivity but differ in their three-dimensional arrangement of atoms in space.

Enantiomers exhibit identical physical and chemical properties, except for their interaction with plane-polarized light (a type of light that oscillates in a single plane).

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