Nitric oxide (NO) from car exhaust is a primary air pollutant. Calculate the equilibrium constant for the reaction
N2(g) + O2(g) equilibrium reaction arrow 2 NO(g)
at 25°C using the data listed in the supporting materials.


Calculate the equilibrium constant at 1496°C, which is a typical temperature inside the cylinders of a car's engine after it has been running for some time. (Assume that both ΔrH° and ΔrS° are temperature independent.)

Answers

Answer 1

This problem is asking for the equilibrium constant at two different temperatures by describing the chemical equilibrium between gaseous nitrogen, oxygen and nitrogen monoxide at 25 °C and 1496 °C as the room temperature and the typical temperature inside the cylinders of a car's engine respectively:

N₂(g) + O₂(g) ⇄ 2 NO(g)

Thus, the calculated equilibrium constants turned out to be 6.19x10⁻³¹ and 9.87x10⁻⁵ at the aforementioned temperatures, respectively, according to the following work:

There is a relationship between the Gibbs free energy, enthalpy and entropy of the reaction, which leads to the equilibrium constant as shown below:

[tex]\Delta _rG=\Delta _rH-T\Delta _rS\\\\\Delta _rG=-RT ln(K)[/tex]

Which means we can calculate the enthalpy and entropy of reaction and subsequently the Gibbs free energy and equilibrium constant. In such a way, we calculate these two as follows, according to the enthalpies of formation and standard entropies of N₂(g), O₂(g) and NO(g) since these are assumed constant along the temperature range:

[tex]\Delta _rH=2*90.25 kJ/mol - (0 kJ/mol+0 kJ/mol)=180.5kJ/mol\\\\\Delta _rS=2*(0.211 kJ/mol*K)-(0.192kJ/mol*K+0.205kJ/mol*K)=0.025kJ/mol*K[/tex]

Then, we calculate the Gibbs free energy of reaction at both 25 °C and 1496 °C:

[tex]\Delta _rG_{25\°C}=180.5-(25+298.15)*0.025=172.42kJ/mol\\\\\Delta _rG_{1496\°C}=180.5-(1496+298.15)*0.025=135.65kJ/mol[/tex]

And finally, the equilibrium constants derived from the general Gibbs equation and Gibbs free energies of reaction:

[tex]K=exp(-\frac{\Delta _rG}{RT} )\\\\K_{25\°C}=exp[-\frac{172420 J/mol}{(8.3145\frac{J}{mol*K})(298.15K)} ]=6.19x10^{-31}\\\\K_{1496\°C}=exp[-\frac{135650J/mol}{(8.3145\frac{J}{mol*K})(1769K)} ]=9.87x10^{-5}[/tex]

Learn more:

(Gibbs free energy) https://brainly.com/question/15213613

Related Questions

According to Hebrews 11, what did Abraham believe God would do if Isaac was slain as a sacrifice?

Answers

Answer:

He thought he was going to bring Isaac back from the dead. They ended up sacrificing the donkey instead.

13. Which has the largest atomic radius?
A. fluorine B. chlorine C. bromine
D. a bromine anion with a charge of 1-

Answers

Answer:

bromine

Explanation:

how are homogeneous mixtures different from heterogeneous mixtures

Answers

Answer:

In Homogenous mixtures, the whole mixture is in the same phase whereas in Heterogeneous mixture, substances can be of two phases and layers may separate. ... Homogeneous mixture could be exemplified as a sugar solution or salt solution whereas Mixture of salt and sand could be used as an example of Heterogeneous mixture.

Which of the following describes a heterotroph?

Heterotrophs get their energy directly from the sun.
Heterotrophs conduct photosynthesis.
Heterotrophs can create their own food.
Heterotrophs cannot create their own food.

Answers

heterotrophs cannot create their own food and rely on others for food

heterotrophs cannot create their own food.

heterotrophs are like animals and humans so humans can’t make their own food.

Please help due tomorrow
Giving Brainlesst

Answers

Answer:

Down arrow:

-a car comes to a stop when a traffic light turns red

Up arrow:

-race car accelerates when a race begins

Circle:

-car driving 45 mile per hour down straight road

Explanation:

and i think the car going around a bend would be an up arrow

If there is .03L of NaOH in a flask, how can a .12M solution of H2SO4 be used to determine the concentration of NaOH in the reaction?

Answers

The concentration of NaOH in the reaction can be determined using the Titration method.

The concentration of NaOH in the reaction can be determined by titration.

A burette if filled with the known concentration of H₂SO₄ and then titrated against the known volume of NaOH in a conical flask. An indicator is used in order to determine the end-point of the titration process. At the end-point of the titration, the volume of acid used is recorded.

Next, we will write the balanced chemical equation of the reaction.

The balanced chemical equation for the reaction is

2NaOH + H₂SO₄ → Na₂SO₄ + 2H₂O

This means 2 moles of NaOH is required to neutralize 1 mole of H₂SO₄

Now, we can determine the concentration of NaOH by using the titration formula.

[tex]\frac{C_{A}V_{A} }{C_{B}V_{B}} = \frac{n_{A}}{n_{B}}[/tex]

Where [tex]C_{A}[/tex] is the concentration of acid

[tex]V_{A}[/tex] is the volume of acid

[tex]C_{B}[/tex] is the concentration of base

[tex]V_{B}[/tex] is the volume of base

[tex]n_{A}[/tex] is the mole ratio of acid

[tex]n_{B}[/tex] is the mole ratio of base

Then, we put the respective parameters, including the volume of acid determined from the titration process, into the formula to determine the concentration of the NaOH.

Hence, the concentration of NaOH in the reaction can be determined using the Titration method.

Learn more on titration here: https://brainly.com/question/25290615

In each of the combinations, predict the more electronegative element based on its position on the
periodic table. Then look up the actual electronegativities. Circle the reaction pair that should
actually caust a reaction.
More
Combination Combination electronegative
A
B
element based on
position on table
Ba + Fe2-
Ba?- + Fe
Actual
Actual
electronegativity electronegativity
of element of element
a)
Ba =
Fe=
b)
)
Sn + Hg
Sn- + Hg
Sn =
Hg =
c)
)
Na + Mg2+
Na + Mg
Na=
Mg =
=
Zn + CO2-
Zn?- + Co
Zn =
Co=

Answers

c)

)

Na + Mg2+

Na + Mg

Na=

Mg =

=

Zn + CO2-

Zn?- + Co

Zn =

Co=

Why do nonmetal atoms share electrons in covalent bonds

Answers

Answer:

pairs of electrons

Explanation:

covalent bondin occurs when pairs of electrons are shared by atoms.... nonmetal will readily form covalent bonds with other nonmetal in order to obtain stability.

Please help me in this question about series circuit and pararell circuit

Answers

Explanation:

it is a parallel circuit.

hope this helps you.

How many moles are in 500 g of P

Answers

Answer:

.....................

30.973761

Draw the Lewis Structure for C2F4. b. Total RED's c. Nonbonding RED's d. Electron-Pair Geometry e. Molecular Shape f. Is it Polar, Nonpolar or Ionic

Answers

The molecule C2F4 has a trigonal planar molecular and electron pair geometry.

The shape of a molecule is dependent on the number of electron pairs that surround the central atom in the molecule. In the molecule C2F4, there are two central carbon atoms.

Each of the central carbon atoms have a trigonal planar molecular and electron pair geometry. C2F4 is a symmetrical molecule so it is nonpolar and has a zero dipole moment.

Learn more: https://brainly.com/question/7558603

the normal human eye responds to visible light of wavelength range from about 390 to 710nm. Determine the frequency range of the human eye.​

Answers

Explanation:

=>7.7 x10¹⁴ to 4.2 x10¹⁴Hz

How many species are known to be living on Earth?

Answers

Answer:

8.7 million species

Explanation:

Scientists have estimated that there are around 8.7 million species of plants and animals in existence.

What is the function of the nervous system? What is the basic unit of the nervous system?

#Nova

Answers

Answer:

The basic unit of the nervous system is a nerve cell or neuron. The nervous system transmits signals between the brain and the rest of the body, this way, the nervous system's activity controls the ability to move, breathe, see, and think.




Explanation:

Have a great rest of your day
#TheWizzer

14. Which has the lowest ionization energy?
A. beryllium (Be) B. strontium (Sr) Calcium (Ca) D. magnesium (Mg)

Answers

Answer: B. strontium

Explanation: This is due to electrons being further away from the nucleus in strontium.

USCTIR ENFIK meaning?

Answers

Answer:

la branche de la mécanique concernée par le mouvement des objets sans référence aux forces qui provoquent le mouvement

Answer:

the features or properties of motion in an object.

You have 15 grams of of MgSO4, how
many moles of MgSO4 do you have?
A 0.125 Moles of MgSO4
B 0.75 Moles of MgSO4
C 7.5 Moles of MgSO4
D 15.88 Moles of MgSO4

Answers

Answer:

C 7.5 Moles of MgSO4

Explanation:

Which molecule does not obey the Octate rule of valence electrons .

BeCl2

FeCl2

CuCl2

ZnCl2​

Answers

Explanation:

Which molecule does not obey the Octate rule of valence electrons .

BeCl2

FeCl2

CuCl2

ZnCl2

→BeCl2

Explaination:

BeCl2 violates the octet rule because the boron should be in a suitable valence state such that it binds to 3 chlorines. However, in this molecule boron is associated with six electrons.

Answer:

BeCl2

Explanation:

hope Its useful for you

[tex] \\ \\ [/tex]

kk

How many electrons does chlorine need to gain in order to be like Argon ?


- 2 electrons

- 3 electrons

- 1 electron

Answers

Chlorine is in group 7 and thus requires 1 more valence electron in order to form a full valence shell as Argon (group 8 or also known as group 0). Therefore, the answer is 1 electron

Heart, 5 stars, and Brainiest if right! Answer needed ASAP PLEASE!What type of forces do not change the motion of an object?
A. Acceleration forces
B. Balanced forces
C. Inertia forces
D. Unbalanced forces

Answers

Answer:

unbalanced force

Explanation:

pls mark me brainliest

Answer:

B. balanced forces

Explanation:

the motion of an object will not change if the forces pushing or pulling the object are balanced

which of the following forces could be used in electronic devices?

spring
gravitational
applied
magnetic

Answers

It’s should be magnetic

Answer:

Explanation:

poop

You have a block of an unknown metal. Which properties would be most helpful in determining what it is? If it could be

Answers

the distributive property would work best

Select True or False: The entropy of a perfectly ordered crystalline substance at 0 K is 0 J/mol. Bloom's Level: Understand

Answers

True, the entropy of a perfectly ordered crystalline substance at 0 K is 0 J/mol.

The third law of thermodynamics states that, the entropy of a system approaches a constant value as the temperature of the system approaches absolute zero.

The entropy of any perfectly ordered, crystalline substance at absolute zero temperature is zero.  That is, the entropy of a pure, perfect crystalline substance at 0 K is 0 J/K.

Thus, we can conclude that the given statement is true.  The entropy of a perfectly ordered crystalline substance at 0 K is 0 J/mol.

Learn more about third law of thermodynamics here: https://brainly.com/question/1156831

What quantity of energy is required to heat a piece of iron wighing 1.31 g from 25.0 degrees celsius to 46.0 degrees celsius

Answers

the mass energy of telegranium

The quantity of energy required to heat a piece of iron weighing 1.31 g from 25.0 degrees Celsius to 46.0 degrees Celsius is 2.93 calories.

What is energy?

The ability or power to perform tasks, such as the ability to move an object (having a certain mass) by exerting force.

Energy can exist in many forms, including electrical, mechanical, chemical, thermal, and nuclear, and it can also change its form.

The equation q = mcT, where m is the sample mass, c is the specific heat, and T is the temperature change, can be used to determine the amount of heat acquired or lost by a sample (q).

Q = mcΔT

Q = 1.31 g x 449 x 21° C = 12.26 joule

12.26 /1 x 1 cal / 4.189= 2.93 calories

Therefore, the quantity of energy required to heat a piece of iron is 2.93 cal.

To learn more about energy, refer to the link:

https://brainly.com/question/22920370

#SPJ2

PLEASE HELP GIVING brainless

Answers

Answer:

An unbalanced force causes the object to change position.

Explanation:

An unbalanced force causes the object on which it is acting to accelerate, changing its position, speed, or direction due to equal forces on opposite sides.

A 4.0 L balloon has a pressure of 406 kPa. When the pressure increases to 2,030 kPa, what is the volume? *
0.4 L
0.8 L
0.2 L
1 L

Answers

The new volume when pressure increases to 2,030 kPa is 0.8L

BOYLE'S LAW:

The new volume of a gas can be calculated using Boyle's law equation:

P1V1 = P2V2

Where;

P1 = initial pressure (kPa)P2 = final pressure (kPa)V1 = initial volume (L)V2 = final volume (L)

According to this question, a 4.0 L balloon has a pressure of 406 kPa. When the pressure increases to 2,030 kPa, the volume is calculated as:

406 × 4 = 2030 × V2

1624 = 2030V2

V2 = 1624 ÷ 2030

V2 = 0.8L

Therefore, the new volume when pressure increases to 2,030 kPa is 0.8L.

Learn more about Boyle's law calculations at: https://brainly.com/question/1437490?referrer=searchResults

A block has 73 kg is being pushed and accelerated at rate of 10 m/s. what force is being applied to the block?

A-730 N
B-7.3 N
C-7300 N
D-730 Kg

Answers

Answer:

730 N

Explanation:

force =mass×acceleration

force= 73kg × 10 m/s

f=730N

what is the approximate pH of a solution labeled 0.050 M HCLO ?

Answers

Answer:

It would be around 4.4 in PH

Explanation:

I hope this helped.

what are nanofluids and how they work?​

Answers

Answer:

What is nanofluids?

Nanofluids are engineered suspensions of nanometer-sized solid particles in a base fluid. Suspending small solid particles in the energy transmission fluids can improve their thermal conductivity and provides an effective and innovative way to enhance their heat transfer characteristics significantly.

How nanofluids work?

Nanofluid refers to the dispersion of metal or non-metal nano-powder into traditional heat exchange media such as water, alcohol, and oil to prepare a uniform, stable and high thermal conductivity. The traditional heat exchange medium has a low thermal conductivity and has been unable to meet the growing demand for industrial engineering heat exchange. The thermal conductivity of some metal or non-metal nanoparticles is often hundreds of times higher than that of heat-conducting media. For example, common silicon carbide nanoparticles have a thermal conductivity of 170-270 W/m•K. The researchers found that if the nanoparticles can be uniformly and stably dispersed in the heat transfer medium, the thermal conductivity of the nanoparticles will be greatly improved.


Explain what is meant by the term 'conservation of mass'.
Give your answer in terms of the atoms that take part in a chemical reaction

Answers

Answer:

Below

Explanation:

In a chemical reaction, per the law of conservation of mass, no atoms or subatomic particles will be created or destroyed; for example, H2O2 will decompose into H2 and O2, meaning no matter was created or destroyed.

Other Questions
It takes 120 mL of 0.15 M of carbonic acid (H2CO3) to neutralize 300 mL of sodium hydroxide (NaOH) for the following balanced chemical reaction:2NaOH + H2CO3 N2CO3 + 2NaOHThe concentration of the sodium hydroxide _____.0.03 M0.24 M0.12 M0.06 M write an algebraic expression for the word expression.the sum of 9 and a number x Giving brainliest to whoever gets it right !!!How does the rising action in a novel help develop the novel's themes?A. It introduces the characters and their motivations.B. It includes various ways of stating the moral of the story.C. It reminds readers of other stories with similar themes.D. It raises questions that the story will eventually answer. what is the punishment for selling lethal poisons in verona I wish this was free Which of the following is the most accurate qualitative description of the the magnetic field vector b inside the cylindrical resistor?. Meenal went to the USA after she_________Complete the following sentence meaningfully. Potatoes are sold at $3.30 per 55 kg bag.(a) Calculate the cost per kilogram.(b) How much will 12 kg cost? Wings of birds,wings of insects and patagia of bats are analogous organ? why how do monosaccharides combine to form polysaccharides Part 1: NounsDirections: Write the plural form of each noun.1. child2. friend3. baby4. lunch5. bike PLEASE HELP ME ON THIS What is it okzzzzzzzzzzzzZ what is the potential energy of a 2kg plant that is on a windowsill 1.3 m high?what is the kinetic energy of a 7.26 kg bowling ball that is rolling at a speed of 2 m/san apple as 6 J of energy. the apple sits on a counter 3 m high. what is the mass of the apple/ please help me i need a long answer on this its biology Evaluate the expression for x = 5 and y = -1xy - y = How do you write 2/5 as a percentage In chemistry class, you are given a density column with 3 liquids (shown in theimage). A small sample of beryllium (a metal) with a mass of 2.8 grams and a volumeof 1.5 mL is added to the column. Where would the metal sample be located in thecolumn? Find the inverse of the function.f(x) = x^3 - 3 Calculate the molar mass of magnesium chloride, CaCl 2. Ca = 40.1g, Cl = 35.5g