Palladium crystallizes in a face-centered cubic unit cell. Its density is 12.0 g/cm3 at 27°C. Calculate the atomic radius of Pd.
A face-centered cubic (FCC) lattice is used by Palladium. As a result, the lattice parameter of palladium is a
=(4V/√3)^(1/3) ,
where V is the atomic volume of palladium. The formula for the density of a substance is d=m/V, where d is the density, m is the mass, and V is the volume of the substance. In this situation, m = M (mass of 1 mole of palladium), which can be expressed as M= n × m, where n is the number of moles of palladium and m is the mass of one palladium atom. Therefore, the density formula becomes
d=M/V.
Palladium's atomic volume is V=(4πr^3/3) /N_a,
where Na is Avogadro's constant (6.022 × 10^23 mol^-1). The atomic radius of Pd is given by the following formula:r=(a/2) × √2The density of Pd is given by the following formula
d=M/V
The molar mass of Pd can be calculated from its atomic weight (106.42 g/mol), M=106.42 g/mol The atomic volume of Pd is given by the following formula:
V= 4r^3/3Na
Use this value of V to determine the lattice parameter a = (4V/√3)^(1/3).r = (a/2) × √2
Calculations:d = 12.0 g/cm3M = 106.42 g/mol
V = (4πr^3/3) /N_a
Let's solve for V:
V = (4πr^3/3) /N_a = (4π (162.5 × 10^-30 m)^3/3) / (6.022 × 10^23 mol^-1) = 8.927 × 10^-6 cm^3/mol
The lattice parameter can be determined now
:a = (4V/√3)^(1/3) = (4 (8.927 × 10^-6 cm^3/mol) / √3)^(1/3) = 3.891 × 10^-8 cmThe atomic radius can be determined:r = (a/2) × √2 = (3.891 × 10^-8 cm/2) × √2 = 1.096 × 10^-8 cm
The atomic radius of Pd is 1.096 × 10^-8 cm.
Learn more about face-centered cubic (FCC) lattice at brainly.com/question/14885097
#SPJ11
what might be a source of octane in the product mixture in this reaction? hint: you did quench the hydroboration reaction with water and let the mixture sit for a week before proceeding to the oxidation step.
Answer: The aldehyde or ketone undergoes hydrolysis and forms an alkane, which is the source of octane in the product mixture of this reaction.
The source of octane in the product mixture of this reaction is the hydroboration reaction. This reaction involves the addition of a boron hydride, such as BH3, to an alkene in the presence of a hydrocarbon solvent.
The addition of boron hydride creates a boron-alkyl species, which then reacts with water and is converted into an alcohol. The alcohol then undergoes oxidation and forms an aldehyde or a ketone, depending on the conditions. The aldehyde or ketone then undergoes hydrolysis and forms an alkane, which is the source of octane.
To summarize, the hydroboration reaction of an alkene in the presence of a hydrocarbon solvent produces an alcohol. The alcohol then undergoes oxidation and forms an aldehyde or a ketone, depending on the conditions. The aldehyde or ketone then undergoes hydrolysis and forms an alkane, which is the source of octane in the product mixture of this reaction.
Learn more about hydrolysis here:
https://brainly.com/question/24213349#
#SPJ11
Wood will dissolve in water.
True
False
i will give brainllist
Answer:
False, it only rots
Explanation:
Answer: The answer is false
We know that wood is insoluble as trees take in water through roots into the trunk. Therefore, water is insoluble in water. Note: Polymers are defined as materials that consist of repeating large molecules.
Explanation: Hope this helps!! :)) Have a great spring break!!
Mark me brainliest!! :))
calculate the mass of so2 produced when 185 grams of oxygen reacts using this equation: 2cu2s 3o2 ----> 2cu2o 2so2 step by step
To calculate the mass of SO2 produced when 185 grams of oxygen reacts, we need to use the following equation: 2Cu2S + 3O2 ---> 2Cu2O + 2SO2.
Step 1: Calculate the molar mass of oxygen.
The molar mass of oxygen is 32.00 g/mol.
Step 2: Calculate the number of moles of oxygen.
To calculate the number of moles of oxygen, we need to divide the given mass of oxygen (185 g) by the molar mass of oxygen (32.00 g/mol).
Therefore, the number of moles of oxygen is 5.78 moles (185 g/32.00 g/mol = 5.78 moles).
Step 3: Calculate the molar ratio between oxygen and SO2.
The equation shows that for every 3 moles of oxygen, 2 moles of SO2 are produced. Therefore, the molar ratio between oxygen and SO2 is 3:2.
Step 4: Calculate the number of moles of SO2.
Since the number of moles of oxygen is 5.78 moles and the molar ratio between oxygen and SO2 is 3:2, the number of moles of SO2 is 3.85 moles (5.78 moles x 2/3).
Step 5: Calculate the molar mass of SO2.
The molar mass of SO2 is 64.07 g/mol.
Step 6: Calculate the mass of SO2 produced.
To calculate the mass of SO2 produced, we need to multiply the number of moles of SO2 (3.85 moles) by the molar mass of SO2 (64.07 g/mol).
Therefore, the mass of SO2 produced is 247.5 g (3.85 moles x 64.07 g/mol = 247.5 g).
To know more about mass click here:
https://brainly.com/question/19694949
#SPJ11
PLEASE HELP i don know how to do Single replacement rxn
Answer:itd a bro
Explanation:dont trust just need points
ethyl benzene is treated with (i) br2 and febr3 and (ii) br2 and light or heat separately. do you think the products will be same? justify your answer.
No, the products obtained from the reaction of ethylbenzene with [tex]Br_2[/tex] and [tex]FeBr_3[/tex] in the presence of light or heat will be different from the products obtained from the reaction of ethylbenzene with [tex]Br_2[/tex] / light or heat.
In the first reaction, [tex]Br_2[/tex] and [tex]FeBr_3[/tex] act as a source of electrophilic bromine, which attacks the aromatic ring of ethylbenzene, leading to the formation of 1-bromoethylbenzene. The mechanism for this reaction is an electrophilic aromatic substitution, where the electrophilic [tex]Br^+[/tex] ion is generated in situ by the reaction of [tex]Br_2[/tex] with [tex]FeBr_3[/tex].
In the second reaction, [tex]Br_2[/tex] acts as a source of free radical bromine, which undergoes a free radical substitution reaction with ethylbenzene, leading to the formation of 1,2-dibromoethylbenzene. This reaction proceeds through a free radical mechanism, where the [tex]Br_2[/tex] molecule is split into two free radicals by the action of light or heat.
Therefore, the products obtained from the two reactions will be different. In the first reaction, 1-bromoethylbenzene will be formed, while in the second reaction, 1,2-dibromoethylbenzene will be formed.
To learn more about Electrophilic aromatic substitution refer to the link: https://brainly.com/question/14908357
#SPJ11
calculate the change in ph when 7.00 ml of 0.100 m hcl(aq) is added to 100.0 ml of a buffer solution that is 0.100 m in nh3(aq) and 0.100 m in nh4cl(aq). consult the table of ionization constants as needed.
When 7.00 mL of 0.100 M HCl(aq) is added to 100.0 mL of a buffer solution that is 0.100 M in NH3(aq) and 0.100 M in NH4Cl(aq), the pH of the solution decreases by 0.24.
This is because the added acid increases the total concentration of H+ ions in the solution, resulting in a lower pH.
When 7.00 mL of 0.100 M HCl(aq) is added to 100.0 mL of a buffer solution that is 0.100 M in NH3(aq) and 0.100 M in NH4Cl(aq),
the change in pH will depend on the relative amounts of acid and base present in the buffer solution.
In order to calculate the change in pH, we must consider the acid dissociation constants (Ka) for both the NH3 and NH4Cl, as well as the total amount of base and acid in the buffer solution.
The Ka value for NH3 is 1.8 x 10^-5, and the Ka value for NH4Cl is 5.6 x 10^-10.
To calculate the change in pH, we must first calculate the concentrations of the two species present in the buffer solution after 7.00 mL of 0.100 M HCl is added.
The total volume of the solution after the addition of the acid is 107.00 mL. This means that the NH3 concentration is 0.093 M and the NH4Cl concentration is 0.093 M.
Using the Ka values, we can then calculate the total amount of H+ ions present in the solution. This is equal to (1.8 x 10^-5)x(0.093) + (5.6 x 10^-10)x(0.093) = 1.71 x 10^-5.
Using the H+ concentration, we can then calculate the pH of the solution using the formula pH = -log[H+].
In this case, the pH of the solution is equal to 4.76. This means that the change in pH is equal to -0.24, as the original pH of the buffer solution was 5.00.
To know more about buffer solution refer here:
https://brainly.com/question/24262133#
#SPJ11
if a gas is colder than its critical temperature, less pressure is required to liquefy it. true false
The statement, "if a gas is colder than its critical temperature, less pressure is required to liquefy it," is true.
The critical temperature is the temperature at which a gas can't be condensed into a liquid through an increase in pressure alone.
If the temperature exceeds the critical temperature, the gas can only exist as a gas regardless of the pressure applied, and no amount of pressure can cause the gas to condense into a liquid at or above the critical temperature.
A gas is typically liquefied by increasing the pressure and reducing the temperature.
A gas can be condensed into a liquid by reducing the pressure or increasing the temperature if the gas is below its critical temperature.
If the gas is above the critical temperature, no amount of pressure can cause it to liquefy. When a gas is below its critical temperature, less pressure is required to liquefy it.
The relationship between pressure and temperature can be shown using a phase diagram.
A phase diagram is a graph of pressure versus temperature that shows the conditions under which different phases of a substance can exist. The critical temperature is depicted as a point on a phase diagram.
Above the critical temperature, there is no distinction between the gas and liquid phases. Below the critical temperature, the liquid and gas phases can coexist at a specific pressure known as the vapor pressure.
As a result, to liquefy a gas, the pressure must be raised above the vapor pressure at a temperature below the critical temperature. Therefore, if a gas is colder than its critical temperature, less pressure is required to liquefy it.
to know more about temperature refer here:
https://brainly.com/question/11464844#
#SPJ11
when 0.0400 mol koh is added to 1.0 l of a solution that is 0.25 m in nh3 and 0.20 m in nh4no3, the ph increases only slightly. which statement best explains this? g
When 0.0400 mol KOH is added to 1.0 L of a solution that is 0.25 M in NH3 and 0.20 M in NH4NO3, the pH increases only slightly.
The statement that best explains this is that the weak acid (NH4+) will combine with OH- to create a weak base (NH3). Explanation: NH3(aq) + H2O(l) ⇌ NH4+(aq) + OH–(aq)The ammonium ion (NH4+) acts as a weak acid that combines with hydroxide ion (OH–) to form ammonia (NH3) and water (H2O).
It is important to remember that ammonia is not strong enough to raise the pH significantly and that ammonium is a weak acid that won't produce a lot of hydroxides. Therefore, the pH change will be negligible. The explanation for the above reaction is as follows: NH4+ + OH– ⇌ NH3 + H2O In this equilibrium, the weak acid (NH4+) will combine with OH– to create a weak base (NH3), resulting in the pH not rising significantly.
You can read more about molarity at https://brainly.com/question/30404105#:
#SPJ11
the given carboxylic acid is reduced via reaction with excess lithium aluminum deuteride. assume that the appropriate acidic workup is performed following this reduction. the final product(s) would best be described as:
The given carboxylic acid is reduced via reaction with excess lithium aluminum deuteride. The appropriate acidic workup is performed following this reduction. The final product(s) would best be described as an alcohol.
Lithium aluminum deuteride is a powerful reducing agent used in organic chemistry. Lithium aluminum deuteride is an odorless, white crystalline powder that is soluble in tetrahydrofuran (THF) and diethyl ether (Et2O). It is often utilized as a source of deuterium. When heated, it emits hydrogen and deuterium. Lithium aluminum deuteride (LiAlD4) is a lithium salt of aluminum hydride with deuterium. It is a strong reducing agent and is frequently utilized in organic synthesis.
The process of adding an electron or hydrogen to a substance is known as reduction, and it is the opposite of oxidation. During the reaction of a carboxylic acid with lithium aluminum deuteride, the carbonyl group (C=O) is reduced to an alcohol (R–OH). Acidic workup is used to quench the reaction and neutralize the unreacted reagent after the lithium aluminum deuteride has reduced the carbonyl group in a carboxylic acid.
Carboxylic acids are a class of organic compounds with a carboxyl functional group that consists of a carbonyl group and a hydroxyl group. Acetic acid, formic acid, and butyric acid are examples of common carboxylic acids. The formula R–COOH is used to represent them. The acidity of carboxylic acids is due to the presence of the acidic proton in the hydroxyl group. The hydrogen ion, H+, is generated when the proton is dissociated.
Learn more about reduction at:
https://brainly.com/question/30451902
#SPJ11
a cholesterol sample is prepared using acetyl coa molecules in which both the methyl group and the carboxyl functional group of the acetyl are radiolabeled with 14c. in the cholesterol product, the 14c label would appear:
A cholesterol sample is prepared using acetyl CoA molecules in which both the methyl group and the carboxyl functional group of the acetyl are radiolabeled with 14c. In the cholesterol product, the 14C label would appear in the acetate component.
Cholesterol is a waxy substance that your liver produces and is found in animal-based foods. Cholesterol is crucial for the functioning of your body. It helps your body produce hormones, vitamin D, and bile acids, which aid in the digestion of fat. However, having too much of it in your blood raises your risk of heart disease and stroke. 14C is a radiolabeled carbon isotope. Isotopes are variants of the same element that have a different number of neutrons. Carbon-14 (14C) is an isotope of carbon that has 6 protons and 8 neutrons in its nucleus. In the cholesterol product, the 14C label would appear in the acetate component.
Learn more about cholesterol at https://brainly.com/question/841110
#SPJ11
how would your calculations of the concentration of [fescn]2 been affected if the cuvette you used had a 1.5 cm path length rather than the 1.0 cm value you were told to use?
The increased distance across the cell will result in an increase absorbance reading.
The concentration of [tex][Fescn]_2[/tex] would be affected if the cuvette had a 1.5 cm path length rather than the 1.0 cm value used.Since the absorbance of a sample is proportional to the concentration of a sample (as described by the Beer-Lambert law), increasing the path length of the cuvette would result in a decrease in absorbance. This means that the concentration of the sample would be lower than if the 1 cm path length was used. In other words, the concentration of [tex][Fescn]_2[/tex]would be lower if the cuvette had a 1.5 cm path length than if it had a 1.0 cm path length.
learn more about cuvette Refer:brainly.com/question/29385690
#SPJ1
how much water do you need to add to 10 ml of a solution of hcl with a ph of 2 to change the ph to 4?
NaOH is a strong base and completely dissociates in water. The number of moles of NaOH will be equal to the number of moles of H+ ions neutralized. Hence, 99 ml of NaOH must be added.
It measures the acidity or basicity of a solution on a scale of 0 to 14. A pH of 7 is neutral, and anything below 7 is acidic, and anything above 7 is basic.
When pH is increased or decreased by one unit, it means a ten-fold decrease or increase in hydrogen ion concentration in a solution.Acid and base are two essential terms to learn here.
An acid is a chemical compound that donates H+ ions in a solution, whereas a base is a chemical compound that accepts H+ ions. These H+ ions determine the acidity of the solution.
The more H+ ions a solution has, the more acidic it is, and the fewer H+ ions a solution has, the more basic it is. A pH of 2 indicates that the solution is highly acidic.
To change the pH of the given solution from 2 to 4, we need to make the solution less acidic, which means we need to add a base to it.
Let the volume of the base we need to add be x ml.The pH of the new solution will be 4. We can write the pH equation as pH = -log[H+], where [H+] represents the concentration of H+ ions.
The concentration of H+ ions in the initial solution is:2 = -log[H+]. Hence, [H+] = 0.01 M.The concentration of H+ ions in the final solution is:4 = -log[H+].
Hence, [H+] = 0.0001 M.We know that[H+] = Acid concentration = Base concentration.Hence, the concentration of NaOH added to the solution will be 0.01 M - 0.0001 M = 0.0099 M.
NaOH is a strong base and completely dissociates in water. So, the number of moles of NaOH will be equal to the number of moles of H+ ions neutralized.
The volume of NaOH needed to achieve this concentration:0.0099 mol/L = n NaOH / V NaOHn NaOH = 0.0099 mol/L x (10 mL + x) = 0.099 molV NaOH = n NaOH / 0.1 mol/L = (0.0099 mol) / (0.1 mol/L) = 0.099 L = 99 ml
Hence, 99 ml of NaOH must be added to 10 ml of a solution of HCl with a pH of 2 to change the pH to 4.
to know more about neutralized refer here:
https://brainly.com/question/27891712#
#SPJ11
to what volume (in ml) would you need to dilute 45.0 ml of a 1.20 m solution of nabr to make a 0.0400 m solution of nabr?
To dilute 45.0 ml of a 1.20 M solution of NaBr to a 0.0400 M solution, you need to add enough water to a total volume of 226.25 ml.
The dilution formula is M1V1 = M2V2, where M1 and V1 are the initial molarity and volume of the solution and M2 and V2 are the desired molarity and volume of the dilute solution.
Calculate V2 (the desired volume) by rearranging the equation and solving for V2: V2 = (M1V1) / M2.
V2 = (1.20M * 45.0ml) / 0.0400M = 226.25ml.
Therefore, to create a 0.0400 M solution of NaBr from a 1.20 M solution of NaBr, you need to add enough water to a total volume of 226.25 ml.
to know more about solution refer here:
https://brainly.com/question/30665317#
#SPJ11
Which of the following best explains why doubling the temperature of a gas in a closed container caused the pressure to be doubled?
The correct option is: Increasing the temperature increases the frequency and force of collisions between gas molecules and the container walls, causing the pressure to increase.
What happens when temperature of a gas increasedWhen the temperature of a gas in a closed container is increased, the gas molecules gain kinetic energy and move faster, colliding with the container walls more frequently and with greater force.
According to the kinetic theory of gases, the pressure of a gas is directly proportional to the frequency and force of collisions between gas molecules and the container walls.
Therefore, doubling the temperature of a gas in a closed container would also double the pressure of the gas.
Learn more about gas laws at:
https://brainly.com/question/25290815
#SPJ1
the atomic electron configuration inflluences the resulting mechanical properties of the material true false
The statement "the atomic electron configuration influences the resulting mechanical properties of the material" is TRUE. The way the electrons are arranged in the atom affects the way atoms interact with each other through forces such as Van der Waals forces.
An atom's electron configuration is a representation of the electrons' position within the atom's energy levels or shells. The quantity of electrons in an atom's outermost shell affects the atom's reactivity or chemical properties. As a result, the atomic electron configuration has an impact on the resulting mechanical properties of the material.
How does atomic electron configuration influence the mechanical properties of materials?
The atomic electron configuration influences the mechanical properties of materials in the following ways:
Brittleness or ductility: Brittle materials are more fragile and break more easily than ductile materials, which are more pliable and less prone to break. The distance between the electrons in the outer shell has an impact on the ductility of a material.Malleability: The ability to deform a material without fracturing it is referred to as malleability. The malleability of a material is influenced by its electron configuration, particularly the number of electrons in the outermost shell.Elasticity: The capacity of a material to return to its original shape after being deformed is referred to as elasticity. The atomic electron configuration, particularly the number of electrons in the outer shell, affects the material's elasticity. The more electrons there are, the greater the material's elasticity.For more questions related to atomic electron configuration .
https://brainly.com/question/29757010
#SPJ11
which substances are strong acids? [select all that apply] group of answer choices hf hi hcl h2so4 hno3 hbr hclo hclo2 hclo3 hclo4 h2s ch3cooh h3po4 nh3 nh4cl koh fecl3 h2n2 ca(oh)2 ch3nh2
Strong acids are substances that have a high affinity for protons, meaning that they can donate or accept protons in order to form an acid-base equilibrium. The following substances are strong acids: HF, HI, HCl, H2SO4, HNO3, HBr, HClO, HClO2, HClO3, HClO4, H2S, CH3COOH, H3PO4, NH3, NH4Cl, KOH, FeCl3, H2N2, Ca(OH)2, and CH3NH2.
HF is a hydrogen halide and is the strongest of the acids listed above. It is used in industrial applications as a strong oxidizing agent. HI is another hydrogen halide, and it is used in the production of organic compounds. HCl, also known as hydrochloric acid, is a strong acid that is commonly used in the chemical industry. H2SO4 is a strong mineral acid used in the production of fertilizers and dyes.
HNO3 is a strong oxidizing agent and is used in the production of fertilizers and explosives. HBr is a strong acid used in the production of organic compounds. HClO, HClO2, HClO3, and HClO4 are strong oxidizing agents that are used in the chemical industry.
Know more about Strong acids here:
https://brainly.com/question/16749233
#SPJ11
11. for a molecule with two atoms, what is the electronegativity difference when there is no bond dipole?
Answer: A molecule with two atoms, the electronegativity difference when there is no bond dipole is zero.
This is because there is no bond dipole when there is no difference in the electronegativity of the two atoms forming the molecule.
What is Electronegativity?The ability of an atom to draw electrons towards itself in a molecule is known as electronegativity. Electronegativity can be used to predict the formation of bonds between atoms. A difference in electronegativity between two atoms determines the type of bond formed. T
he greater the difference in electronegativity, the greater the bond polarity. This results in a partial positive charge on the atom with lower electronegativity and a partial negative charge on the atom with higher electronegativity. Bond Dipole in a polar molecule, the electrons spend more time around the atom with the greater electronegativity.
This results in a partial negative charge on this atom and a partial positive charge on the other atom. The separation of these partial charges produces a dipole known as a bond dipole. When two atoms in a molecule have the same electronegativity, the bond is non-polar and there is no bond dipole.
Learn more about electronegativity here:
https://brainly.com/question/17762711#
#SPJ11
1. personal connections describe your reaction to the events in act i. why might you want to continue reading? explain.
Readers may want to continue reading a work if they are intrigued by the characters, interested in the plot, or invested in the themes and messages presented.
Why will a reader continue reading?
In general, act sets the stage for the rest of the work, introducing key characters, establishing conflicts, and setting the tone and mood.
If a reader finds these elements compelling or engaging, they may be motivated to continue reading to see how the story unfolds and how the characters develop. Additionally, Act I may introduce questions or mysteries that pique the reader's curiosity and encourage them to keep reading to find the answers.
Thus, a reader may want to continue reading a work if they are in interested in the plot.
Learn more about reading here: https://brainly.com/question/24716030
#SPJ1
adding this test solution will precipitate sulfate ions: select one: a. naoh b. bacl2 c. hno3 d. nh4cl
Answer: The solution that will precipitate sulfate ions is B. BaCl2.
How do you test for sulfate ions?
The most reliable test for sulfate ions is to add a few drops of barium chloride to the test solution. If sulfate ions are present, they will combine with the barium ions to create a white precipitate of barium sulfate.
In the presence of barium ions, sulfuric acid is added to the test solution to look for the sulfate ions that are there. A white precipitate of barium sulfate is formed as a result of the reaction.
The production of a white precipitate of barium sulfate means that sulfate ions are present. In order to eliminate carbonates and other anions, the test solution should be treated with a few drops of dilute hydrochloric acid before testing.
Learn more about Barium chloride here:
https://brainly.com/question/14444265#
#SPJ11
What product is formed when the compound is treated with Tollens reagent (Ag2O,NH4OH) ? With some compounds, no reaction occurs. If no reaction occurs, draw the reactant.
The product that will be formed by the oxidation using Ag2O,NH4OH is CH3(CH2)4COOH.
How are primary alcohols oxidized using Ag2O?Primary alcohols can be oxidized to aldehydes or carboxylic acids using silver(I) oxide (Ag2O) as an oxidizing agent in the presence of water (H2O) and heat. The reaction proceeds as follows:
RCH2OH + [O] → RCHO + H2O (aldehyde formation)
or
RCH2OH + 2[O] → RCOOH + H2O (carboxylic acid formation)
where R is an alkyl group.
In this reaction, the silver(I) oxide acts as a source of oxygen, which is required for the oxidation of the alcohol. The oxygen is transferred to the alcohol, forming a carbonyl group (C=O) in the aldehyde or carboxylic acid product.
Learn more about alcohols:https://brainly.com/question/30829120
#SPJ1
A sample of ideal gas occupies 208ml at 36. 2 degree celsius and 704 torr what is the volume at stp
At Standard Temperature and Pressure (STP) the volume of the gas at is 216.1 ml.
A sample of ideal gas occupies 208ml at 36.2 degree Celsius and 704 torr what is the volume at stp
For a sample of ideal gas, the relationship between volume, pressure, and temperature is given by the Ideal Gas Law:
PV = nRT
Where P is the pressure of the gas, V is the volume of the gas, n is the number of moles of the gas, R is the universal gas constant, and T is the temperature of the gas.
At STP (Standard Temperature and Pressure), the pressure of the gas is 1 atm and the temperature of the gas is 0°C (273 K). Therefore:
P1 = 704 torr
V1 = 208 mL
T1 = 36.2°C = 309.35 K
P2 = 1 atm
V2 = ?
T2 = 0°C = 273 K
To find V2, we can use the following equation:
V2 = V1(P2/P1)(T1/T2)
Plugging in the given values:
V2 = 208 mL (1 atm/704 torr) (309.35 K/273 K)
V2 = 208 mL (0.939) (1.132)
V2 = 216.1 mL
For more such questions on Standard Temperature and Pressure, click on:
https://brainly.com/question/14820864
#SPJ11
which of the methods can be used to improve the resolution between two compounds for a liquid separation using a packed chromatography column?
High-performance liquid chromatography (HPLC) is the method used.
The process of chromatography separates mixtures into their constituents by distributing the constituents of a mixture between two phases: a stationary phase and a mobile phase.
Separation is based on the differential partitioning of analytes between these two phases.
The resolution of a chromatographic separation is a function of the differences in retention times and peak widths between two peaks of interest.
The resolution between two compounds for a liquid separation using a packed chromatography column can be improved using several methods.
Here are some of the methods that can be used to improve the resolution between two compounds for a liquid separation using a packed chromatography column:1.
Using a smaller particle size. A smaller particle size stationary phase decreases HETP and broadens the range of flow rates that can be used for a separation, providing higher resolution.2.
Increasing the length of the column. A longer column provides a larger surface area, more separation can occur, and thus higher resolution can be obtained.3. Changing the particle size distribution.
Changing the particle size distribution of the stationary phase can result in a greater variation of pore sizes, resulting in a greater variety of interactions between the analytes and the stationary phase.
This leads to an increase in resolution.4. Changing the solvent or buffer system. Altering the solvent or buffer system to optimize the separation conditions can result in an increase in resolution.
Solvent changes, pH changes, or changing the ionic strength of the buffer system can be used.5. Modifying the temperature.
Modifying the temperature can affect the degree of analyte interaction with the stationary phase, thereby affecting the separation.
It is also necessary to note that liquid chromatography, which is frequently referred to as high-performance liquid chromatography (HPLC),
has a variety of advantages over gas chromatography (GC), which are better suited for volatile or small molecular weight analytes.
to know more about chromatography refer here:
https://brainly.com/question/30907934#
#SPJ11
suppose you want to prepare a buffer with a ph of 4.42 using formic acid. what ratio of [sodium formate]/[formic acid] do you need to make this buffer? formic acid has a ka of 1.8x10-4.
This ratio shows that to prepare a buffer with a pH of 4.42 using formic acid, you require the ratio of [sodium formates]/[formic acid] to be 49.23:1.
Explanation:
To prepare a buffer with a pH of 4.42 using formic acid, you need to determine the ratio of [sodium formate]/[formic acid].
A buffer solution is a solution that can resist changes in pH, even when subjected to acid or base. The buffer solution comprises a weak acid or a weak base with its conjugate base or acid, respectively.
Suppose you want to prepare a buffer with a pH of 4.42 using formic acid, with a Ka of 1.8x10^-4. Find the ratio of [sodium format]/[formic acid]. Here, we can use the Henderson-Hasselbalch equation, which is:
pH = pKa + log ([A-] / [HA])
Here, [A-] represents the conjugate base concentration, and
[HA] represents the weak acid concentration.
Rearranging the above equation gives:
log([A-]/[HA]) = pH - pKa putting values gives:
log([A-]/[HA]) = 4.42 - (-log 1.8x10^-4) lo([A-]/[HA]) = 4.42 + 3.74log([A-]/[HA]) = 8.16log([A-]/[HA]) = 1.74
Now, taking antilog of both sides: [A-]/[HA] = 10^1.74[A-]/[HA] = 49.23:1
This ratio shows that to prepare a buffer with a pH of 4.42 using formic acid, you require the ratio of [sodium formate]/ [formic acid] to be 49.23:1.
To know more about Formic acid, refer here:
https://brainly.com/question/28169167#
#SPJ11
PLEASE HELPPPP asapppppppppp
a solution made up of 40% alcohol by volume is mixed with 4 liters of solution that is 10% alcohol by volume. how much, in liters, of the 40% alcoholic solution is needed to make a mixture that is 25% alcohol by volume?
The volume, in liters, of the 40% alcoholic solution needed to make a mixture that is 25% alcohol by volume is 4 L.
To find the amount of 40% alcoholic solution needed to make a mixture that is 25% alcohol by volume, we need to use the following formula:
C₁V₁ + C₂V₂ = CfVf
where C₁ is the concentration of the first solution, V₁ is the volume of the first solution, C₂ is the concentration of the second solution, V₂ is the volume of the second solution, Cf is the desired concentration of the resulting mixture, and Vf is the volume of the resulting mixture.
In this case, we know the first solution is 40% alcohol by volume and the second solution 10% alcoholic by volume, and we need to make a mixture that is 25% alcoholic by volume. We need to know the volume of the first solution, V₁.
Plugging in the values, we get:
C₁V₁ + C₂V₂ = CfVf
0.40V₁ + (0.10)(4) = (0.25)(4 + V₁ )
Solving for the value of V₁, we get:
0.40V₁ + 0.40 = 1 + 0.25V₁
0.15V₁ = 0.60
V₁ = 4
Therefore, 4 liters of the first solution is needed.
Learn more about mixture here: https://brainly.com/question/11868977
#SPJ11
1. What particles determine the mass number?
2. Why is mass number always a whole number?
3. One isotope of carbon (C) has exactly the same mass number and atomic mass since it was used as the definition of the atomic mass unit (amu). Which isotope is it and what is its atomic mass?
4. What is the approximate mass of one proton? __________amu
5. What is the approximate mass of one neutron? __________amu
The mass number of an atom is determined by the total number of protons and neutrons in its nucleus.
The mass number is always a whole number because it is the sum of the number of protons and neutrons in the nucleus, and both of these particles have a mass of approximately 1 atomic mass unit (amu). Since the mass of an electron is much smaller compared to protons and neutrons, it is not included in the calculation of the mass number.
The isotope of carbon that has the same mass number and atomic mass is carbon-12. Its atomic mass is exactly 12 amu.
The approximate mass of one proton is 1 amu.
The approximate mass of one neutron is also 1 amu.
write an equation showing how the mass of the substance sought can be derived from the mass of the weighed substance on the right.
What is the key bond being formed in a Grignard reaction? A. Carbon-Magnesium B. Magnesium-Bromine
C. Carbon-Carbon D. Carbon-Oxygen
Answer:
carbon-magnesium
Explanation:
H3C - Mg - Br
write the balanced chemical equation for the gas-phase production of ammonia from elemental nitrogen and hydrogen
The balanced chemical equation for the gas-phase production of ammonia from elemental nitrogen and hydrogen is:
N2 + 3H2 → 2NH3
This equation represents the reaction of nitrogen molecules, N2, with hydrogen molecules, H2, to form ammonia molecules, NH3. This reaction occurs when nitrogen and hydrogen gases are combined in a 1:3 ratio, in other words, one nitrogen molecule reacts with three hydrogen molecules to produce two ammonia molecules. This reaction is endothermic, meaning energy must be supplied for it to occur.
In general, this reaction is carried out at high temperatures and pressures, often at around 400-600°C and up to 200atm. A catalyst is usually also used, usually iron, to speed up the reaction. In the presence of a catalyst, the reaction rate can increase by a factor of thousands compared to a reaction without a catalyst.
Overall, the balanced chemical equation for the gas-phase production of ammonia from elemental nitrogen and hydrogen is:
N2 + 3H2 → 2NH3
To know more about catalyst click on below link :
https://brainly.com/question/24430084#
#SPJ11
Which of the following contains less solute at a given temperature and pressure ?
unsaturated solution or saturated solution .
The one contains the less solute at the given temperature and the pressure is the unsaturated solution.
The unsaturated solution is the solution that contains the less solute than the saturated solution at the given temperature and the pressure. The Unsaturated solutions are the solutions in which the amount of the dissolved solute is the less than the saturation point of solvent.
If the amount of the dissolved solute will be equal to the saturation point of solvent, then the solution is called the saturated solution. The solution in the which the solute can further to be dissolved at the any fixed temperature is called the unsaturated solution.
To learn more about solution here
https://brainly.com/question/14591590
#SPJ4