The body is capable of manufacturing all of the amino acids it needs but it must have sufficient energy to be able to do so.True or False

Answer:

In order is 2, 3, 4, 1

Explanation:

It starts when you come into contact with a trigger that you inhale, swallow, or get on your skin. In response, your body starts to make a protein called IgE, which grabs onto the allergen. Then histamine and other chemicals get released into the blood.

Answer: Because its dissolution is exothermic

Explanation:

The dipeptide structure with labels a through d represents the different functional groups and atoms present in the molecule.

Label a is located at the end of the molecule with the positively charged NH3 group, indicating the presence of an amino group. The b label is placed by the bond between the carbonyl group and the amine, indicating the presence of a peptide bond.

Label c is next to a carbon with shown single bonds to the carboxylate, a CH2OH, and the rest of the molecule, indicating the presence of a side chain. Finally, the d label is next to the carboxylate at the end of the molecule,

indicating the presence of a carboxylic acid functional group. Understanding the different functional groups and atoms present in the dipeptide structure is important in understanding its properties and behavior in chemical reactions and biological processes.

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Molarity (M) is a unit of concentration that expresses the amount of solute dissolved in a solution. It is defined as the number of moles of solute present per liter of solution (mol/L).

Molarity is commonly used in chemistry to express the concentration of a solute in a solution and is typically represented as moles of solute per liter of solution (mol/L or mol L^-1). Molarity is used to describe the concentration of a solution and is important in various calculations involving chemical reactions and solutions.

To calculate molarity, follow these steps:
1. Determine the number of moles of solute in the solution.
2. Measure the volume of the solution in liters.
3. Divide the moles of solute by the volume of the solution in liters.

Molarity = moles of solute/liters of solution

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Molarity is a unit of concentration in chemistry. It is defined as the number of moles of solute per liter of solution. In other words, it measures the amount of substance (in moles) dissolved in a given volume of solution (in liters). the left column contains "molarity," "moles," and "liters," and the sentences.

To match the items in the left column to the appropriate blanks in the sentences on the right, we can use the following:
- Molarity: a unit of concentration in chemistry
- Number of moles: the amount of substance dissolved in a solution
- Liter of solution: the volume in which the substance is dissolved
- Solvent: the substance in which the solute is dissolved
- Solute: the substance that is dissolved in a solvent to make a solution

So the sentences could be:
- Molarity is a unit of concentration in chemistry that measures the amount of substance (in moles) dissolved in a given volume of solution (in liters).
- The number of moles of solute per liter of solution is known as molarity.
- A liter of solution is the volume in which the solute is dissolved to make a solution with a certain molarity.
- A solvent is a substance in which a solute is dissolved to make a solution of a certain molarity.
- A solute is a substance that is dissolved in a solvent to make a solution of a certain molarity.
Hello! Molarity is a measure of the concentration of a solute in a solution, expressed as moles of solute per liter of solution. To match items in the left column to the appropriate blanks in the sentences on the right, follow these steps:

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In changing the size of the zinc electrode would not impact the voltage of the cell.

If the size of the zinc electrode were doubled, the cell voltage would stay the same. This is because the voltage of a cell is dependent on the difference in potential between the two electrodes, not their size.

Doubling the size of the zinc electrode would not change the potential difference between the zinc and copper electrodes, therefore the cell voltage would remain constant.

The only factor that would affect the cell voltage would be a change in the concentration or temperature of the electrolyte solution or a change in the material or surface area of the copper electrode.

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The best describes her speed and velocity is; Her speed is 4. 4 m/s, and her velocity will be 0 m/s. Option A is correct.

Lila's speed will be calculated by dividing the total distance she covered by  time it took her to complete the race;

Speed = Total distance/Time

In this case, Lila will covered 4 laps, which is a total distance of 4 x 400 = 1600 meters. She completed the race in 6 minutes, which is 6 x 60 = 360 seconds. Therefore, her speed is;

Speed = 1600 meters / 360 seconds

Speed = 4.44 m/s (rounded to two decimal places)

Velocity, on the other hand, is a vector quantity that takes into account both speed and direction. Since Lila ran four laps around a circular track, she ended up at the same position where she started. However, her displacement (change in position) is zero, which means her velocity is also zero.

Hence, A. is the correct option.

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--The given question is incomplete, the complete question is

"Lila is a track and field athlete. She must complete four laps around a circular track. The track itself measures 400 meters from start to finish and the race took her 6 minutes to complete. Which best describes her speed and velocity? A) Her speed is 4. 4 m/s, and her velocity is 0 m/s. B) Her speed is 1. 1 m/s, and her velocity is 0 m/s. C) Her speed is 0 m/s, and her velocity is 2400 m/s. D) Her speed is 4. 4 m/s, and her velocity is 4. 4 m/s"--

The atmospheric pressure on top of Mt. Everest is 250 mmHg and 0.328 atm, when rounded to 3 significant digits.

Pressure is a force that is exerted over a surface area. It is the amount of force applied to an object per unit area. Pressure is typically expressed in units of force per unit of area, such as pounds per square inch (psi) or pascals (Pa). Pressure is an important factor in many areas of engineering, physics, chemistry, and biology.

Atmospheric pressure can be measured in torr (1 Torr = 1mmHg), atm (1 atm = 760mmHg) or in kPa (1 atm = 101.3kPa).
250 torr = 250 mmHg
250 mmHg / 760 mmHg = 0.328 atm

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If a glass manufacturer has only a few costly ways of reducing pollutants, it will end up paying the pollution tax, option A.

A chemical or energy that is introduced into the environment and has negative consequences or reduces the usability of a resource is referred to as a pollutant or new entity. These can be either anthropogenic in origin (i.e., produced materials or results of biodegradation) or naturally formed (i.e., minerals or extracted chemicals like oil). When pollutants are present in sufficient quantities to have noticeable detrimental effects on the environment or public health, pollution results.

By altering the development rate of plant or animal species, or by affecting human amenities, comfort, health, or property values, a pollution may inflict long- or short-term damage.

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Complete question:

If a glass manufacturer has only a few ________________ of reducing pollutants, it will ____________________ .

A. costly ways; end up paying the pollution tax.

B. inexpensive ways; incur the pollution tax instead.

C. costly ways; do so to minimize its pollution taxes.

D. inexpensive ways; buy the most expensive technology.

A sample of [tex]Br_2[/tex](g) takes 14.0 min to diffuse out through a membrane. It would take 7 min for the same number of moles of Ar(g) to effuse through the same membrane.

According to Graham's Law of Diffusion, it is known that the rate of diffusion of a gas is proportional to the reciprocal of the square root of the molar mass of the gas. The rate of diffusion is recorded under the same pressure and temperature conditions.

It can be written as [tex]\frac{r_1}{r_2}[/tex] ∝ [tex]\sqrt\frac{m_2}{m_1}[/tex]

where [tex]r_1[/tex] is the rate of diffusion of one of the gas

[tex]r_2[/tex]  is the rate of diffusion of the second gas

[tex]r_1[/tex] is the molar mass of one of the gas

[tex]m_2[/tex]  is the molar mass of the second gas

According to the question,

[tex]\frac{14}{r_2}=\sqrt\frac{160}{40}\\\frac{14}{r_2}=\sqrt\frac{4}{1} \\\\r_2 = 14\sqrt{\frac{1}{4} } = 7[/tex]

Therefore the time taken for the diffusion of Ar (g) is 7 min

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It would take approximately 7.0 minutes for the same number of moles of Ar(g) to effuse through the same membrane.

Using Graham's law of effusion, we can compare the rates of effusion for Br2(g) and Ar(g). The formula for Graham's law is:

Rate₁ / Rate₂ = √(M₂ / M₁)

Here, Rate₁ and Rate₂ are the effusion rates of the two gases, and M₁ and M₂ are their molar masses. In this case, Br2(g) is gas 1 and Ar(g) is gas 2. The molar mass of Br2 is 159.8 g/mol, and the molar mass of Ar is 39.95 g/mol.

Since we know the time it takes for Br2 to effuse, we can write:

Time₁ / Time₂ = Rate₂ / Rate₁ = √(M₁ / M₂)

Plugging in the given time and molar masses:

14.0 min / Time₂ = √(159.8 g/mol / 39.95 g/mol)

Solving for Time₂:

Time₂ = 14.0 min * √(39.95 g/mol / 159.8 g/mol) ≈ 7.0 min

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Answer:

data given

mass of NaCl 4.56

dissolved volume 20ml(0.02l)

density of solution 1.03g/ml

Required molality

Explanation:

molarity=m/mr×v

where

m is mass

mr molar mass

v is volume

now,

molarity=4.56/58.5×0.02

molarity =3.9

: .molarity is 3.9mol/dm^3

According to molal concentration, the concentration (in molality) of an aqueous solution of NaCl is 0.0047 mole/kg.

Molal concentration is defined as a measure by which concentration of chemical substances present in a solution are determined. It is defined in particular reference to solute concentration in a solution . Most commonly used unit for molal concentration is moles/kg.

The molal concentration depends on change in volume of the solution which is mainly due to thermal expansion. Molal concentration is calculated by the formula, molal concentration=mass/ molar mass ×1/mass of solvent in kg.

In terms of moles, it's formula is given as molal concentration= number of moles /mass of solvent in kg.

Substitution in formula gives the answer but first mass of solution is determined which  is density×volume= 1.03×20=20.6 g , mass of solvent= 20.6-4.56=16.05, thus molal concentration=4.56/58.5×1/16.05=0.0047 moles/kg.

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1) 5.1167 x 10²⁴atoms of chlorine. 2) 248.00 g. 3) 4.8825 x 10⁷ moles of helium. 4) 2.7757 x 10²⁴ atoms of sulfur.  5) Molar mass of Co (cobalt) is 58.93 g/mol.  6) Formula mass =  310.18 g/mol.

Sum of the atomic masses of all the atoms in chemical formula is called formula mass

1.)  Number of atoms = 8.500 moles x 6.022 x 10²³ atoms/mole = 5.1167 x 10²⁴ atoms of chlorine.

2.) Molar mass of oxygen is 16.00 g/mol. Therefore:

Mass of 15.50 moles of oxygen = 15.50 moles x 16.00 g/mol = 248.00 g.

3.) Molar mass of helium is 4.00 g/mol. Therefore, the number of moles of helium in 1.953 x 10⁸ g is:

Number of moles = 1.953 x 10⁸ g / 4.00 g/mol = 4.8825 x 10⁷ moles of helium.

4.) Molar mass of sulfur is 32.06 g/mol. Therefore, the number of moles of sulfur in 147.82 g is:

Number of moles = 147.82 g / 32.06 g/mol = 4.6084 moles of sulfur.

To find the number of atoms, we can use Avogadro's number again:

Number of atoms = 4.6084 moles x 6.022 x 10²³ atoms/mole = 2.7757 x 10²⁴ atoms of sulfur.

5.) Molar mass of Co (cobalt) is 58.93 g/mol.

6.) Ca₃(PO₄)₂ contains 3 calcium atoms, 2 phosphorus atoms, and 8 oxygen atoms.

Atomic masses of these elements are:

Calcium (Ca) = 40.08 g/mol

Phosphorus (P) = 30.97 g/mol

Oxygen (O) = 16.00 g/mol

Therefore, formula mass of Ca₃(PO₄)₂ is:

Formula mass = (3 x 40.08 g/mol) + (2 x 30.97 g/mol) + (8 x 16.00 g/mol)

= 120.24 g/mol + 61.94 g/mol + 128.00 g/mol

= 310.18 g/mol.

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The rate of the reaction is directly proportional to the stability of the carbocation intermediate, and any changes in the solvent will affect the rate of the reaction.

In an SN1 reaction, the rate-determining step is the formation of a carbocation intermediate. The stability of the carbocation intermediate affects the rate of the reaction.

In this case, if 2-propanol (isopropanol) was used instead of 2-methyl-2-propanol (t-butanol), the rate of the reaction would decrease. This is because the carbocation intermediate formed in 2-propanol is less stable compared to the one formed in t-butanol.

The carbocation intermediate formed in t-butanol is tertiary, which is more stable than the one formed in isopropanol, which is secondary. This means that the reaction will be slower in isopropanol due to the less stable carbocation intermediate.

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the overlap integral simplifies to:

S = c1c2 + d1d2d1d2.

To calculate the overlap integral between two linear combinations of atomic orbitals on a carbon atom in ethene, we first need to express the orbitals in terms of the hydrogen-like atomic orbitals. Let's assume that the two orbitals are denoted as ψ1 and ψ2, and can be expressed as linear combinations of the hydrogen-like atomic orbitals ϕ1 and ϕ2 as follows:

ψ1 = c1ϕ1 + d1ϕ2
ψ2 = c2ϕ1 + d2ϕ2

where c1, d1, c2, and d2 are constants.

The overlap integral between these two orbitals can be calculated using the following formula:

S = ∫ψ1ψ2*dτ

where dτ represents the infinitesimal volume element.

Substituting for ψ1 and ψ2, we get:

S = ∫(c1ϕ1 + d1ϕ2)(c2ϕ1 + d2ϕ2)*dτ

Expanding the product, we get:

S = c1c2∫ϕ1ϕ1*dτ + c1d2∫ϕ1ϕ2*dτ + d1c2∫ϕ2ϕ1*dτ + d1d2∫ϕ2ϕ2*dτ

Since the hydrogen-like atomic orbitals are orthonormal, the integral of ϕ1ϕ2 and ϕ2ϕ1 will be zero. Therefore, we can simplify the expression as follows:

S = c1c2∫ϕ1ϕ1*dτ + d1d2∫ϕ2ϕ2*dτ

Using the orthonormality of the hydrogen-like atomic orbitals, we know that the integral of ϕ1ϕ1 and ϕ2ϕ2 will both be equal to 1. Therefore, the overlap integral simplifies to:

S = c1c2 + d1d2d1d2.

In order to calculate the value of S, we need to know the values of the constants c1, d1, c2, and d2. These constants will depend on the specific linear combinations of atomic orbitals that we are considering. Without this information, we cannot calculate the value of the overlap integral.

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If two orbitals as linear combinations of two atomic orbitals on carbon atom in ethene, then value of the overlap integral [tex]S_{12} = \int{\phi_{1}}^{*}\phi_{2}d \tau[/tex], is equals to zero. So, option(b) is correct.

Orthonormal atomic orbitals are follow the following property:

Now, we have provide that two orbitals are as a linear combinations of two atomic orbitals on carbon atom in ethene. [tex]\phi_{1 } = \frac{1}{ \sqrt{2} } ( {\psi_{2s }} + {\psi_{2p }}_{2})[/tex]

[tex]\phi_{2 } = \frac{1}{ \sqrt{2} } ( \psi_{2 s} - {\psi_{2p} }_{2})[/tex]

In the ethylene molecule, consists each carbon atom is bonded to two hydrogen atoms. Therefore, for the C-H, σ bond (sp²(C) - 1s(H)) in ethylene, the two sp² hybrid orbitals overlap with the 1s orbitals of the two hydrogen atoms. Let the hydrogen-like atomic orbitals, [tex]\psi_{2 s} and {\psi_{2p} }_{2}[/tex] are orthonormal to each other. So, the overlap integral [tex]S_{12} = \int{ \phi_{1}}^{*}\phi_{2}d \tau[/tex]

[tex] = \int \frac{1}{\sqrt{2}}( \psi_{2s} + {\psi_{2p} }_{2}) \frac{1}{\sqrt{2}}( \psi_{2s} - {\psi_{2p} }_{2})d \tau\\ [/tex]

[tex] = \frac{1}{\sqrt{2}}( \int \psi_{2s}\psi_{2s} d \tau + \int {\psi_{2p} }_{2}\psi_{2s} d \tau - \int \psi_{2s} {\psi_{2p}}_{2} d \tau - \int {\psi_{2p} }_{2} {\psi_{2p} }_{2} d \tau) \\ [/tex].

Using above formula, [tex]\psi_{2 s} [/tex] and [tex]{\psi_{2p} }_{2}[/tex] are orthonormal so, [tex]\int \psi_{2 s} {\psi_{2p} }_{2} d\tau = 0[/tex]. Also [tex]\psi_{2 s} [/tex] and [tex]\psi_{2 s}[/tex] are normalised so [tex]\int \psi_{2 s} \psi_{2 s} d\tau = 1[/tex]. Similarly [tex]\int {\psi_{2p} }_{2} {\psi_{2p} }_{2} d\tau = 1 [/tex].

Substitute all integral values in equation (1),

= 1 + 0 - 0 - 1

= 0

Hence, the required integral value is 0.

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Complete question:

given two orbitals as linear combinations of two atomic orbitals on carbon atom in ethene:

[tex]\phi_{1 } = \frac{1}{ \sqrt{2} } ( {\psi_{2s }} + {\psi_{2p }}_{2})[/tex]

[tex]\phi_{2 } = \frac{1}{ \sqrt{2} } ( \psi_{2 s} - {\psi_{2p} }_{2})[/tex]

where the hydrogen-like atomic orbitals are orthonormal. what is the value of the overlap integral,

[tex] S_{12} = \int \phi_{1} \times \phi_{2}dr[/tex]

a) 1

b) 0

c) 1.5

d) 2

When lactic acid accumulates, the compensatory mechanism initially triggered to maintain acid-base balance is the respiratory system. It increases the rate and depth of breathing to eliminate more carbon dioxide, which helps reduce acidity and restore pH balance in the body.

As lactic acid accumulates, the compensatory mechanism that is initially triggered to maintain acid-base balance is increased ventilation or hyperventilation. This is because the increased ventilation leads to a decrease in carbon dioxide (CO2) levels in the blood, which helps to offset the acidic effects of lactic acid accumulation. This is a temporary compensatory mechanism, however, as the body will eventually need to eliminate the excess lactic acid through other means such as metabolism and excretion.

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The root mean square speed of F2 Gas molecules under the same conditions is approximately 582.19 m/s

Given: Average kinetic energy (E_k) = 6430 J/mol
Molar mass of F2 = 2 * Molar mass of F = 2 * 19 g/mol = 38 g/mol (since F has a molar mass of 19 g/mol)

First, let's convert the molar mass of F2 from grams to kilograms:
Molar mass of F2 = 38 g/mol * (1 kg/1000 g) = 0.038 kg/mol

Now, we can use the equation for the average kinetic energy to determine the root mean square speed (v_rms):

E_k = (3/2) * R * T = (1/2) * m * v_[tex]rms^{2}[/tex]

Where R is the universal gas constant (8.314 J/mol K) and T is the temperature in Kelvin.

Since we want to find v_rms, we can rearrange the equation as follows:

v_[tex]rms^{2}[/tex] = (2 * E_k) / m

Plugging in the given values:

v_[tex]rms^{2}[/tex] = (2 * 6430 J/mol) / 0.038 kg/mol = 338947.37[tex]m^{2}/ s^{2}[/tex]

Finally, we take the square root to find the root mean square speed: a

v_rms = √338947.37[tex]rms^{2}[/tex] = 582.19 m/s

So, the root mean square speed of F2 gas molecules under the same conditions is approximately 582.19 m/s.

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Answer:

Propyl methanoate

Explanation:

The ester that can be synthesized from propanol and methanoic acid is propyl methanoate (also known as methyl propanoate or propyl formate). The reaction between propanol and methanoic acid, which is a carboxylic acid, is a classic example of an esterification reaction, which results in the formation of an ester and water.

The value of Kp at 90°C is zero. This indicates that the decomposition of baking soda at this temperature is essentially complete, and the equilibrium lies far to the right.

We can use the expression for the equilibrium constant Kp, which is given by:

Kp = (P([tex]CO_{2}[/tex] ) × P([tex]H_{2} O[/tex])) / (P([tex]Na_{2} CO_{3}[/tex] ))

where P([tex]CO_{2}[/tex]), P([tex]H_{2} O[/tex]), and P([tex]Na_{2} CO_{3}[/tex]) are the partial pressures of carbon dioxide, water vapor, and sodium carbonate, respectively, at equilibrium.

From the balanced equation, we know that for every 2 moles of [tex]NaHCO_{3}[/tex]that decompose, 1 mole of [tex]CO_{2}[/tex] is produced. Therefore, the partial pressure of [tex]CO_{2}[/tex] can be calculated as:

P([tex]CO_{2}[/tex] ) = (1/2) × (total pressure) = 0.2726 atm

Similarly, for every 2 moles of [tex]NaHCO_{3}[/tex] that decompose, 1 mole of Na2CO3 is produced. Therefore, the partial pressure of [tex]Na_{2} CO_{3}[/tex]can be calculated as:

P([tex]Na_{2} CO_{3}[/tex]) = (1/2) × (total pressure) = 0.2726 atm

Finally, the partial pressure of water vapor can be calculated as the difference between the total pressure and the partial pressures of CO2 and [tex]Na_{2} CO_{3}[/tex]:

P([tex]H_{2} O[/tex]) = (total pressure) - P([tex]CO_{2}[/tex]) - P([tex]Na_{2} CO_{3}[/tex]) = 0.5451 - 0.2726 - 0.2726 = 0.0 atm

This means that there is no water vapor present at equilibrium, and we can assume that its partial pressure is zero. Substituting these values into the expression for Kp, we get:

Kp = (P([tex]CO_{2}[/tex]) × P([tex]H_{2} O[/tex])) / (P([tex]Na_{2} CO_{3}[/tex]))

= (0.2726 × 0.0) / 0.2726

= 0.0

Therefore, the value of Kp at 90°C is zero. This indicates that the decomposition of baking soda at this temperature is essentially complete, and the equilibrium lies far to the right.

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When an ionic compound was dissolved in 250 mL of water and the temperature of the solution increased from 25°C to 42°C, the value of ΔH is lesser than zero and has a small magnitude and the value of ΔG is also lesser than zero.

When ionic compounds dissolve in water, the ions in the solid separate and disperse uniformly throughout the solution because water molecules surround and solvate the ions, reducing the strong electrostatic forces between them. This process represents a physical change known as dissociation.

In this there is increase in temperature which means that heat energy is released which makes the dissolution exothermic and thus it has ΔH negative. Since the reaction is feasible, the ΔG will be less than zero.

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Answer:

condensation nuclei

Explanation:

When building a bridge in South America, it is important to consider the climate and terrain of the region. The company should research the area and use the most appropriate materials for the task.

Materials are substances or resources that are used to create or make something else. Examples of materials include plastics, metals, fabrics, and paper. Materials are used in the manufacturing of products, such as food, clothing, furniture, and electronics. Materials can also be found in nature, including wood, stone, and minerals. They are also used in the construction of buildings, bridges, and other structures.

For example, they should use steel or reinforced concrete to build the bridge, as these materials are highly durable in wet, humid climates. Additionally, they should make sure to use corrosion-resistant fasteners and coatings to prevent rusting. The company should also consider the seismic activity in the region when designing the bridge, as earthquakes can cause significant structural damage. They should make sure to use seismic-resistant designs and materials, such as flexible joints, to help reduce the risk of damage. Lastly, the company should include guardrails and other safety features on the bridge, as it will be traversed by both pedestrians and vehicles.

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The amount of copper obtained by the reaction depends on the amount of copper chloride reacted and the limiting reagent in the reaction.

Without information on the amounts of reactants used, it is not possible to calculate the amount of copper obtained by the reaction or compare it to the expected amount. However, if the reaction was carried out under controlled conditions and all reactants were used in the stoichiometric ratio, the amount of copper obtained should be the expected amount calculated based on the balanced chemical equation.

In order to calculate the expected amount of copper obtained, the amount of copper chloride reacted should be known, and the limiting reagent should be identified. The amount of copper obtained will be determined by the limiting reagent.

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The complete question is:

Calculate the amount of copper obtained by the reaction. Was it the amount you expected? Explain. ​

3CuCl2(aq) +2 Al (s) ----> 2AlCl3(aq) + 3Cu(s)

Explanation:

Moles in the 20 ml  

   .020 L   *   1.5  moles/L = .03 moles

now in 50 ml   (which is  .05 liters )

      .03 moles / .05 L   = .6 m

Answer:

A

Explanation:

M.G has no cure. it's an autoimmune disease that affects communication between nervous and the muscles.

Changes in the chemical environment of a basic buffer solution can cause shifts in the equilibrium between ammonia, hydroxide ion, and ammonium ion, leading to changes in their respective concentrations.

When a basic buffer solution of equal concentrations of ammonia and ammonium nitrate is subjected to changes in its chemical environment, the concentrations of ammonia, hydroxide ion, and ammonium ion will be affected as follows:

1) Addition of an acid: The acid reacts with the hydroxide ion present in the buffer solution to form water. This decreases the concentration of hydroxide ion and shifts the equilibrium towards the formation of more ammonia and ammonium ion, thus increasing their concentrations.

2)Addition of a base: The base reacts with the ammonium ion present in the buffer solution to form ammonia and water. This decreases the concentration of ammonium ion and shifts the equilibrium towards the formation of more hydroxide ion, thus increasing its concentration.

3)Dilution: Diluting the buffer solution with water decreases the concentrations of both ammonia and ammonium ion, but does not affect the concentration of hydroxide ion.

4)Addition of ammonium chloride: The ammonium chloride dissociates into ammonium ion and chloride ion in the buffer solution. The increase in ammonium ion concentration causes the equilibrium to shift towards the formation of more ammonia and hydroxide ion, thus increasing their concentrations.

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Both options (a) and (b) are evidence for a chemical reaction.

In option (a), the yellow flame is an indication that a chemical reaction has occurred between the sodium metal and water, producing hydrogen gas and sodium hydroxide.

In option (b), the gas bubbles produced indicate that a chemical reaction has occurred between the iron metal and the acid, producing hydrogen gas and iron(II) ions. Based on the given options, evidence for a chemical reaction can be observed in both (a) and (b).

In (a), dropping sodium metal into water produces a yellow flame, indicating a chemical reaction as new substances are formed. In (b), dropping iron metal into acid produces gas bubbles, which also signifies a chemical reaction as a new product, in this case gas, is generated.

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Ammonia ionizes only partially in water. Option 4 is correct.

When ammonia dissolves in water, it reacts with water to form ammonium ions (NH₄⁺) and hydroxide ions (OH⁻), according to the equation: NH₃ + H₂O ⇌ NH₄⁺ + OH⁻. However, this reaction is reversible and only a small fraction of ammonia molecules ionize to form ions. As a result, ammonia is classified as a weak electrolyte, meaning that it only conducts electricity weakly in solution.

Weak electrolytes are characterized by their partial ionization in solution, and they have relatively low electrical conductivity compared to strong electrolytes, which ionize completely in solution. Hence Option 4 is correct.

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The decrease in the second ionization energy of alkali metals going down the group is due to the increase in atomic radius.

As the atomic radius increases, the distance between the nucleus and the outermost electron increases, which reduces the coulombic force of attraction between the nucleus and the electron.

This reduced coulombic force of attraction reduces the energy required to remove the electron, thus resulting in a decrease in the ionization energy. Additionally, due to the increased number of electrons, the effective nuclear charge decreases, which further reduces the force of attraction between the nucleus and the electron, thus resulting in a further decrease in the ionization energy.

Therefore, the decrease in the second ionization energy of alkali metals going down the group can be attributed to a decrease in the coulombic force of attraction due to the increase in atomic radius and the decrease in the effective nuclear charge.

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True. The standard conditions for measuring thermodynamic properties such as enthalpy, entropy, and Gibbs free energy are well-defined and standardized.

These conditions are used to compare and evaluate the relative stability and reactivity of different chemical species. The standard conditions for measuring these properties include a concentration of 1.0 m for soluble aqueous species, pure solids and liquids, and

a partial pressure of 1 atm for gaseous species. This means that the molar concentration of soluble aqueous species is set at 1.0 mol/L, and the pressure of gaseous species is set at 1 atm.

Pure solids and liquids are considered to have an activity of 1, which means that they do not affect the thermodynamic properties.

These conditions are used to determine the standard thermodynamic properties of chemical reactions, which are used to predict the direction and extent of chemical reactions.

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If 120 cm³ of oxygen gas is collected at 713.3 mm Hg pressure, the volume of the dry gas at STP is 0.102 cm³.

To solve this problem, we will use the ideal gas law, which relates the pressure, volume, temperature, and number of moles of a gas:

PV = nRT

First, we need to convert the given conditions to the correct units. The temperature is already in Celsius, so we need to convert it to kelvins by adding 273.15:

T = 27 + 273.15 = 300.15 K

The pressure is given in millimeters of mercury (mm Hg), so we need to convert it to atmospheres (atm) to use in the ideal gas law. There are 760 mm Hg in 1 atm, so:

P = 713.3 mm Hg / 760 mm Hg/atm = 0.938 atm

Next, we can use the ideal gas law to find the number of moles of oxygen gas:

n = PV/RT = (0.938 atm)(120 cm³)/(0.08206 L·atm/(mol·K))(300.15 K) = 0.00454 mol

Finally, we can use the molar volume of a gas at STP (standard temperature and pressure) to find the volume of the dry gas at STP. At STP, the temperature is 273.15 K and the pressure is 1 atm. The molar volume of a gas at STP is 22.4 L/mol, so:

V = n(22.4 L/mol) = (0.00454 mol)(22.4 L/mol) = 0.102 cm³

Therefore, the volume of the dry gas at STP is 0.102 cm³.

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