The criterion of -850mV is referenced to which electrode?
A) Calomel
B) CSE
C) silver-silver chloride
D) Zinc

Answers

Answer 1

The criterion of -850mV is referenced to the silver-silver chloride electrode (Ag/AgCl).  Therefore the correct option is option C.

In electrochemistry, the silver-silver chloride electrode is frequently used as a standard reference electrode in studies of corrosion and other electrochemical reactions.

The potential of the silver-silver chloride electrode, which is defined at 0.1976 V vs the standard hydrogen electrode (SHE) at 25°C, is stable and repeatable.

In investigations on corrosion, the corrosion potential—the potential at which the rate of corrosion is minimized—is frequently determined using the criterion of -850 mV.

The corrosion potential is normally evaluated in relation to the silver-silver chloride electrode, and a corrosion study's standard criterion is typically a potential of -850 mV versus Ag/AgCl. Therefore the correct option is option C.

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Related Questions

What type of forces are a result of an attraction between molecules due to a distortion in the electron cloud, which causes an uneven distribution of negative charge?

Answers

The answer is that the forces you are referring to are known as Van der Waals forces.

Van der Waals forces arise from an attraction between molecules caused by a distortion in the electron cloud, which leads to an uneven distribution of negative charge.

This type of attraction is often seen between nonpolar molecules, such as those found in hydrocarbons. The explanation for this phenomenon lies in the fact that all atoms have electron clouds, which can be distorted by the presence of nearby atoms. This distortion leads to temporary dipoles, or areas of partial positive and negative charges, which can then attract other nearby molecules. In conclusion, Van der Waals forces are an important type of intermolecular attraction, which play a key role in determining the physical and chemical properties of many materials.

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if you have 50.0g of potassium chloride, kcl, in 2.50 liters of solution what is the molarity of the solution (I will give brainliest)

Answers

If we have 50.0g of potassium chloride, KCl, in 2.50 liters of solution then the molarity of the solution is 0.27 moles.

Basically,  to find out the molarity of a solution, we need to know two things

the total number of moles of solute present in solutionthe total volume of the solution

The problem provides you with a 50.0 g sample of potassium chloride, KCl, and a total volume of a solution of 2500. mL.

So, in order to find the number of moles of potassium chloride, our solute, we must use the compound's molar mass, which as we know tells us the mass of one mole of potassium chloride.

50.g × (1 mole/74.55 g) = 0.67 moles

Now the molarity is calculated as,

1 L × (10³mL/L) × (0.67 moles/2500mL) = 0.27 moles of KCl.

Hence, the number of moles in KCl is 0.27.

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recall that it is the pattern of electrons in an atom that causes the atom to behave in a predictable way. properties such as the reactivity of metals, types of bonds that form, numbers of bonds that form, and reactions with such elements as oxygen all exist due to the electron configuration of the element. the electron configurations of atoms are reflected by the positions of elements on the periodic table; thus, the properties of elements can be predicted based on patterns of the elements as modeled in the periodic table. 1. If an element has a total of 14 electrons, how many electrons would exist in the outer (valence) energy level? 2. Write three electron configurations for atoms on the periodic table with a similar reactivity that can be attributed to there being two electrons in the outermost (valence) energy level. 3. Reactivity of a metal increases as one moves down a column of the periodic table. a) With this statement in mind, based on periodic trends in ionization energy, explain why potassium is a more reactive metal than sodium. b) Locate the elements calcium, magnesium, beryllium, and strontium on the periodic table of the elements. Based on the locations of these elements on the periodic table, predict the order of reactivity that these elements would have, starting with the least reactive. 4. Use the location of each element on the periodic table to predict which atom gains electrons and which atom loses electrons when potassium combines with oxygen in a chemical reaction. Explain your answer. 5. a) An atom has an electron configuration of [Ar] 4s² 3d104p. Determine the group, block, and period of this element. What type of element is this (metal, nonmetal, metalloid)? b) Predict if this atom will gain or lose electrons in a chemical reaction. Justify your answer. 6. Arrange the following elements in increasing order of atomic radius, ionization energy, and electronegativity. O, C, Na, F, Li, B, N, and Be Radius: Ionization energy: Electronegativity:

Answers

The electron configuration of an element determines its properties, and the number of valence electrons can be determined by its position on the periodic table. Periodic trends in ionization energy, atomic radius, and electronegativity can be used to predict the reactivity and chemical behavior of elements.

1. If an element has a total of 14 electrons, it would have 4 electrons in the outer (valence) energy level. This is because the electronic configuration of the element would be 1s² 2s² 2p⁶ 3s² 3p², and the outermost energy level is the third energy level, which has a total of 8 electrons. Thus, the number of valence electrons would be 4 (2 in 3s orbital and 2 in 3p orbital).

2. Three electron configurations for atoms on the periodic table with a similar reactivity that can be attributed to there being two electrons in the outermost (valence) energy level are:

Li: [He] 2s¹

Na: [Ne] 3s¹

K: [Ar] 4s¹

These elements are all alkali metals with similar chemical properties due to their one valence electron.

3. a) Potassium is a more reactive metal than sodium because it has a lower ionization energy. Ionization energy is the energy required to remove an electron from an atom, and it decreases as you move down a column of the periodic table due to the increasing distance of the valence electrons from the nucleus and the shielding effect of inner electrons. Since potassium is located below sodium in the same column, its valence electrons are farther from the nucleus and are shielded by more inner electrons, making them easier to remove and resulting in a lower ionization energy.

3. b) Based on their locations on the periodic table, the order of reactivity of these elements starting with the least reactive is: beryllium, magnesium, calcium, strontium. This is because they are all alkaline earth metals with similar chemical properties, and their reactivity generally increases as you move down a column of the periodic table due to the same reasons as explained in part a.

4. In a chemical reaction between potassium and oxygen, potassium would lose one electron to form a positively charged ion (K⁺), while oxygen would gain two electrons to form a negatively charged ion (O²⁻). This is because potassium has one valence electron in its outermost energy level, while oxygen has six valence electrons in its outermost energy level. Potassium would prefer to lose one electron to achieve the stable electron configuration of argon ([Ar]), while oxygen would prefer to gain two electrons to achieve the stable electron configuration of neon ([Ne]).

5. a) The electronic configuration [Ar] 4s² 3d¹⁰ 4p¹ belongs to the element germanium (Ge). Ge is a metalloid, located in group 14 (IVA), block p, and period 4 of the periodic table.

5. b) Germanium is located in group 14, which means it has 4 valence electrons. It is likely to neither gain nor lose electrons in a chemical reaction, as it would require a significant amount of energy to either gain four electrons or lose four electrons. Therefore, germanium is expected to be relatively inert chemically.

6. Increasing order of atomic radius: F, O, N, C, B, Be, Li, Na.

This is because atomic radius decreases across a period and increases down a group.

Increasing order of ionization energy: Li, Be, B, C, N, O, F, Na.

This is because ionization energy increases across a period and decreases down a group.

Increasing order of electronegativity: Na, Li, Be, B, C, N, O, F.

This is because electronegativity generally increases across a period and decreases down a group.

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Based on the solubility graph above, which of the following substances is the most
soluble in water at 40° C?
A KCI
B KNO3
C NaCl
D NH3

Answers

KNO3 is the substance that is most soluble at 40° C.

What is the graph of solubility?

A solubility graph is a graphic depiction of a substance's solubility at various temperatures. The saturation point, also known as the maximum quantity of a solute that may dissolve in a given amount of solvent at a specific temperature, is shown.

The graph typically includes two axes: one for solubility (measured in grams of solute per 100 grams of solvent) and one for temperature (in degrees Celsius or Fahrenheit).

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Rank the following types of intermolecular forces in general order of decreasing strength.

a. dipole-dipole

b. hydrogen bonding

c. ion-dipole

d. London dispersion

Answers

The general order of decreasing strength for intermolecular forces is: c. ion-dipole, b. hydrogen bonding, a. dipole-dipole, and d. London dispersion.



Intermolecular forces are forces between molecules. Ion-dipole forces are the strongest, as they involve charged ions interacting with a polar molecule.

Hydrogen bonding, a specific type of dipole-dipole interaction, occurs when hydrogen atoms are bonded to highly electronegative atoms like fluorine, oxygen, or nitrogen. Dipole-dipole forces are interactions between polar molecules.

Lastly, London dispersion forces are the weakest and are present in all molecules, resulting from temporary fluctuations in electron distribution.



Hence,  The intermolecular forces, in order of decreasing strength, are ion-dipole, hydrogen bonding, dipole-dipole, and London dispersion forces.

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You have 300,000 atoms of a radioactive substance. After 4 half-lives have past, how

many atoms remain?

Remember that you cannot have a fraction of an atom, so round the answer to the nearest whole number.

Nvm, I've solved and got the answer,
It's 18750 atoms

Answers

The number of atoms remaining after 4 half-lives has past is 18750 atoms

How do i determine the amount remaining?

From the question given above the following data were obtained:

Original amount of radioactive substance (N₀) = 300000 atomsNumber of half-lives (n) = 4 half-livesAmount remaining (N) = ?

The number of half-lives, original and amount remaining are related according to the following equation:

N = N₀ / 2ⁿ

Inputting the given parameters, we have:

N = 300000 / 2⁴

N = 300000 / 16

N = 18750 atoms

Thus, we can conclude that the amount remaining after 4 half-lives is 18750 atoms

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copper
A) more active than hydrogen
B) more active than chloride
C) less active (or more noble) than hydrogen
D) less active (or more anodtic ) than hydrogen

Answers

The answer C less active (or more noble) than hydrogen. This is because copper has a lower tendency to lose electrons and form cations compared to hydrogen. In other words, copper is a relatively stable element that is not as easily oxidized as hydrogen.

They can be seen in the electrochemical series, which ranks elements according to their tendency to undergo oxidation or reduction reactions. Hydrogen is located higher up on the series, indicating that it is more reactive and has a greater tendency to lose electrons and form cations. On the other hand, copper is located lower down on the series, indicating that it is less reactive and has a lower tendency to undergo oxidation. It is worth noting that copper can still undergo oxidation reactions under certain conditions. For example, when exposed to air and moisture, copper can slowly react to form copper oxide. Additionally, copper can be used as an anode in certain electrochemical cells, indicating that it is more anodic than some other metals. However, in general, copper is considered to be a relatively stable and unreactive element, particularly compared to hydrogen.

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what volume does 0.20 g methane gas (ch4) occupy at 312 k and 2.00 atm? your answer should include two significant figures (round your answer to two decimal places). provide your answer below:

Answers

To solve this problem, we can use the ideal gas law: PV = n RT, First, we need to find the number of moles of methane gas present. We can use the molar mass of methane (16.04 g/mol) to convert from mass to moles:

0.20 g CH4 x (1 mol CH4 / 16.04 g CH4) = 0.0125 mol CH4
Next, we can rearrange the ideal gas law to solve for volume:
V = (nRT) / P
where n is the number of moles, R is the gas constant (0.0821 L·atm/mol·K), T is the temperature in Kelvin, and P is the pressure in atmospheres.
Plugging in the values we have:
V = (0.0125 mol) x (0.0821 L·atm/mol·K) x (312 K) / (2.00 atm) = 0.156 L
To round to two significant figures, we look at the digit in the hundredths place (5) and round up if it is 5 or greater. Therefore, the final answer is:
V = 0.16 L

To determine the volume that 0.20 g methane gas (CH4) occupies at 312 K and 2.00 atm, you can use the Ideal Gas Law equation: PV = nRT, where P is pressure, V is volume, n is the number of moles, R is the ideal gas constant (0.0821 L atm/mol K), and T is temperature.
1. First, convert the mass of methane to moles by dividing it by its molar mass (CH4 = 12.01 g/mol for C + 4 × 1.01 g/mol for H = 16.04 g/mol):
n = 0.20 g / 16.04 g/mol = 0.0125 mol (rounded to four significant figures)
2. Rearrange the Ideal Gas Law equation to solve for volume: V = nRT/P
3. Plug in the values:
V = (0.0125 mol) × (0.0821 L atm/mol K) × (312 K) / (2.00 atm)
4. Calculate the volume:
V = 0.319 L
The volume of 0.20 g methane gas (CH4) at 312 K and 2.00 atm is 0.32 L.

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Which transition metals are paramagnetic but can easily form ferromagnetic alloys with other metals?

Answers

The transition metals iron (Fe), cobalt (Co), and nickel (Ni) are paramagnetic and can easily form ferromagnetic alloys with other metals. Here options A, B, and C are the correct answer.

Transition metals are a group of elements that are characterized by their partially filled d-orbitals. Some of these elements exhibit magnetic properties, including paramagnetism and ferromagnetism. Paramagnetic materials are attracted to an external magnetic field, while ferromagnetic materials exhibit strong magnetic properties even in the absence of an external field.

Among the transition metals, iron (Fe), cobalt (Co), and nickel (Ni) are known to be paramagnetic and can easily form ferromagnetic alloys with other metals. These three elements are often referred to as the "iron group" and are known for their strong magnetic properties.

Iron, in particular, is commonly used in the production of ferromagnetic alloys, such as steel. The addition of small amounts of iron to other metals can dramatically increase their magnetic properties, making them useful in a wide range of applications, including electronics and data storage.

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Complete question:

Which of the following transition metals are paramagnetic and can readily form ferromagnetic alloys with other metals?

A) Iron (Fe)

B) Cobalt (Co)

C) Nickel (Ni)

D) Copper (Cu)

A chemist titrates ________ of a ________ acetic acid ________ solution with ________ ________ solution at ________. Calculate the pH at equivalence. The ________, of acetic acid is ________ Round your answer to 2 decimal places Note for advanced students: you may assume the total volume of the solution equals the initial volume plus the volume of NaOH solution added.

Answers

The pH at equivalence to be 4.78. A chemist titrates 25 mL of a 0.2 M acetic acid solution with 0.1 M NaOH solution at 25°C. The Ka, of acetic acid is 1.8 x 10-5.

To calculate the pH at equivalence, we need to use the Henderson-Hasselbalch equation. This equation states that pH = pKa + log [A-]/[HA], where pKa is the acid dissociation constant, [A-] is the concentration of the conjugate base and [HA] is the concentration of the weak acid.

In this case, the Ka of acetic acid is 1.8 x 10-5. The initial concentration of acetic acid is 0.2 M, so the initial concentration of the conjugate base is 0. Since 25 mL of 0.1 M NaOH was added, the final concentration of the conjugate base is 0.0025 M.

With this information, we can calculate the pH at equivalence. Plugging all the numbers into the Henderson-Hasselbalch equation, we get a pH of 4.77. Round this to 2 decimal places, and we get a pH of 4.78.

To summarize, we used the Henderson-Hasselbalch equation to calculate the pH of a 0.2 M acetic acid solution titrated with 0.1 M NaOH. We assumed that the total volume of the solution was equal to the initial volume plus the volume of NaOH solution added.

The Ka, of acetic acid was given to be 1.8 x 10-5. After plugging in all the numbers and rounding to 2 decimal places, we calculated the pH at equivalence to be 4.78.

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the velvet mesquite trees that populate areas of southwestern arizona are a member of the legume family and have nitrogen-fixing bacteria in their root nodules. (d) describe the relationship between nitrogen-fixing bacteria and velvet mesquite trees.

Answers

The velvet mesquite tree is a member of the legume family and has a symbiotic relationship with nitrogen-fixing bacteria. The bacteria, which live in the root nodules of the tree, convert atmospheric nitrogen into a form that the tree can use for growth and development.

The return, the tree provides the bacteria with carbohydrates and other nutrients that they need to survive. This relationship is known as mutualism, as both the bacteria and the tree benefit from their partnership. The bacteria are able to access a source of energy that they would not be able to obtain on their own, while the tree is able to grow and thrive in environments where other plants may struggle due to a lack of nitrogen. This relationship is important not only for the velvet mesquite tree, but also for the ecosystems in which it lives. By fixing nitrogen in the soil, the tree helps to create a more nutrient-rich environment for other plants to grow in. This, in turn, can lead to greater biodiversity and a more resilient ecosystem overall.

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Consider a steam power plant that operates on a reheat Rankine cycle and has a net power output of 80 MW. Steam enters the high pressure turbine at 10 MPa and 500oC and the low pressure turbine at 1 MPa and 500oC. Steam leaves the condenser as a saturated liquid at a pressure of 10 kPa. The isentropic efficiency of the turbine is 80% , and that of the pump is 95% .Show the cycle on a T-s diagram with respect to saturation lines, and determinea) Quality (or temperature, if superheated) of the steam at the turbine exit,b) The thermal efficiency of the cycle,c) The mass flow rate of the steam.

Answers

To solve this problem, we first need to draw the cycle on a T-s diagram with respect to saturation lines. The T-s diagram for a reheat Rankine cycle is shown below:

Reheat Rankine Cycle T-s Diagram

In this diagram, the process from 1 to 2 is the high pressure turbine, the process from 2 to 3 is the reheater, the process from 3 to 4 is the low pressure turbine, and the process from 4 to 1 is the condenser.

From the problem statement, we know that the steam enters the high pressure turbine at 10 MPa and 500°C. Using a steam table, we can find that the specific entropy of the steam at state 1 is 6.3295 kJ/kg·K. We also know that the isentropic efficiency of the turbine is 80%, which means that the actual specific entropy at state 2 is:

s2 = s1 - (s1 - s2,isentropic) / 0.8

s2 = 6.3295 - (6.3295 - 5.1146) / 0.8

s2 = 5.7222 kJ/kg·K

The specific enthalpy at state 2 can be found using a steam table:

h2 = 3624.4 kJ/kg

The steam is then reheated to 500°C at constant pressure before entering the low pressure turbine at 1 MPa. The specific entropy at state 3 is the same as that at state 2, because the process from 2 to 3 is isobaric. Using a steam table, we can find that the specific enthalpy at state 3 is:

h3 = 3975.5 kJ/kg

The steam leaves the low pressure turbine at 1 MPa and 500°C, and enters the condenser where it is condensed into a saturated liquid at 10 kPa. Using a steam table, we can find that the specific enthalpy of the saturated liquid at state 4 is:

h4 = 191.81 kJ/kg

Now we can calculate the quality (or temperature, if superheated) of the steam at the turbine exit. Since the steam is superheated at state 2, we can use the steam tables to find the temperature at state 2:

T2 = 500°C

Since the process from 2 to 3 is isobaric, the temperature at state 3 is also 500°C. Therefore, the steam is still superheated at state 3.

Next, we can calculate the thermal efficiency of the cycle using the equation:

ηth = (Wnet / Qin) x 100%

where Wnet is the net power output and Qin is the heat input. The net power output is given as 80 MW, and the heat input can be calculated as:

Qin = (h1 - h4) + (h3 - h2)

Qin = (3624.4 - 191.81) + (3975.5 - 3624.4)

Qin = 834.69 kJ/kg

Therefore, the thermal efficiency of the cycle is:

ηth = (80 / 834.69) x 100%

ηth = 9.59%

Finally, we can calculate the mass flow rate of the steam using the equation:

Wnet = m (h1 - h2) + m (h3 - h4)

where m is the mass flow rate of the steam. Rearranging this equation, we get:

m = W

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The smallest group of atoms with a characteristic chemical composition and the basic crystal structure of a mineral is called a

Answers

The smallest group of atoms with a characteristic chemical composition and the basic crystal structure of a mineral is called a unit cell. A unit cell is the fundamental repeating building block of a crystal lattice, which makes up the mineral's structure.

Minerals are naturally occurring, inorganic substances that possess a specific chemical composition and a well-ordered crystalline structure. Atoms, which are the smallest units of matter, come together to form the chemical composition of a mineral. These atoms arrange themselves in an organized, repeating pattern, resulting in the mineral's basic crystal structure.
The arrangement of atoms within a unit cell is crucial to understanding the properties of a mineral, as it defines the mineral's overall structure, appearance, and physical properties. The unit cell's geometry can be described by the lengths of its three axes and the angles between them, which determine the shape of the crystal lattice.
Various types of unit cells exist, with each type corresponding to a specific crystal system. Some common crystal systems include cubic, tetragonal, orthorhombic, and hexagonal. The type of crystal system a mineral belongs to depends on the specific arrangement of its atoms within the unit cell.
In summary, the unit cell is the smallest group of atoms that exhibits a mineral's characteristic chemical composition and basic crystal structure. This fundamental building block plays a significant role in defining the properties and appearance of minerals, making it a crucial concept in the study of mineralogy.

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What is the energy change for 150 g of water to go from 115 C to 80 C

Answers

The energy change for 150 g of water to go from 115°C to 80°C is -2205 J.

The energy change for 150 g of water to go from 115°C to 80°C can be calculated using the formula;

q = mcΔT

Where; q = energy change (in Joules)

m = mass of water (in grams)

c = specific heat capacity of water (in J/g°C)

ΔT = change in temperature (in °C)

First, we need to determine specific heat capacity of water. The specific heat capacity of water is 4.18 J/g°C.

Next, we can put the given values into the formula and calculate the energy change;

m = 150 g (given)

c = 4.18 J/g°C (specific heat capacity of water)

ΔT = (80°C - 115°C) = -35°C (change in temperature, noting that the temperature is decreasing)

q = 150 g x 4.18 J/g°C x -35°C

q = -2205 J

Therefore, the energy change is -2205 J (negative sign indicates a release of energy).

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What is the pH of a buffer in which the concentration of benzoic acid, C6H5COOH, is 0.25 M and the concentration of sodium benzoate, NaC6H5COO, is 0.15 M ?
Enter your answer with 2 digits past the decimal.
Ka of C6H5COOH is 6.30 x 10-5

Answers

The pH of the buffer can be calculated using the Henderson-Hasselbalch equation, which is pH = pKa + log([A-]/[HA]), where pKa is the negative logarithm of the acid dissociation constant, [A-] is the concentration of the conjugate base, and [HA] is the concentration of the acid.

First, we need to find the pKa of benzoic acid using the given Ka value:
Ka = [H+][C6H5COO-]/[C6H5COOH]
6.30 x 10^-5 = x^2 / 0.25
x = 0.00501 M
pKa = -log(Ka) = 4.20
Now we can plug in the given concentrations of benzoic acid and sodium benzoate:
pH = 4.20 + log(0.15 / 0.25)
pH = 4.20 - 0.322
pH = 3.88
Therefore, the pH of the buffer is 3.88.
It is important to note that sodium benzoate acts as a buffer because it can react with any added acid or base to maintain a relatively constant pH. The concentration of sodium benzoate is lower than the concentration of benzoic acid, which means that the buffer will be more effective at resisting a decrease in pH (i.e. addition of acid) than an increase in pH (i.e. addition of base). Additionally, the pH of the buffer is close to the pKa of benzoic acid, which means that the buffer is most effective at resisting changes in pH around that value.

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Gastrin production, a task that is performed by the stomach, results in which of the following effects?A) Simulation of pancreatic enzyme secretionsB) Stimulation of HCl secretions by parietal cellsC) Conversion of polysaccharides to monosaccharidesD) Release of insulin in response to glucose load

Answers

Gastrin production, a task that is performed by the stomach, results in B) Stimulation of HCl secretions by parietal cells.

The primary purpose of the hormone gastrin, which is produced by G cells in the stomach, is to encourage the release of hydrochloric acid (HCl) by the parietal cells in the stomach. HCl helps to digest food and eliminates stomach germs. Additionally, gastrin boosts stomach muscular contractions and stimulates the formation of the stomach lining, which aids in mixing and advancing food along the digestive tract.

A) Gastrin synthesis is not directly related to the simulation of pancreatic enzyme secretions. Cholecystokinin (CCK), a hormone secreted by the small intestine in response to the presence of food, stimulates pancreatic enzymes

C) Enzymes like amylase and sucrase, which are made in the pancreas and small intestine, respectively, are responsible for the conversion of polysaccharides into monosaccharides.

D) The pancreas, specifically cells known as beta cells that create insulin in reaction to rising blood glucose levels, regulates the release of insulin in response to glucose load.

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please help Due today!

Answers

Answer: Wrote the answers below

Explanation:

The balanced equation for Number 1 is:

Fe2O3(s) + 3H2(g) --> Fe(s) + 3H2O(l)

Step 1:

moles ratio of iron (III) oxide and hydrogen is 1:3

step 2:

work out mr (molar mass) of fe2o3: 111.68+ 48 = 159.68

moles of  iron (III) oxide: 33.5g  divided by 159.68 = 0.21 mol

Step 3:

1:3 ratio so 0.21 times 3 = 0.63 mol of hydrogen

Step 4:

mass of hydrogen = mol times mr

0.63 times 2 = 1.26g

mass of hydrogen = 1.26g or 1.27g depending on whether you used 1.00 or 1.01 for the mr of hydrogen

The following mechanism has been proposed to account for the rate law of the decomposition of ozone to O2(g):O3 + M k1/K-1 O2 + O + MO + O3 k2 2O_2Apply the steady-state hypothesis to the concentration of atomic oxygen, and derive the rate law for the decomposition of ozone. (M stands for an atom or molecule that can exchange kinetic energy with the particles undergoing the chemical reaction.)

Answers

The rate law for the decomposition of ozone is:

[tex]Rate = k1[O3][M] / (k1/K-1[O2] + k2[M])[/tex]

What is the steady-state hypothesis and rate law for the decomposition of ozone?

To apply the steady-state hypothesis to the concentration of atomic oxygen, we assume that the concentration of atomic oxygen remains constant during the reaction, meaning that the rate of its production must be equal to the rate of its consumption.

The rate of production of atomic oxygen is given by the second elementary step: k2[O3][M].

The rate of consumption of atomic oxygen is given by the sum of the first and third elementary steps: k1[O3] + K-1[O2][O].

Setting the rate of production equal to the rate of consumption, we get:

[tex]k2[O3][M] = k1[O3] + K-1[O2][O][/tex]

Solving for [O], we get:

[tex][O] = (k1[O3] / K-1[O2]) - ([M] k2[O3] / K-1[O2])[/tex]

Substituting [O] back into the expression for the rate law, which is given by the rate of the first elementary step, we get:

[tex]Rate = k1[O3] = k1[O3][M] / (k1/K-1[O2] + k2[M])[/tex]

Therefore, the rate law for the decomposition of ozone is:

[tex]Rate = k1[O3][M] / (k1/K-1[O2] + k2[M])[/tex]

where k1, K-1, and k2 are rate constants for the individual steps of the mechanism, [O3] is the concentration of ozone, [M] is the concentration of the third body, and [O] is the concentration of atomic oxygen.

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2.
Copy and complete the following table by giving the formulae of the
compounds formed:
Na+
Ca²+
K+
Mg2+
A1³+
NH4+
OH-
NO3™ SO4²- CO3²-
MnO4 PO4³-

Answers

The formulae of the chemical compounds formed are as follows:

Na⁺ : NaClCa²⁺ : CaSO₄K⁺ : K₂SO₄Mg²⁺ : MgCl₂Al³⁺ :  Al(SO₄)₃NH₄⁺ : (NH₄)₂SO₄OH⁻ : NaOHNO₃⁻ : NaNO₃SO₄²⁻ : Na₂SO₄CO₃²⁻ : Na₂CO₃MnO₄⁻ : KMnO₄PO₄³⁻ Ca₃(PO₄)₂

What are chemical compounds?

A chemical compound is formed when two or more elements are combined together in a definite proportion. Chemical bonds are formed when the elements interact with one another. These bonds develop as a result of atoms sharing electrons.

Examples of chemical compounds include baking soda, water, and table salt.

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_____ is the SI unit for pressure. However, standard pressure is measured in ____which is equivalent to 101.3 kPa.

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Pascal (Pa) is the SI unit for pressure. However, standard pressure is measured in atmosphere (atm), which is equivalent to 101.3 kPa.

What is  pressure?

Defining pressure involves measuring how much force acts upon a surface relative to its area. This scalar quantity typically employs metrics expressed in units like Pascal or psi for effectively capturing various data types including those found within physics and engineering disciplines.

Both solid materials and fluids can generate differing levels of pressure when exerting their effects on surfaces, making this concept critical to understanding many systems across domains.

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Testing precision and accuracy of scale, weigh block exactly 1.000g. these are measurements captured:
0.843 g
0.842 g
0.843 g
Is the scale precise, accurate, both, or neither?

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we can conclude that the scale is precise but not accurate. The correct option is d.This means that the scale consistently gives the same measurements, but they are not accurate or close to the true value.

To understand whether the scale is precise, accurate, both, or neither, we need to define these terms. Precision refers to the consistency or reproducibility of measurements, while accuracy refers to how close the measured value is to the true or accepted value. In this case, the true value is 1.000g, and the measurements captured are 0.843 g, 0.842 g, and 0.843 g.Looking at these measurements, we can see that they are not accurate since none of them are close to 1.000g. However, we can also see that they are precise since they are all very similar to each other, with a difference of only 0.001g between the highest and lowest measurement.
Therefore, To improve accuracy, the scale may need to be recalibrated or replaced.

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complete question: Testing precision and accuracy of scale, weigh block exactly 1.000g. these are measurements captured:

a. 0.843 g

b. 0.842 g

c. 0.843 g

d. Is the scale precise, accurate, both, or neither?

complete reduction of the ketones in benzil to alcohols with nabh4 leads to three stereoisomers. draw fischer projections of the three stereoisomers. state whether each is optically active or not.

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Three stereoisomers two optically active isomers and one non-optically active meso isomer—are produced when benzil is completely reduced with NaBH₄.

When benzil undergoes complete reduction with NaBH₄, three stereoisomers of the resulting alcohols are formed due to the presence of two chiral centers. The Fischer projections of the three stereoisomers can be drawn as follows:
1. 2R,3S-2,3-butanediol:
  CH₃       CH₃
   |          |
   OH       OH
   |          |
  CHOH     CHOH
   |          |
   CH₃       CH₃
This stereoisomer is optically active because it has two different chiral centers.
2. 2S,3S-2,3-butanediol:
  CH₃       CH₃
   |          |
   OH       OH
   |          |
  CHOH     CHOH
   |          |
   CH₃       CH₃
This stereoisomer is also optically active because it has two different chiral centers.
3. meso-2,3-butanediol:
  CH₃       CH₃
   |          |
   OH       OH
   |          |
  CHOH     CHOH
   |          |
   CH₂OH   CH₂OH
This stereoisomer is not optically active because it has a plane of symmetry that divides the molecule into two mirror-image halves.
Therefore, the complete reduction of benzil with NaBH₄ leads to three stereoisomers: two optically active isomers and one meso isomer that is not optically active.

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At 25.0 °C the Henry's Law constant for methane (CH,) gas in water is 1.4 x 10^-3 M/atm. Calculate the mass in grams of CH4 gas that can be dissolved in 150. mL of water at 25.0 °C and a CH, partial pressure of 2.50 atm. Round your answer to 2 significant digits.

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The amount of mass that is required of CH₄ that can be dissolved in 150 ml of water at 25.0 °C and a CH, partial pressure of 2.50 atm is 0.0084 g.

We can use Henry's Law equation, which relates the concentration of a gas in a solution to its partial pressure:

C = kH * P

where C is the concentration of the gas in the solution (in moles per liter), kH is the Henry's Law constant (in M/atm), and P is the partial pressure of the gas (in atm).

First, we need to convert the volume of water from milliliters to liters:

150 mL = 0.150 L

Next, we can use the equation to calculate the concentration of methane in the water:

C = kH * P = (1.4 x 10^-3 M/atm) * (2.50 atm) = 3.5 x 10^-3 M

Now we can use the concentration and the volume of water to calculate the moles of methane dissolved:

moles = concentration * volume = (3.5 x 10^-3 M) * (0.150 L) = 5.25 x 10^-4 moles

Finally, we can use the molar mass of methane (16.04 g/mol) to convert the moles to grams:

mass = moles * molar mass = (5.25 x 10^-4 moles) * (16.04 g/mol) = 8.4 x 10^-3 g

Rounding to two significant digits gives us an answer of 0.0084 g of CH₄ gas dissolved in 150 mL of water at 25.0 °C and a CH₄ partial pressure of 2.50 atm.

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Can Delta S be less than 0?

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Yes, Delta S can be less than 0. This means that there is a decrease in entropy, which is a measure of disorder or randomness in a system.

A negative value for Delta S indicates that the system is becoming more ordered, which typically requires the input of energy. When the entropy of a system decreases, it means the system becomes more ordered and less random. In such cases, Delta S will be a negative value, which indicates that the final entropy (S_final) is less than the initial entropy (S_initial). In summary, Delta S can be less than 0 when the system becomes more ordered as the reaction or process occurs.

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predict the ideal bond angles around n in n2f2 using the molecular shape given by the vsepr theory. (the two n atoms are the central atoms.)

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The molecular shape of N₂F₂ is linear, with an N-F-N-F arrangement. The electron domain geometry is trigonal planar, but the bond angles in N₂F₂ are 180 degrees due to its linear structure.

The ideal bond angles around N in N₂F₂ using the VSEPR theory, follow these steps:

1. Determine the molecular shape: N₂F₂ has a structure where each N atom is connected to two F atoms and the other N atom, creating a linear shape with an N-F-N-F arrangement.

2. Identify the electron domain geometry: Each nitrogen atom in N₂F₂ has three electron domains (two bonding domains with F atoms and one bonding domain with the other N atom). This gives a trigonal planar electron domain geometry.

3. Determine the ideal bond angles: In a trigonal planar electron domain geometry, the ideal bond angles are The molecular shape of N₂F₂ is linear, with an N-F-N-F arrangement. The electron domain geometry is trigonal planar, but the bond angles in N₂F₂ are 180 degrees due to its linear structure degrees. However, since N₂F₂ has a linear molecular shape, the bond angle between N-F-N and N-N-F will be 180 degrees.

So, the ideal bond angles around N in N₂F₂ are 180 degrees, according to the molecular shape given by the VSEPR theory, with the two N atoms being the central atoms.

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Why are perchlorate salts unusually hazardous?
- They are toxic and volatile.
- Some are shock-sensitive.
- They are strong bases.
- They are water-reactive.

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Perchlorate salts are unusually hazardous primarily because they are toxic and volatile.

Perchlorate salts are unusually hazardous primarily because they are toxic and some are shock-sensitive. Their toxicity can pose a risk to human health and the environment, while their shock-sensitive nature can cause them to react violently upon impact, potentially leading to accidents or explosions. Perchlorate salts are unusually hazardous due to several reasons. Firstly, they are toxic and volatile, meaning they can easily vaporize and become airborne, increasing the risk of inhalation and absorption through the skin. Secondly, some perchlorate salts are shock-sensitive, meaning they can easily detonate or explode when subjected to impact or friction.

Additionally, perchlorate salts are strong bases, which can cause severe chemical burns and damage to tissues and organs upon contact. Finally, they are also water-reactive, which can cause them to release oxygen and hydrogen gas, leading to potential fire and explosion hazards. Overall, the unique combination of these characteristics makes perchlorate salts particularly hazardous and requires careful handling and disposal.

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in the 13c nmr of benzil, which carbon is responsible for the resonance at 194.5 ppm? the other peaks are at 134.8, 132.9, 129.8 and 128.9 ppm. which carbon(s) are responsible for the resonances at 134.8 and 132.9 ppm? you do not need to assign each resonance, but identify which carbon(s) might give rise to these signals

Answers

In the 13C NMR spectrum of benzil, the carbon responsible for the resonance at 194.5 ppm is the carbonyl carbon of the ketone group, which is in the middle of the molecule.

The peaks at 134.8 and 132.9 ppm are likely due to the carbons in the aromatic ring adjacent to the carbonyl group.

The carbon directly adjacent to the carbonyl group (ortho position) usually appears at higher chemical shift values (around 135 ppm), while the next carbon (meta position) usually appears at slightly lower values (around 130 ppm).

Therefore, the peaks at 134.8 and 132.9 ppm likely correspond to the ortho and meta carbons, respectively.

The other peaks at 129.8 and 128.9 ppm are due to the carbons in the aromatic ring farthest from the carbonyl group, while the peak at 194.5 ppm is due to the carbonyl carbon in the ketone group.

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The ears of the deer are long and eyes are on the side of the head because? ​

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The ears of the deer are long and the eyes are on the side of the head because it helps them detect predators and prey in a wider range of directions.

The position of the eyes on the sides of the head provides deer with a panoramic view of their surroundings, allowing them to spot potential dangers from many directions. The long ears serve as sensitive receivers of sound, which helps deer detect the presence and direction of predators and other animals, as well as communicate with each other. Together, these adaptations give deer a better chance of survival in their environment.

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A weather map of Chicago with a high pressure system and warm front.
Based on the weather map, what might the upcoming weather be like in Chicago?

Warm, dry, clear skies
Warm, humid, possible thunderstorms
Cold, dry, clear skies
Cool, humid, possible thunderstorms

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Based on the weather map with a high-pressure system and warm front, the upcoming weather in Chicago is likely to be warm, humid, and may have possible thunderstorms, which is the second option.

A high-pressure system is associated with sinking air and stable atmospheric conditions, which typically result in clear, dry weather. However, when a warm front is approaching, it can cause warm, moist air to rise and potentially form thunderstorms. A warm front occurs when warm air moves into an area of cooler air, which can lead to instability and the formation of clouds and precipitation. In this case, the warm front is likely to bring warm, moist air from the south, which will interact with the high-pressure system and potentially form thunderstorms.

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Answer: A

Explanation: I havr evidence

which of the following has 90 degree bond angles? which of the following has 90 degree bond angles? ch4 xef4 nf3 co2

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Hi! Among the given molecules, "ch4 xef4 nf3 co2", Xenon hexafluoride (XeF4) has 90-degree bond angles.XeF4 has a square planar molecular geometry with two lone pairs on the central Xenon (Xe) atom, resulting in 90-degree bond angles between the adjacent Fluorine (F) atoms.

The other molecules have different bond angles and molecular geometries:
1. Methane (CH4) has a tetrahedral geometry with bond angles of approximately 109.5 degrees.
2. Nitrogen trifluoride (NF3) also has a tetrahedral geometry with bond angles close to 109.5 degrees.
3. Carbon dioxide (CO2) has a linear molecular geometry with a bond angle of 180 degrees between the Oxygen (O) atoms.
So, in summary, XeF4 is the molecule with 90-degree bond angles among the given options.

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