The molecular formula of a certain compound is x2O3. If 18.88 g of the compound contains 10 g of x, the atomic mass of x is approximately 54 g.
Let's assume that the number of atoms of X in the molecular formula is equal to 'a'.
Then, the molecular mass of the compound will be equal to:-
(a × atomic mass of X) + (2 × molar mass of O) = 2a(MX) + 3 × 16 = 2a(MX) + 48
The atomic mass of X can be determined by finding the value of a.
The molecular mass of the compound = 18.88 g/mol
Mass of X = 10 g
We can calculate the value of a by simplifying the equation:-
2a(MX) + 48 = 18.88MX = (18.88 - 48)/- 4aMX = 14/3a
Now, on substituting the values,
The atomic mass of X = (18.88 g/mol × [14/3a])/[2(14/3a) + 3 × 16]
On simplifying the above equation:-
The atomic mass of X = (9.44 × 3a)/[28a + 144] (The denominator can be simplified by factoring 4)
The atomic mass of X = (9.44 × 3a)/(4 × (7a + 36))= 2.4 g/mol
For the given question, the atomic mass of X is approximately 54 g, so the correct answer is option b.
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Calculate the pH of a 0.050 M solution of hydroxylamine, NH2OH. Kb = 6.6 x 10^-9
The pH of hydroxylamine will be 8.76.
The first step is to write the balanced equation for the reaction of hydroxylamine with water:
NH₂OH + H₂O ⇌ NH₃OH⁺ + OH⁻
The Kb expression for this reaction is:
Kb = [NH₃OH⁺][OH⁻] / [NH₂OH]
We are given the Kb value as 6.6 x 10⁻⁹, so we can use this to find the concentration of hydroxylamine that has been deprotonated:
Kb = [NH₃OH⁺][OH⁻] / [NH₂OH]
6.6 x 10⁻⁹ = x² / (0.050 - x)
Assuming that x is very small compared to 0.050, we can simplify the expression as follows:
6.6 x 10⁻⁹ = x² / 0.050
x² = 3.3 x 10⁻¹⁰
x = 5.7 x 10⁻⁶ M
Now that we have the concentration of hydroxide ions, we can use this to find the pH of the solution:
pOH = -log[OH-] = -log(5.7 x 10⁻⁶) = 5.24
pH = 14.00 - pOH = 8.76
Therefore, the pH of a 0.050 M solution of hydroxylamine is 8.76.
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what are the physical processes by which atoms rearrange during phase transformations in the solid state
Diffusion, nucleation, and crystal growth are the physical processes by which atoms rearrange during phase transformations in the solid state.
Phase transformations in the solid state refer to a type of reaction that happens to the solid state of matter, which results in different properties of the substance.
It is important to note that the process of phase transformation happens through different physical processes that include evaporation, melting, sublimation, and condensation, among others.
During phase transformation in the solid state, atoms undergo a rearrangement process that changes the physical properties of the solid into a different phase. This process usually happens in a few ways, such as:
- Diffusion: This is the movement of atoms from one place to another due to the application of heat or pressure, which allows the atoms to shift positions within the solid. The diffusion process enables the atoms to break and form new bonds, resulting in phase transformation.
- Nucleation: This is a process that happens when the solid phase undergoes a change, which causes the formation of new atoms or molecules. This process typically occurs in areas where there is a higher concentration of atoms, and it takes place due to the application of heat or pressure.
- Crystal Growth: This is a process that happens when the atoms of a solid phase come together to form a new crystal structure. The crystal structure has a different arrangement of atoms, which results in different physical properties.
These processes change the physical properties of the solid into a different phase, resulting in different properties.
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a certain organic compound contains only c, h, and o. combustion of 0.1000 g of this compound produced 0.2921 g of co2 and 0.0951 g of h2o. what is the empirical formula of the compound?
The empirical formula of the organic compound is C1H1O1 and the simplified form is CHO.
To find the empirical formula of the compound, we need to determine the mole ratios of the elements in the compound.
First, we need to find the number of moles of CO2 and H2O produced by the combustion of 0.1000 g of the compound:
moles of CO2 = 0.2921 g / 44.01 g/mol = 0.006639 mol
moles of H2O = 0.0951 g / 18.02 g/mol = 0.005275 mol
Next, we need to find the number of moles of C and H in the compound. From the combustion reactions, we know that all of the carbon in the compound is converted to CO2, and all of the hydrogens are converted to H2O.
Therefore, the number of moles of C and H in the compound is equal to the number of moles of CO2 and H2O produced, respectively:
moles of C = 0.006639 mol
moles of H = 0.005275 mol
Finally, we need to find the number of moles of O in the compound. We can do this by subtracting the number of moles of C and H from the total number of moles of elements in the compound, which is equal to the mass of the compound divided by its molar mass:
moles of O = (0.1000 g / molar mass of compound) - moles of C - moles of H
The molar mass of the compound is equal to the sum of the molar masses of its constituent elements:
molar mass of compound = molar mass of C + molar mass of H + molar mass of O
Since we don't know the formula of the compound yet, we can assume a generic formula of CxHyOz and calculate the molar mass of this compound as:
molar mass of compound = x(molar mass of C) + y(molar mass of H) + z(molar mass of O)
Using the atomic masses of C, H, and O, we can calculate the molar masses of these elements as:
molar mass of C = 12.01 g/mol
molar mass of H = 1.01 g/mol
molar mass of O = 16.00 g/mol
Substituting these values, we get:
molar mass of compound = 12.01x + 1.01y + 16.00z
Now, we can solve for the number of moles of O in the compound:
moles of O = (0.1000 g / molar mass of compound) - moles of C - moles of H
Substituting the values we found earlier for moles of C and H, we get:
moles of O = (0.1000 g / (12.01x + 1.01y + 16.00z)) - 0.006639 mol - 0.005275 mol
Simplifying, we get:
moles of O = 0.1000 g / (12.01x + 1.01y + 16.00z) - 0.011914 mol
To determine the empirical formula of the compound, we need to find the smallest whole number mole ratio of the elements in the compound. We can do this by dividing the number of moles of each element by the smallest number of moles:
moles of C / 0.005275 = 1.259
moles of H / 0.005275 = 1.000
moles of O / 0.005275 = (0.1000 g / (12.01x + 1.01y + 16.00z) - 0.011914 mol) / 0.005275
Simplifying, we get:
moles of O / 0.005275 = 18.998 - (1.258x + y)
To find the smallest whole number ratio, we can multiply each mole ratio by a common factor that makes the smallest ratio a whole number. In this case, the smallest ratio is 1:1, so we can multiply each ratio by a factor of approximately 0.79 to make the C and H ratios both equal to 1. This gives us:
C: 1.000
H: 0.790
O: 1.484
Since we want whole numbers, we can round these ratios to the nearest whole number, giving us the empirical formula: C1H1O1 or simply CHO.
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which gas is not an example of a naturally occurring greenhouse gas? responses methane methane chlorofluorocarbon chlorofluorocarbon nitrous oxide nitrous oxide water vapor
Chlorofluorocarbon (CFC) is not an example of a naturally occurring greenhouse gas.
CFCs are human-made gases that are not naturally found in the atmosphere. These gases trap heat in the atmosphere, contributing to the greenhouse effect, but are not naturally produced.
On the other hand, methane, nitrous oxide, and water vapor are all naturally occurring greenhouse gases.
Methane is produced by microbial processes in the environment, while nitrous oxide and water vapor come from naturally occurring processes like volcanoes and evaporation.
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which of the following will affect the vapor pressure of a pure molecular substance? select all that apply. multiple select question. the external pressure the structure of the substance the strength of the intermolecular forces the temperature
As temperature increases, vapor pressure of substance also increases due to an increase in kinetic energy of the molecules. The correct answers are options: 1, 2, 3, 4.
As temperature increases, vapor pressure of a substance also increases due to an increase in kinetic energy of molecules Substances with stronger intermolecular forces will have lower vapor pressure because it requires more energy to break bonds between molecules and transition into gas phase. An increase in external pressure will decrease vapor pressure. Molecular size and shape of a substance can affect intermolecular forces and therefore its vapor pressure. For example, larger molecules tend to have stronger intermolecular forces, which result in lower vapor pressures. Options are 1, 2, 3, 4 correct .
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--The complete Question is, which of the following will affect the vapor pressure of a pure molecular substance?
select all that apply.
1. the external pressure
2. the structure of the substance
3. the strength of the intermolecular forces
4. the temperature
5. the weather conditions--
what is the balanced form of equation for Sodium plus chlorine equals to sodium chloride
Answer:
Na (s) + Cl2 (g) → NaCl (s)
Explanation:
A reaction of sodium with chlorine to produce sodium chloride is an example of a combination reaction. 2 Na + Cl 2 → 2 NaCl.
The equilibrium constant, Kc, for the following reaction is 11.8 at 752 K. 2NH3(g) N2(g) + 3H2(g) Calculate Kc at this temperature for the following reaction: 1/2N2(g) + 3/2H2(g) NH3(g) The equilibrium constant, Kc, for the following reaction is 5.70 at 719 K. 2NH3(g) N2(g) + 3H2(g) Calculate Kc at this temperature for the following reaction: NH3(g) 1/2N2(g) + 3/2H2(g)
The equilibrium constant for the new reaction at 752 K is approximately 0.29 and at 719 K is approximately 0.42.
Step wise explanation:
1) For the first reaction, the equilibrium constant (Kc) is given as 11.8 at 752 K for the reaction:
[tex]2NH_{3}[/tex](g) ⇌ [tex]N_{2}[/tex](g) + [tex]3H_{2}[/tex](g)
You are asked to calculate Kc for the following reaction:
[tex]1/2N_{2} + 3/2H_{2}[/tex] ⇌ [tex]NH_{3}[/tex](g)
To find Kc for the new reaction, note that it is the reverse of the original reaction with all coefficients divided by 2. To calculate the equilibrium constant for the reverse reaction, take the reciprocal of the original Kc, and then raise it to the power of the coefficients ratio (1/2):
Kc (new) =[tex]\sqrt{ (1 / Kc (original))}[/tex] = [tex]\sqrt{(1 / 11.8)}[/tex] ≈ 0.29
So, the equilibrium constant for the new reaction at 752 K is approximately 0.29.
2) For the second reaction, the equilibrium constant (Kc) is given as 5.70 at 719 K for the reaction:
[tex]2NH_{3}[/tex](g) ⇌ [tex]N_{2}[/tex](g) + [tex]3H_{2}[/tex](g)
You are asked to calculate Kc for the following reaction:
[tex]NH_{3}[/tex](g) ⇌ [tex]1/2N_{2}[/tex](g) + [tex]3/2H_{2}[/tex](g)
This new reaction is the reverse of the original reaction with all coefficients divided by 2. Similar to the first case, take the reciprocal of the original Kc and then raise it to the power of the coefficients ratio (1/2):
Kc (new) = [tex]\sqrt{(1 / Kc (original))}[/tex] = [tex]\sqrt{(1 / 5.70)}[/tex] ≈ 0.42
So, the equilibrium constant for the new reaction at 719 K is approximately 0.42.
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a desulfurization reaction involves the conversion of a thioacetal to an alkane by treating the thioacetal with raney nickel. during the reaction, the sulfur atoms of the thioacetal are replaced by hydrogen atoms. desulfurization reactions are a type of:
A desulfurization reaction is a type of hydrogenation reaction, where sulfur atoms in a compound are replaced by hydrogen atoms. In a desulfurization reaction, a thioacetal is treated with Raney nickel, resulting in the conversion of the thioacetal to an alkane.
Desulfurization reactions are a type of chemical reaction that involves the conversion of a thioacetal to an alkane by treating the thioacetal with raney nickel. During the reaction, the sulfur atoms of the thioacetal are replaced by hydrogen atoms.
Desulfurization is the process of converting sulfur-containing chemicals into non-sulfur containing substances by means of a chemical reaction. It is applied in refineries and in the petrochemical industry to lower sulfur emissions. Sulfur emissions contribute to acid rain and other environmental problems.
Therefore, desulfurization is an essential process for reducing pollution caused by sulfur dioxide emissions. In conclusion, desulfurization reactions are a type of chemical reaction that involves the replacement of sulfur atoms with hydrogen atoms. They are used in the petrochemical industry to reduce sulfur emissions and prevent environmental pollution caused by acid rain and other environmental problems.
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if the rate constant for a reaction triples when the temperature rises from 25 oc to 65 oc, what is the activation energy of the reaction? give answer in kj/mole.
The activation energy of the reaction, given that the rate constant has tripled when the temperature rose from 25 °C to 65 °C, is 42.6 kJ/mole.
Activation energy is the minimum energy required for a reaction to take place. It is calculated using the Arrhenius equation, which states that the rate constant, k, is proportional to the exponential of negative activation energy (Ea) divided by the gas constant (R) multiplied by the absolute temperature (T).
As the rate constant has tripled when the temperature increased, the activation energy can be calculated as Ea = -R * (1/T2 - 1/T1).
Plugging in the given temperature values of 25 °C and 65 °C and the gas constant, R, the activation energy is 42.6 kJ/mole.
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which of the combinations below will produce an insoluble salt? a) ba(oh)2 hcl b) mnso4 pb(no2)2 c) h2so4 albr3
The combination that will produce an insoluble salt is b) MnSO4 Pb(NO2)2.
A salt is a chemical compound made up of cations (positively charged ions) and anions (negatively charged ions) (negatively charged ions). The ions must be combined in such a way that the sum of the charges is zero. NaCl is the most well-known saltand it is made up of sodium cations (Na+) and chloride anions (Cl-).MnSO4 Pb(NO2)2 is the answer since both of these elements are soluble. MnSO4 is a soluble substance that is sometimes used in the production of ceramics.
MnSO4 is often used as a nutritional supplement for animals since it is a good source of manganese. Pb(NO2)2 is a powder that is bright yellow, it has a molar mass of 325.2 g/mol. It is made up of two NO2 anions (negatively charged ions) and one Pb2+ cation (positively charged ion).The formation of insoluble salts can occur when the cations and anions in a reaction solution bind to create a new solid. Since the newly formed solid is insoluble, it settles to the bottom of the solution and can be separated from the liquid through filtration. The insoluble salt that is formed is a white or colorless substance that appears as a powder.
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how many ml of alcohol and how many ml of water are needed to prepare a 35% alcohol solution containing 15.0 ml alcohol
To prepare a 35% alcohol solution containing 15.0 ml of alcohol, you will need 27.9 ml of water and 15 ml of alcohol.
To calculate this, you can use the equation C1V1 = C2V2, where C1 is the concentration of the alcohol (in this case, 35%), V1 is the volume of alcohol you need (15 ml), C2 is the desired concentration of the solution (35%), and V2 is the total volume of the solution (25 ml).
To prepare a 35% alcohol solution containing 15.0 ml alcohol, you will require 27.9 ml of water. The amount of alcohol and water required to prepare a 35% alcohol solution containing 15.0 ml alcohol is given below:
Given data:
Volume of alcohol = 15 ml% of alcohol = 35%Let us find the amount of water required.
Volume of solution = Volume of alcohol + Volume of waterUsing the above formula, Volume of solution = 15 + Volume of water
Let us find the percentage of water in the solution.
35% alcohol solution implies that the solution contains 35 ml of alcohol in 100 ml of solution. Therefore, the amount of solution that contains 1 ml of alcohol is:
1 ml of alcohol = (100 / 35) ml of solution = 20 / 7 ml of solution= 2.86 ml of solution.Therefore, the amount of solution required to prepare 15 ml of alcohol is:
15 ml of alcohol = 15 × (2.86 ml of solution) = 42.9 ml of solution.Using the formula for volume of solution, 42.9 ml of solution = 15 ml of alcohol + Volume of water.
Volume of water = 42.9 ml of solution - 15 ml of alcohol= 27.9 ml.Therefore, you will require 15 ml of alcohol and 27.9 ml of water to prepare a 35% alcohol solution containing 15 ml of alcohol.
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in an equilibrium mixture at 500k, the partial pressure of pcl 5 is 0.860 atm, pcl 3 is 0.350 atm, and cl 2 is 1.22 atm. calculate the equilibrium constant (k p ) for this reaction.
0.493 is the equilibrium constant (k p ) for [tex]PCl_5[/tex] (g) ⇌ [tex]PCl_3[/tex] (g) + [tex]Cl_2[/tex] (g) reaction at 500k.
The reaction is given as
[tex]PCl_5[/tex] (g) ⇌ [tex]PCl_3[/tex] (g) + [tex]Cl_2[/tex] (g)
At 500 K, the partial pressure of [tex]PCl_5[/tex] is 0.860 atm, [tex]PCl_3[/tex] is 0.350 atm, and [tex]Cl_2[/tex] is 1.22 atm.
To calculate the equilibrium constant ([tex]K_P[/tex]) for this reaction, we need to use the equation
[tex]K_P[/tex] = [[tex]PCl_3[/tex]] [[tex]Cl_2[/tex]] / [[tex]PCl_5[/tex]]
Here, [[tex]PCl_5[/tex]] = 0.860 atm
[[tex]PCl_3[/tex]] = 0.350 atm
[[tex]Cl_2[/tex]] = 1.22 atm
Substituting these values, we get
[tex]K_P[/tex] = (0.350)(1.22) / 0.860
[tex]K_P[/tex] = 0.493
Therefore, the equilibrium constant ([tex]K_P[/tex]) for this reaction at 500 K is 0.493.
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what would be the unit of measurement for a surface area that has degrees farenheit as the height and time as the width?
The unit of measurement for a surface area that has degrees Fahrenheit as the height and time as the width would be square degrees Fahrenheit x time.
Surface area is a measurement of the total area that the surface of an object occupies. The surface area is measured in square units. If the surface of an object is rectangular or square, it is calculated by multiplying the length of the object by the width of the object. For the curved surfaces, the formula for the surface area is complicated. However, the concept of square units remains the same for curved surfaces.
Fahrenheit is a unit of temperature that is used to measure the temperature of an object. This is used primarily in the United States and other countries that have adopted the Imperial system of units. It is based on a scale of 180 degrees between the freezing and boiling points of water, where the freezing point is 32°F and the boiling point is 212°F.
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4. a laboratory experiment calls for 0.150 m hno3. what volume of 0.150 m hno3 can be prepared form 0.350 l of 1.98 m hno3?
The volume of 0.150 M HNO3 that can be prepared from 0.350 L of 1.98 M HNO3 is 0.07112 L, or approximately 71.12 mL (since 1 L = 1000 mL).
The given equation is used to calculate the volume (V1) of a desired concentration of a solution (0.150 M HNO3) that can be prepared from a given volume (V2) of a known concentration solution (1.98 M HNO3), using the ratios of their concentrations (C1 and C2).
Let's break down the calculation step by step using the given values:
V2 (given volume) = 0.350 L
C1 (desired concentration) = 0.150 M
C2 (known concentration) = 1.98 M
Plugging these values into the equation, we get:
V1 (0.150 M HNO3) = V2 (1.98 M HNO3) x (C1 (0.150 M) / C2 (1.98 M))
V1 = 0.350 L x (0.150 M / 1.98 M)
V1 = 0.350 L x 0.0758
V1 = 0.07112 L
Therefore, the volume of 0.150 M HNO3 that can be prepared from 0.350 L of 1.98 M HNO3 is 0.07112 L, or approximately 71.12 mL (since 1 L = 1000 mL).
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in which scenario would we be unable to treat the first and second ionization of a diprotic acid as completely separate reactions?
The first and second ionization of a diprotic acid cannot be treated as completely separate reactions when the reaction is taking place in an environment with a fixed pH.
The second ionization of the acid is dependent on the concentration of the ions produced from the first ionization.
If the pH is fixed, then the concentration of the first ionization is also fixed, so the second ionization will not occur completely independently.
For example, a diprotic acid such as oxalic acid can be completely ionized in two steps. In the first ionization, the hydrogen ions of the oxalic acid are replaced with hydroxide ions, forming the oxalate ion:
H2C2O4 + 2H2O → H3O+ + HC2O4–
In the second ionization, the oxalate ion is further dissociated, forming two separate anions and hydronium ions:
HC2O4– + H2O → H3O+ + C2O4–2
However, in an environment with a fixed pH, the second ionization will not take place as the concentration of oxalate ions from the first ionization is fixed.
Therefore, the two ionizations must be treated together in order to accurately predict the final concentrations of the products.
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Answer:
The first ionization constant is greater than the second ionization constant by only a factor of 10.
Explanation:
The two ionization constants must differ by a factor of at least 20 in order to treat the first and second ionizations as chemically (and mathematically) distinct.
A gas sample at constant pressure and temperature filled with Helium gas had a volume of 221 mL and 4.00 moles. If the volume is increased to 500 ml what is the number of moles of Helium gas that could occupy the container? 0.11 K 9.05 kPa 0.11 kPa 9.05 mol
The number of moles of Helium gas that could occupy the container when the volume is increased to 500 mL is 9.05 mol.
What is the number of moles of the gas?We can use the combined gas law to solve this problem:
(P1 x V1) / (n1 x T1) = (P2 x V2) / (n2 xT2)
where;
P is pressure, V is volume, n is number of moles, and T is temperature.We know that the pressure and temperature are constant, so we can simplify the equation to:
V1/n1 = V2/n2
Solving for n2, we get:
n2 = (V2n1) / V1
Plugging in the values, we get:
n2 = (500 mL * 4.00 mol) / 221 mL
n2 = 9.05 mol
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if 0.0200 m fe3 is initially mixed with 1.00 m oxalate ion, what is the concentration of fe3 ion at equilibrium?
If 0.0200 m fe3 is initially mixed with 1.00 m oxalate ion, then concentration of Fe3+ ion at equilibrium is 0 M.
The balanced chemical equation for the reaction of Fe3+ ion and oxalate ion is:
Fe3+ + 3C2O42- -> Fe(C2O4)33-
The reaction quotient, Qc, for the above reaction is given by the expression:
Qc = [Fe(C2O4)33-]/[Fe3+][C2O42-]
Here, the initial concentration of Fe3+ ion
= 0.0200 m
And, the initial concentration of oxalate ion is 1.00 m . According to the stoichiometry of the balanced equation, 1 mole of Fe3+ ion reacts with 3 moles of C2O42- ions to form 1 mole of Fe(C2O4)33- complex ion. Hence, the concentration of C2O42- ion that reacts with the given initial concentration of Fe3+ ion is given by the expression: [C2O42-] = 3[Fe3+] = 3 x 0.0200 m = 0.0600 m. After the reaction comes to equilibrium, let the concentration of Fe3+ ion be x M.Now, [Fe(C2O4)33-] = 0 M (as the entire Fe3+ ion is converted into Fe(C2O4)33- complex ion)Substituting the given and calculated values in the expression for Qc, we get:
Kc = [Fe(C2O4)33-]/[Fe3+][C2O42-]
=> 0/[x][0.0600]
=> 0x
=> 0 M
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a solution of cacl2 cacl 2 in water forms a mixture that is 31.5% 31.5 % calcium chloride by mass. if the total mass of the mixture is 195.4 g, 195.4 g, what masses of cacl2 cacl 2 and water were used?
The masses of calcium chloride (CaCl2) and water used to form the mixture are 61.18 g and 134.22 g, respectively.
The mass of calcium chloride (CaCl2):
The percentage of calcium chloride (CaCl2) in the mixture is 31.5%.
Multiply the total mass of the mixture (195.4 g) by 31.5% to find the mass of calcium chloride (CaCl2) in the mixture:
Mass of calcium chloride (CaCl2) = (195.4 g) x (31.5%) = 61.18 g
The mass of water:
Subtract the mass of calcium chloride (CaCl2) from the total mass of the mixture (195.4 g) to find the mass of water in the mixture:
Mass of water = (195.4 g) - (61.18 g) = 134.22 g
Therefore, masses of calcium chloride (CaCl2) and water used to form the mixture are 61.18 g and 134.22 g, respectively.
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A mixture of 90. 0grams of ch4 and 10. Ograms of argon has a pressure of 250 torr under the condition of constant temperature and pressure the partial pressure of ch4 is
The partial pressure of CH₄ in the mixture is 239 torr.
We can use the mole fraction of methane (CH4) to calculate its partial pressure in the mixture. First, we need to convert the masses of each component into moles:
moles of CH₄ = 90.0 g / 16.04 g/mol = 5.61 mol
moles of Ar = 10.0 g / 39.95 g/mol = 0.250 mol
Next, we can calculate the total moles of gas in the mixture,
total moles = moles of CH₄ + moles of Ar = 5.61 mol + 0.250 mol = 5.86 mol
Now we can calculate the mole fraction of CH₄,
mole fraction of CH₄ = moles of CH₄ / total moles = 5.61 mol / 5.86 mol = 0.957
Finally, we can use the mole fraction and total pressure to calculate the partial pressure of CH₄,
partial pressure of CH₄ = mole fraction of CH₄ x total pressure = 0.957 x 250 torr = 239 torr
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Valdez notices that a wooden door in his house is difficult to open in the summer, but not in the winter. Valdez explains to Tony that the temperature of the door changes throughout the year. Tony says there is no way to measure the temperature of a solid because solids do not have a lot of thermal expansion. Valdez disagrees. Develop an argument supporting or opposing Tony's claim. Support your argument with at least two pieces of evidence.
I would argue against Tony's claim that the temperature of a solid cannot be measured, just because solids do not have a lot of thermal expansion.
What is thermal expansion?Thermal expansion is the tendency of materials to change in size, shape, or volume in response to changes in temperature.
There are several ways to measure the temperature of solids. One common method is to use a thermometer, which can be inserted into the solid to measure its temperature. Another method is to use an infrared thermometer, which measures the temperature of a solid by detecting the amount of infrared radiation it emits.
Second, while it is true that solids have a lower coefficient of thermal expansion than liquids or gases, they still expand and contract with changes in temperature. This is evident in Valdez's example of the wooden door, which becomes difficult to open in the summer when the temperature is higher, and easier to open in the winter when the temperature is lower. This change in the size of the door is due to thermal expansion and contraction of the wood.
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a sample of xe takes 75 seconds to effuse out of a container. an unknown gas takes 37 seconds to effuse out of the identical container under identical conditions. what is the most likely identity of the unknown gas?
The most likely identity of the unknown gas that effuses taking 37s is Oxygen(O₂).
Since the unknown gas effuses out faster, it must be lighter than Xe.
The most likely identity of the unknown gas can be determined using Graham's Law of Diffusion. According to this, the time taken for effusion/diffusion of two different gases under identical conditions is directly proportional to the square roots of their densities or molecular masses. It is given as:
t₂/t₁ = √(M₂/M₁)
where t₂,t₁ are the times taken and M₂, M₁ are the molecular masses.
This ratio is determined by the ratio of the molecular weights of the unknown gas and the sample of Xe. The heavier the molecular weight, the slower the rate of effusion.
Rearranging and plugging in the values as t₂= 75s, t₁= 37s, M₁= 131g (for Xe), we get M₂ as follows:
M₂= (37/75)² x 131 = 31.8 ≈ 32g
32g corresponds to the molecular weight of O₂ and it is lighter than Xe.
Therefore, the unknown gas that effuses out of the container faster than the sample of Xe, resulting in the unknown gas taking 37 seconds, and the sample of Xe taking 75 seconds is oxygen(O₂).
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g cyclohexane and 2 hexene have the same molecular formula what chemical test would you carry out to distinguish the two compounds provide a chemical equation for the reaction
To distinguish between cyclohexane and 2-hexene, you can carry out the bromine water test. Chemical equation for the reaction is 2-hexene + Br2 (aq) -> 2,3-dibromohexane
This test is based on the fact that cyclohexane is an alkane and 2-hexene is an alkene. Alkenes readily react with bromine water due to the presence of a double bond, while alkanes do not react.
Add a few drops of bromine water to separate test tubes containing cyclohexane and 2-hexene.
Observe the color change in the test tubes.
Chemical equation for the reaction:
2-hexene + Br2 (aq) -> 2,3-dibromohexane
Upon reaction, the bromine water loses its color in the presence of 2-hexene, while it remains the same in the presence of cyclohexane.
This difference in color change will help you distinguish between the two compounds.
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Indicate if the following pairs of compounds could be separated via liquid-liquid extraction.First, draw the structures of the compounds, next determine whether they are acids or bases or neutral. Finally, look up their pKa (or pKb) values and indicate which aqueous solution would separate them or if they are inseparable. Assume that you can utilize aqueous HCl, NaOH, or NaHCO3 for your extractions. For each case that will not work, give the reason.You don't have to draw structure, just explain if they are able to be separated or not and with what and why.1. picric acid and phenol2. salicyclic acid and phenol3. triethylamine and diethylamine4. 3-nitrobenzoic acid and 2-nitrobenzoic acid5. benzylamine and aniline
Picric acid and phenol, Salicylic acid and phenol & Benzylamine and aniline can be separated using liquid-liquid extraction but Triethylamine and diethylamine & 3-nitrobenzoic acid and 2-nitrobenzoic acid cannot be separated using liquid-liquid extraction.
1. Picric acid and phenol can be separated using liquid-liquid extraction. Picric acid is a stronger acid (pKa ~0.4) than phenol (pKa ~10). Adding aqueous NaOH will deprotonate picric acid and make it soluble in the aqueous layer, while phenol remains in the organic layer. Then, the two compounds can be separated.
2. Salicylic acid and phenol can also be separated using liquid-liquid extraction. Salicylic acid (pKa ~3) is more acidic than phenol (pKa ~10). Adding aqueous NaHCO3 will deprotonate salicylic acid, making it soluble in the aqueous layer, while phenol remains in the organic layer. The compounds can then be separated.
3. Triethylamine and diethylamine cannot be easily separated via liquid-liquid extraction, as both are bases (pKb values are similar). Aqueous HCl, NaOH, or NaHCO3 will not be effective in separating these compounds. Alternative separation methods, like distillation, may be needed.
4. 3-nitrobenzoic acid and 2-nitrobenzoic acid cannot be separated using liquid-liquid extraction, as they have similar acidity (pKa values are close) and will react similarly with HCl, NaOH, or NaHCO3. Alternative separation methods, like chromatography, should be considered.
5. Benzylamine and aniline can be separated using liquid-liquid extraction. Benzylamine is a weaker base (pKb ~4.2) than aniline (pKb ~9.4). Adding aqueous HCl will protonate aniline, making it soluble in the aqueous layer, while benzylamine remains in the organic layer. The two compounds can then be separated.
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potassium nitrate is used for a variety of applications, including fertilizer, rocket fuel, and fireworks. how many formula units of potassium nitrate are in a 25 g sample?
There are 1.49 × 10²³ formula units of potassium nitrate in a 25 g sample.
One formula unit is defined as the simplest formula of a substance, which indicates the relative amounts of the elements in the molecule. As a result, the number of formula units in a sample can be calculated by dividing the sample's mass by the substance's molar mass.
The molecular formula of potassium nitrate is KNO3. It contains one potassium atom (K), one nitrogen atom (N), and three oxygen atoms (O). The atomic masses of the elements can be used to calculate the molar mass of the compound.
One potassium atom has a molar mass of 39.1 g/mol, one nitrogen atom has a molar mass of 14.0 g/mol, and three oxygen atoms have a combined molar mass of 48.0 g/mol.
The molar mass of KNO3 = (1 × 39.1 g/mol) + (1 × 14.0 g/mol) + (3 × 16.0 g/mol) = 101.1 g/mol.
Now, on dividing the sample's mass (25 g) by the molar mass of potassium nitrate (101.1 g/mol), a value of 0.247 mol is obtained. The Avogadro constant can be used to convert moles into formula units. The Avogadro constant, 6.022 × 10²³ formula units per mole, represents the number of formula units in one mole of a substance.
The number of formula units = (0.247 mol) × (6.022 × 10²³ formula units/mol) = 1.49 × 10²³ formula units.
Therefore, there are 1.49 × 10²³ formula units of potassium nitrate in a 25 g sample.
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upon combustion, a compound containing only carbon and hydrogen produces 2.77 gco2 and 0.851 gh2o . find the empirical formula of the compound.
Answer:Gco is 0.953
Explanation:
onsider a process in which an ideal gas is compressed to one-fourth of its original volume at a constant temperature. calculate the entropy change per mole of gas.
The entropy change per mole of gas is -1.387R.
The entropy change per mole of gas in a process in which an ideal gas is compressed to one-fourth of its original volume at a constant temperature can be calculated as follows:
Let us denote the original volume as V₁, the final volume as V₂, and the number of moles of the gas as n. The entropy change can be calculated using the formula:
ΔS = nR ln (V₂/V₁)
Therefore, the entropy change per mole of gas is given by:
ΔSper mole = R ln (V₂/V₁)
In this case, V₁ = 4V₂ and so,
ΔSper mole = R ln (1/4) = - R ln 4 = -2.303 R log 4 = -1.387R
Thus, the entropy change per mole of gas when an ideal gas is compressed to one-fourth of its original volume at a constant temperature is -1.387R.
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when carbonates (co32-) or bicarbonates (hco3-) are reacted with an acid in an acid-base reaction, the resulting product is:
When carbonates (CO3^2-) or bicarbonates (HCO3^-) are reacted with an acid in an acid-base reaction, the resulting product is carbonic acid (H2CO3).
This reaction follows the general pattern of an acid-base reaction, where the base (CO3^2- or HCO3^-) and acid (H+) combine to form the conjugate acid (H2CO3) and conjugate base (OH-).
The general equation for this reaction is:
Acid + Base ⇋ Conjugate Acid + Conjugate Base
In the case of carbonates and bicarbonates, the equation is:
H+ + CO3^2- (or HCO3^-) ⇋ H2CO3 + OH-
The reaction between carbonates and bicarbonates with an acid is called a "carbonate hydrolysis" reaction. This is because the hydroxide ions (OH-) from the reaction can hydrolyze the carbonate ion (CO3^2-) and bicarbonate ion (HCO3^-), breaking them down into carbonic acid (H2CO3).
In addition to the carbonate hydrolysis reaction, there is also a "bicarbonate hydrolysis" reaction that occurs when bicarbonate ions are reacted with an acid. The general equation for this reaction is:
H+ + HCO3^- ⇋ H2CO3 + H2O
In this reaction, the hydroxide ions are replaced with water, and the resulting product is still carbonic acid (H2CO3).
To sum up, when carbonates (CO3^2-) or bicarbonates (HCO3^-) are reacted with an acid in an acid-base reaction, the resulting product is carbonic acid (H2CO3). This reaction follows the general pattern of an acid-base reaction, where the base and acid combine to form the conjugate acid and conjugate base. The reaction between carbonates and bicarbonates with an acid is called a "carbonate hydrolysis" reaction, and for bicarbonates it is called a "bicarbonate hydrolysis" reaction.
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calculate time in hours required for 99.9% of the 2-chloro-2-methylpropane to hydrolyze if reaction proceed at room temperature
By plugging in the values for each of the parameters and solving for t, the time required for 99.9% of the 2-chloro-2-methylpropane to hydrolyze can be determined.
The time required for 99.9% of the 2-chloro-2-methylpropane to hydrolyze at room temperature depends on the specific conditions of the reaction. Generally, it will take several hours for this reaction to occur.
To calculate the exact time required, we can use the Arrhenius equation, which is given as:
k = A*e(-Ea/RT)
Where:
k = rate constant for the reaction
A = pre-exponential factor
Ea = activation energy
R = gas constant
T = temperature
The values for each of the parameters and solving for t in the equation, the time required for 99.9% of the 2-chloro-2-methylpropane to hydrolyze can be determined.
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when looking down the c2-c3 bond of pentane, how many staggered conformations have the same representation (show the same orientation)?
When looking down the C2-C3 bond of pentane, the staggered conformations have the same representation (show the same orientation) there are three staggered conformations
Isomers are molecules with the same formula but a different spatial orientation of the atoms, meaning they have different shapes. Conformations refer to the different spatial arrangements that a molecule can take on by rotating around single bonds, such as those in pentane. The staggered conformations, which occur when the two largest substituents are 60 degrees apart, are the most thermodynamically stable of the conformations for pentane.
Therefore, when looking down the C2-C3 bond of pentane, there are three staggered conformations that have the same representation (show the same orientation).
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does any solid cu(oh)2 form when 0.075 g koh is dissolved in 1.0 l of 1.0 x 10 -3 m cu(no3)2? ksp of cu(oh)2
Yes, a solid Cu(OH)2 will form when 0.075 g KOH is dissolved in 1.0 L of 1.0 x 10^-3 M Cu(NO3)2. 0.107 g of solid Cu(OH)2 will form.
First, we need to determine the amount of Cu2+ ions present in the solution:
1.0 x 10^-3 M Cu(NO3)2 means that there are 1.0 x 10^-3 moles of Cu2+ ions per liter of solution.
Next, we can use stoichiometry to determine the amount of OH- ions that will react with the Cu2+ ions to form Cu(OH)2. The balanced chemical equation for this reaction is:
Cu2+ (aq) + 2OH- (aq) → Cu(OH)2 (s)
For every 1 mole of Cu2+ ions, we need 2 moles of OH- ions. Therefore, the total amount of OH- ions needed to react with all of the Cu2+ ions in the solution is:
2 x 1.0 x 10^-3 mol = 2.0 x 10^-3 mol
Now we can use the Ksp of Cu(OH)2 to calculate the concentration of Cu2+ and OH- ions in the solution. The Ksp expression for Cu(OH)2 is:
Ksp = [Cu2+][OH-]^2
Since we know the Ksp value for Cu(OH)2, we can solve for either [Cu2+] or [OH-]. Let's solve for [OH-]:
Ksp = [Cu2+][OH-]^2
4.8 x 10^-20 = (1.0 x 10^-3 M)[OH-]^2
[OH-]^2 = 4.8 x 10^-17
[OH-] = 2.2 x 10^-9 M
Therefore, the concentration of OH- ions in the solution is 2.2 x 10^-9 M. Since we need 2 moles of OH- ions for every mole of Cu2+ ions, we know that the concentration of Cu2+ ions is half of the concentration of OH- ions:
[Cu2+] = 1.1 x 10^-9 M
Finally, we can use the molar mass of Cu(OH)2 to determine the mass of solid that will form:
Molar mass of Cu(OH)2 = 97.56 g/mol
1 mole of Cu(OH)2 is formed for every mole of Cu2+ ions, so the mass of Cu(OH)2 that will form is:
0.0011 mol x 97.56 g/mol = 0.107 g
Therefore, 0.107 g of solid Cu(OH)2 will form when 0.075 g KOH is dissolved in 1.0 L of 1.0 x 10^-3 M Cu(NO3)2.
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