The Ammonium Chloride solution at 0.25 M has a pH of 2.67.
Why is the pH of Ammonium Chloride below 7?As a result, the weak basic (Chlorine) in the solution is overpowered by the conjugate acid (Ammonium cation), making the solution mildly acidic. According to the equation pH =log[Hydrogen ion], an acidic solution has a pH lower than 7. Aqueous ammonium chloride solution has a pH that is less than 7.
Ammonium cation + Water ⇌ Nitrogen trihydride + Hydronium ion
Kb = [Nitrogen trihydride][Hydronium ion] / [Ammonium cation]
[Nitrogen trihydride] = [Hydronium ion] = x
[Ammonium cation] = 0.25 - x
Kb = [Nitrogen trihydride][Hydronium ion] / [Ammonium cation]
1.8 × 10–5 = x² / (0.25 - x)
1.8 × 10–5 = x² / 0.25
x² = 4.5 × 10–6
x = 2.12 × 10–3
pH = -log[Hydronium ion] = -log(2.12 × 10–3) = 2.67
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At 25 ∘C
, the equilibrium partial pressures for the reaction
A(g)+2B(g)↽−−⇀C(g)+D(g)
were found to be A=5.63
atm, B=5.00
atm, C=5.47
atm, and D=5.63
atm.
What is the standard change in Gibbs free energy of this reaction at 25 ∘C
?
The standard change in Gibbs free energy of the reaction at 25 ∘C is -1.69 kJ/mol.
What is standard change?
To find the standard change in Gibbs free energy of the reaction, we need to use the following equation:
ΔG° = -RT ln(K)
where ΔG° is the standard change in Gibbs free energy, R is the gas constant (8.314 J/mol·K), T is the temperature in Kelvin (25 °C = 298 K), and K is the equilibrium constant.
To find K, we need to use the equilibrium partial pressures:
K = (PC × PD) / (PA × PB²)
where PA, PB, PC, and PD are the equilibrium partial pressures of A, B, C, and D, respectively.
Substituting the values, we get:
K = (5.47 atm × 5.63 atm) / (5.63 atm × (5.00 atm)²)
K = 0.6176
Now we can calculate the standard change in Gibbs free energy:
ΔG° = -RT ln(K)
ΔG° = -(8.314 J/mol·K) × (298 K) × ln(0.6176)
ΔG° = -1,690 J/mol or -1.69 kJ/mol
Therefore, the standard change in Gibbs free energy of the reaction at 25 ∘C is -1.69 kJ/mol.
What is free energy?
Free energy, also known as Gibbs free energy, is a thermodynamic quantity that represents the amount of energy in a system that is available to do work at a constant temperature and pressure. It is denoted by the symbol G and is expressed in units of joules (J) or calories (cal).
In simple terms, free energy is the energy that can be used to do work. It is defined by the equation:
ΔG = ΔH - TΔS
where ΔH is the change in enthalpy (heat content) of the system, ΔS is the change in entropy (disorder) of the system, and T is the absolute temperature in Kelvin.
If ΔG is negative, the reaction is spontaneous and can proceed without the input of external energy. If ΔG is positive, the reaction is non-spontaneous and requires energy input to proceed. If ΔG is zero, the system is at equilibrium.
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In the Periodic Table below, shade all the elements for which the neutral atom has an outer electron configuration of ms2nd2, where n and m are integers, and =m+n1.
The elements that have an outer electron configuration of ms2nd2 are located in the d-block of the periodic table and include some of the transition metals and lanthanides.
What is the periodic table?To determine which elements in the periodic table have this outer electron configuration, you can look at the position of the d-block elements in the table. The d-block elements are located in the middle of the table and include the transition metals. These elements have partially filled d orbitals, which can accommodate up to 10 electrons.
Elements in the d-block with an atomic number of 21 through 30 (scandium through zinc) have an outer electron configuration of d10s2 and do not fit the ms2nd2 configuration. However, elements in the d-block with an atomic number of 39 through 48 (yttrium through cadmium) have an outer electron configuration of d10s2p1 and can have the ms2nd2 configuration by removing the single electron in the p orbital. Elements in the d-block with an atomic number of 57 through 80 (lanthanum through mercury) also have the possibility of having an outer electron configuration of ms2nd2.
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What is true of spontaneous reactions?
O They are indicated by a negative change in Gibbs free energy.
O They have a positive value of AS.
O They are instantaneous.
O They always release heat.
Help 20pts
The two possible units of molarity are
Answer: The units for molarity are moles/liter.
Similarly, the equation to find molarity is moles divided by liters.
Explanation:
mol / L is a unit of molar concentration. These are the number of moles of dissolved material per liter of solution. 1 mol / L is also called 1M or 1molar. Mol / m3 is also a unit of molar concentration.
Molarity is expressed in units of moles per liter (mol / L). This is a very common unit, so it has its own symbol, which is the uppercase M. A solution with a concentration of 5 mmol / l is called a 5 M solution or has a concentration value of 5 mol.
The molar concentration of the solution is equal to the number of moles of the solute divided by the mass of the solvent (kilogram), and the molar concentration of the solution is equal to the number of moles of the solute divided by the volume of the solution (liter). increase.
What happens when a solid is dissolved into a liquid?
.
CaCO3 + 2HCI =CaCl2 + H₂O + CO2
5. Calcium carbonate (CaCO3) combines with HCl to produce calcium chloride (CaCl₂),
water, and carbon dioxide gas (CO₂). How many grams of HCI are required to react with
6.35 mol CaCO3?
463.5 grams of HCl are required to react with 6.35 moles of CaCO₃.
What is meant by molar mass?Mass of one mole of substance is referred to as the molar mass. The molar mass of a substance can be calculated by adding up the atomic masses of all the atoms in a molecule.
Balanced chemical equation for the reaction between calcium carbonate (CaCO₃) and hydrochloric acid (HCl) is: CaCO₃ + 2HCl → CaCl₂ + H₂O + CO₂
6.35 mol CaCO₃ * 2 mol HCl / 1 mol CaCO₃ = 12.7 mol HCl
Now, we use the molar mass of HCl (36.46 g/mol) to convert from moles to grams: 12.7 mol HCl * 36.46 g/mol = 463.5 g HCl
Therefore, 463.5 grams of HCl are required to react with 6.35 moles of CaCO₃.
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A flask filled to the 25.0 ml mark contain 29.97 g of a concentrated salt water solution. What is the density of the solution?
A concentrated saltwater solution weighing 29.97 g and fitting into a flask to the mark of 25.0 ml has a density of about 1199.2 g/L.
How is the density of the solution determined?By dividing the solution's mass by its volume, we may get its density: density = mass/volume
We need to know the density of water at the solution's temperature as well as the capacity of the flask up to the 25.0 ml level in order to calculate the volume of the solution.
Since 1 mL = 0.001 L, volume is equal to 25.0 mL, or 0.0250 L.
Now, we may determine the solution's density as follows:
1199.2 g/L or 29.97 g/0.0250 L is what is referred to as density.
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