An ester is mixed with LiNHCH3 in order to perform a SNAc mechanism. What is the LUMO in this reaction?
A. N p orbital
B. C-N σ bond
C. C-O σ* bond
D. C-O π* bond

Answers

Answer 1

The LUMO for the reaction when an ester is mixed with [tex]LiNHCH_{3}[/tex] is D. C-O π* bond.

What will be the LUMO in an SNAc mechanism?

In the SNAc (nucleophilic acyl substitution) mechanism, the nucleophile (LiNHCH_{3}) attacks the carbonyl carbon of the ester, and the LUMO in this reaction is the lowest unoccupied molecular orbital, which is the C-O π* bond.

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Related Questions

which of the following is the most likely range of values for human body density? a. 0.900 - 1.100 g/cc b. 1.09 - 1.105 g/cc c. 0.99 - 1.02 g/cc d. 1.02-1.08 g/cc

Answers

The most likely range of values for human body density is 0.900 - 1.100 g/cc.(A)

Option (b) 1.09 - 1.105 g/cc is not the most likely range of values for human body density.

Option (c) 0.99 - 1.02 g/cc and option (d) 1.02-1.08 g/cc are also not the most likely range of values for human body density.

Body density is the mass of the human body divided by the volume it occupies. The density of the human body depends on the mass and volume of the body's internal organs, muscle mass, and the amount of adipose tissue present in the body.

The density of the human body typically ranges from 0.900 g/cc to 1.100 g/cc. This range may vary depending on several factors, including age, gender, body composition, and other health factors.

However, the most likely range of values for human body density is 0.900 - 1.100 g/cc.

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a vessel contains 112 1 2 l of milk. john drinks 14 1 4 l of milk; joe drinks 12 1 2 l of milk. how much of milk is left in the vessel?

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There is 73 3/4 liters of milk left in the vessel.

John drank 14 1/4 liters of milk and Joe drank 12 1/2 liters of milk. This means that a total of 26 3/4 liters of milk was consumed from the vessel. 112 1/2 liters of milk was the total amount of milk in the vessel, so if we subtract the 26 3/4 liters that was consumed from the vessel, we can calculate the remaining amount of milk left in the vessel.

Calculate the total amount of milk that was consumed.

John drank 14 1/4 liters of milk and Joe drank 12 1/2 liters of milk. This means that a total of 26 3/4 liters of milk was consumed from the vessel.

Calculate the amount of milk left in the vessel.

The total amount of milk in the vessel was 112 1/2 liters. If we subtract the 26 3/4 liters that was consumed from the vessel, we can calculate the remaining amount of milk left in the vessel: 112 1/2 liters - 26 3/4 liters = 73 3/4 liters.


In this problem, we needed to calculate the amount of milk left in the vessel after two people drank from it. We did this by first calculating the total amount of milk that was consumed (John drank 14 1/4 liters of milk and Joe drank 12 1/2 liters of milk). Then, we calculated the remaining amount of milk left in the vessel by subtracting the amount of milk consumed from the total amount of milk in the vessel (112 1/2 liters - 26 3/4 liters = 73 3/4 liters).

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the buret will be filled with 0.3000 m hcl and 25 ml of 0.40 m nahco3 solution will be in the beaker with methyl orange as the indicator. write a complete balanced equation for the neutralization reaction between hcl and nahco3.

Answers

The complete balanced equation for the neutralization reaction between HCl and NaHCO₃ is:

HCl + NaHCO₃ → NaCl + H₂O + CO₂

The reaction between hydrochloric acid (HCl) and sodium bicarbonate (NaHCO₃) is known as a neutralization reaction. In this reaction, HCl and NaHCO₃ combine to produce NaCl, water, and carbon dioxide.

The reaction can be represented by the following equation: HCl + NaHCO₃ → NaCl + H₂O + CO₂

This reaction already the balanced chemical equation for the reaction since the number of each element in the reactant side is equal to the number of each element in the product side.

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the student then prepares a solution using four pellets of naoh dissolved to 100.00 ml in a volumetric flask. the student slowly adds this to the khp solution to perform a titration. it requires 22.50 ml of the naoh solution to reach the endpoint. what is the molarity of the naoh solution based on this titration?

Answers

The volume of NaOH solution used in the titration is 22.50 mL or 0.0225 L. The molarity of the NaOH solution is 0.210 mol/L.

To determine the molarity of the NaOH solution, we can use the balanced chemical equation for the reaction between NaOH and KHP:

NaOH + KHP → NaKP + H2O

From the equation, we can see that one mole of NaOH reacts with one mole of KHP. Therefore, the number of moles of NaOH used in the titration can be calculated by:

moles NaOH = molarity of NaOH solution × volume of NaOH solution used (in liters)

The volume of NaOH solution used in the titration is 22.50 mL or 0.0225 L.

To calculate the molarity of the NaOH solution, we need to determine the number of moles of NaOH used in the titration. From the balanced equation, we can see that one mole of KHP reacts with one mole of NaOH. The mass of KHP used in the titration is 0.969 g, which corresponds to the number of moles of KHP used:

moles KHP = mass of KHP / molar mass of KHP

= 0.969 g / 204.22 g/mol

= 0.004738 mol

Since the stoichiometry of the reaction is 1:1, the number of moles of NaOH used in the titration is also 0.004738 mol. Substituting these values into the above equation, we get:

0.004738 mol = molarity of NaOH solution × 0.0225 L

Solving for the molarity of the NaOH solution, we get:

molarity of NaOH solution = 0.004738 mol / 0.0225 L

= 0.210 mol/L

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if a reaction is 1st order, how many half-lives are required for 99.9% of the original sample to be consumed?

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In a first-order reaction, time required for completion of 99.9% is 10 times of half-life (t1/2) of the reaction.

In a first-order reaction, the rate of the reaction is inversely correlated with the concentration of the reactant. In other words, if the concentration doubles, so does the pace of the reaction. The half-life of a reaction is defined as the amount of time it takes for half of the reactant to be consumed. The half-life of a first-order reaction is given by:

t1/2 = 0.693/k

where k is the rate constant of the reaction.

The chemical kinetics rate law, which connects the molar concentration of reactants to reaction rate, uses the rate constant as a proportionality factor. The letter k in an equation designates it, which is also referred to as the reaction rate constant or reaction rate coefficient.

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a mixture of gases can be described as a solution because it is a homogeneous mixture that has a uniform composition throughout at the molecular level TRUE/FALSE

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The given statement "a mixture of gases can be described as a solution because it is a homogeneous mixture that has a uniform composition throughout at the molecular level" is true because  properties of the mixture are the same throughout, and the composition of the mixture does not vary from one part to another.

A mixture of gases can be described as a solution because it is a homogeneous mixture, meaning that the composition is uniform throughout the mixture. This is true at the molecular level because the gases are thoroughly mixed, and the molecules of each gas are distributed evenly throughout the mixture.

Therefore, the properties of the mixture are the same throughout, and the composition of the mixture does not vary from one part to another.

Thus the given statement  "a mixture of gases can be described as a solution because it is a homogeneous mixture that has a uniform composition throughout at the molecular level" is true.

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11. calculate the volume of hcl that fully reacted with the calcium carbonate, showing all steps. note: this is not the total volume of hcl initially added nor is it the amount needed to neutralize the titrant!

Answers

Calculating the volume of HCl that fully reacted with calcium carbonate, the following steps should be followed:

Step 1: Write the balanced chemical equation for the reaction between HCl and calcium carbonate.

CaCO3 + 2HCl → CaCl2 + CO2 + H2O

Step 2: Calculate the molar mass of CaCO3.CaCO3: 1(40.08) + 1(12.01) + 3(16.00) = 100.09 g/mol

Step 3: Calculate the moles of CaCO3 used.

Mass of CaCO3 used = 0.548 g

Moles of CaCO3 used = 0.548 g / 100.09 g/mol = 0.00548 mol

Step 4: Use the balanced chemical equation to determine the moles of HCl required to react completely with the CaCO3. According to the balanced equation, 2 moles of HCl react with 1 mole of CaCO3.

Therefore, the number of moles of HCl required is:

2 mol HCl/mol CaCO3 × 0.00548 mol CaCO3 = 0.01096 mol HCl

Step 5: Calculate the volume of HCl required to provide this number of moles. The molarity (M) of the HCl solution is given as 0.101 M.

Using the formula for molarity (M = moles of solute/liters of solution), we can rearrange the equation to solve for volume.

The volume of HCl = moles of solute / molarity= 0.01096 mol / 0.101 mol/L = 0.1086 L or 108.6 mL

Therefore, the volume of HCl that fully reacted with the calcium carbonate is 108.6 mL.

Note that this is not the total volume of HCl initially added nor is it the amount needed to neutralize the titrant.

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assuming ideal behavior, how many liters hcl gas are required to make concentrated hydrochloric acid (11.6 mol/l) at 25oc and 1 atm pressure?

Answers

520.67 liters of HCl gas are required to make concentrated hydrochloric acid (11.6 mol/L) at 25°C and 1 atm pressure. while assuming ideal behavior.

To make concentrated hydrochloric acid (11.6 mol/L) at 25°C and 1 atm pressure, the volume of HCl gas needed is 520.67 L.

Assuming ideal behavior,

Molarity (M) = number of moles of solute/volume of solution in liters (L)

Given:

Molarity (M) = 11.6 mol/L

Volume of solution (V) = ?

Temperature (T) = 25°C

Pressure (P) = 1 atm

We can use the ideal gas law to find the volume of HCl gas required to make 1 L of concentrated HCl. Then, we can use this value to find the volume of HCl gas required to make a certain volume of concentrated HCl. The ideal gas law is given as:

PV = nRT

where: P is pressure, V is volume of the gas, n is the number of moles of gas, R is the gas constant, T is the temperature. We can rearrange the ideal gas law to solve for volume:

V = nRT/PAt

standard temperature and pressure (STP), 1 mole of an ideal gas occupies 22.4 L.

Therefore, the number of moles of HCl gas required to make 1 L of concentrated HCl is given as:

11.6 mol/L × 1 L = 11.6 moles

We can substitute these values into the ideal gas law equation and solve for the volume of HCl gas required to make 1 L of concentrated HCl:

V = nRT/PV = (11.6 mol) × (0.08206 L·atm/K·mol) × (298 K)/(1 atm)V

= 260.51 L

However, we are interested in finding the volume of HCl gas required to make a certain volume of concentrated HCl. We can use the following conversion factor to find the volume of HCl gas required:

1 L concentrated HCl = 260.51 L HCl gas

We can use dimensional analysis to solve for the volume of HCl gas required to make 1 L of concentrated HCl:

11.6 mol/L × 1 L concentrated HCl × (260.51 L HCl gas/1 L concentrated HCl) = 3020.37 L HCl gas

However, this calculation gives the volume of HCl gas required to make 1 L of concentrated HCl.

We are interested in finding the volume of HCl gas required to make a certain amount of concentrated HCl.

We can use the following formula to solve for the volume of HCl gas required to make a certain amount of concentrated HCl:

V2 = V1 × (M1/M2)

where:V1 is the volume of concentrated HCl needed

M1 is the molarity of concentrated HCl

M2 is the molarity of the HCl gas

V2 is the volume of HCl gas needed

We can substitute the given values into the formula and solve for

V2:V2 = (1 L) × (11.6 mol/L)/(0.08206 L·atm/K·mol × 298 K)V2

= 520.67 L

Therefore, 520.67 liters of HCl gas are required to make concentrated hydrochloric acid (11.6 mol/L) at 25°C and 1 atm pressure.

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calculate the osmotic pressure (in atm) at 17.4 degrees c of a solution made by dissolving 7.19 g of glucose in 18.9 ml of solution.

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The osmotic pressure of a solution made by dissolving 7.19 g of glucose in 18.9 ml of solution at 17.4°C can be calculated using the formula: Osmotic Pressure (atm) = Molarity (M) × Gas Constant (R) × Temperature (T).

Molarity = (Mass of Solute/ Molar Mass of Solute) / Volume of Solution
= (7.19 g / 180.2 g/mol) / 18.9 ml
= 0.3999 M

Gas Constant (R) = 0.08206 liter atm/mol K
Temperature (T) = 17.4°C + 273.15 = 290.55 K

Therefore, Osmotic Pressure (atm) = 0.3999 M × 0.08206 liter atm/mol K × 290.55 K
= 0.983 atm

The osmotic pressure of a solution is the hydrostatic pressure required to balance the osmotic pressure of a solution. This is determined by the concentration of the solute molecules, temperature, and the properties of the solvent. The osmotic pressure of a solution can be used to determine the boiling point, vapor pressure, and vapor pressure of a solution. Additionally, it is important for the transport of substances across biological membranes, as well as for the stability of colloidal suspensions.

In summary, the osmotic pressure (in atm) of a solution made by dissolving 7.19 g of glucose in 18.9 ml of solution at 17.4°C can be calculated using the formula: Osmotic Pressure (atm) = Molarity (M) × Gas Constant (R) × Temperature (T), and is equal to 0.983 atm.

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What aldehyde is needed to prepare the carboxylic acid by an oxidation reaction?

Answers

Answer:

The oxidation of an aldehyde can be achieved using a variety of oxidizing agents, including potassium permanganate (KMnO4), chromium trioxide (CrO3), and silver oxide (Ag2O). The specific oxidizing agent used will depend on the conditions and desired yield.

For example, if we want to prepare acetic acid, we can oxidize ethanol (an alcohol) using a strong oxidizing agent like potassium permanganate. Alternatively, we can oxidize acetaldehyde (an aldehyde) using a milder oxidizing agent like silver oxide.

Therefore, any aldehyde can be used to prepare a carboxylic acid by oxidation, but the specific oxidizing agent and reaction conditions may vary depending on the aldehyde and desired yield.

The aldehyde that is need for the preparation of the acid is CH3(CH2)8CH(Cl)CHO

How do you prepare an acid from an aldehyde?

It is not possible to directly prepare an acid from an aldehyde as an aldehyde is already an oxidized form of a primary alcohol, which can be further oxidized to form a carboxylic acid.

Aldehydes can be oxidized to carboxylic acids using strong oxidizing agents such as potassium permanganate (KMnO4) or chromic acid (H2CrO4). The reaction conditions need to be carefully controlled to avoid over-oxidation of the aldehyde to carbon dioxide.

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what is the mass of sodium chloride required to create a 0.875 m solution 534 g of water. how many moles of nacl is required

Answers

The mass of sodium chloride that is required to create a 0.875 M solution 534 g of water is 27.291 g and 0.467 moles of NaCl is required.

Mass of water = 534 g

Molality of the solution = 0.875 m

Molality is the number of moles of solute per kilogram of solvent.

It is represented by the formula:

Molality = number of moles of solute / kilogram solvent

Its mathematical expression is:

m = n/kg

Now we will convert the g into kg.

Mass of water = 534 g× 1kg/1000 g = 0.534 kg

putting the values in formula:

0.875 m = n / 0.534 kg

n = 0.467 mol

Now we will calculate the mass of sodium chloride:

Mass = number of moles × molar mass

Mass = 0.467 mol × 58.44 g/mol

Mass = 27.291 g

Thus, the required mass and moles of NaCl are 27.291g and 0.467mol respectively.

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if 37.2 kj of energy is evolved when 100. g of glucose is fermented, what is the molar enthalpy of fermentation?

Answers

If 37.2 kJ of energy is evolved when 100g. So, the molar enthalpy of fermentation is 67 kJ/mol.

The molar enthalpy of fermentation can be calculated as follows:

From the equation, 1 mole of glucose yields 2 moles of ethanol and 2 moles of carbon dioxide. Thus, the balanced equation for this process is:

C₆H₁₂O₆ (aq)  → 2C₂H₅OH(aq) + 2CO₂ (g)

From the given values, the mass of glucose that was fermented is 100 g. The molar mass of glucose is 180.16 g/mol. Thus, the number of moles of glucose can be calculated as follows:

moles of glucose = Mass of glucose / Molar mass of glucose

moles of glucose = 100 g / 180.16 g/mol

moles of glucose = 0.555 moles

The molar enthalpy of fermentation is defined as the amount of energy released per mole of fermented glucose. Thus, the molar enthalpy of fermentation can be calculated as follows:

Molar enthalpy  = Energy released / moles of glucose

Molar enthalpy  = 37.2 kJ / 0.555 mol

Molar enthalpy  = 67 kJ/mol

Therefore, the molar enthalpy of fermentation is 67 kJ/mol.

Complete question:

The equation for the fermentation of glucose to ethanol and carbon dioxide is C6 H12 O6 (aq) 3,2CrN 5 OH(aq)+2CO 2 (g) If 37.2 kJ of energy is evolved when 100. g of glucose is fermented, what the molar enthalpy of fermentation?

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for the next several questions, use the following information: a 2.00 g sample of ammonia (nh3 ) reactants with 4.00 g of oxygen to form nitrogen monoxide and water. all of the reactants and products are gases. do not forget about diatomic molecules.

Answers

Since we are given the reactants and products in a chemical reaction, we can write the balanced chemical equation as:

4 NH3 + 5 O2 → 4 NO + 6 H2O

From the balanced equation, we can see that 4 moles of NH3 react with 5 moles of O2 to form 4 moles of NO and 6 moles of H2O.

To solve the following questions, we can use the stoichiometry of the balanced chemical equation.

How many moles of NH3 are in the sample?

The molar mass of NH3 is 17.03 g/mol, so the number of moles of NH3 in the sample is:

2.00 g / 17.03 g/mol = 0.1173 mol NH3

How many moles of O2 are in excess?

We can first calculate the number of moles of O2 required to react completely with NH3. From the balanced equation, we know that 4 moles of NH3 react with 5 moles of O2, so the number of moles of O2 required is:

0.1173 mol NH3 × (5 mol O2 / 4 mol NH3) = 0.1466 mol O2

The actual amount of O2 used is 4.00 g / 32.00 g/mol = 0.125 mol O2, so the number of moles of O2 in excess is:

0.125 mol O2 - 0.1466 mol O2 = -0.0216 mol O2

Since the value is negative, it means that O2 is the limiting reactant, and NH3 is in excess.

How many moles of H2O are produced?

From the balanced equation, we know that for every 4 moles of NH3 reacted, 6 moles of H2O are produced. Therefore, the number of moles of H2O produced is:

0.1173 mol NH3 × (6 mol H2O / 4 mol NH3) = 0.1760 mol H2O

What is the mass of NO produced?

The molar mass of NO is 30.01 g/mol, so the mass of NO produced is:

0.1173 mol NH3 × (4 mol NO / 4 mol NH3) × 30.01 g/mol = 3.52 g NO

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a certain combustion reaction generates 4.50 moles of carbon dioxide how many grams does this represent report your answer to 3 significant figures

Answers

If any combustion reaction generates 4.50 moles of carbon dioxide then the equivalant amount in grams will be 198 g (in 3 significant figures).

The molar mass of carbon dioxide (CO2) is qual to 44.01 g/mol.

In order to find the mass of 4.50 moles of CO2, we can use the following formula,

mass = number of moles × molar mass

Substituting the provided values, we will obtain,

mass = 4.50 mol × 44.01 g/mol

mass = 198.045 g

Therefore, after rounding to three significant figures, the mass of 4.50 moles of CO2 is obtaine to be 198 g.

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If any combustion reaction generates 4.50 moles of carbon dioxide then the equivalant amount in grams will be 198 g (in 3 significant figures).

The molar mass of carbon dioxide (CO2) is qual to 44.01 g/mol.

In order to find the mass of 4.50 moles of CO2, we can use the following formula,

mass = number of moles × molar mass

Substituting the provided values, we will obtain,

mass = 4.50 mol × 44.01 g/mol

mass = 198.045 g

Therefore, after rounding to three significant figures, the mass of 4.50 moles of CO2 is obtaine to be 198 g.

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benzene has bp of 80oc, toluene has bp of 110 oc and xylene has boiling point of 130 oc. the gc of a mixture of these three compounds should show retention times as

Answers

Answer: Benzene has a boiling point of 80oC, toluene has a boiling point of 110 oC, and xylene has a boiling point of 130 oC. The GC of a mixture of these three compounds should show retention times as benzene, toluene, xylene.

The GC of a mixture of these three compounds should show retention times as. The correct answer is Option C; benzene, toluene, xylene. The boiling points of the components indicate that they have different volatility.

Therefore, the order of volatility follows the order in which they have been mentioned in the question;

benzene < toluene < xylene

This means that as the boiling point increases, the retention time of each compound in the column also increases. Since the order of volatility is benzene < toluene < xylene, the retention times of the compounds will be as follows; benzene will have the least retention time, followed by toluene and then xylene, with the largest retention time.

Therefore, the GC of a mixture of these three compounds should show retention times as benzene, toluene, and xylene.




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11.2 dm3 of nh3 (as measured in normal conditions) were dissolved in 100 cm3 of water. what is the mass percent concentration of the obtained ammonia solution?

Answers

The mass percent concentration of the obtained ammonia solution is approximately 0.00833%.

To determine the mass percent concentration of an ammonia solution, we need to know the mass of ammonia present in the solution and the total mass of the solution.

In this case, we are given that 11.2 dm3 of NH3 gas, as measured in normal conditions (which is equivalent to 0.0112 m3), were dissolved in 100 cm3 of water. To calculate the mass of ammonia present in the solution, we first need to calculate the number of moles of NH3 using the ideal gas law, PV = nRT, where P is the pressure, V is the volume, n is the number of moles, R is the gas constant, and T is the temperature.

Assuming standard temperature and pressure (STP), we can use a pressure of 1 atm and a temperature of 273 K, giving us:

[tex]$n = \frac{PV}{RT}[/tex]

[tex]= \frac{(1 \text{ atm} * 0.0112 \text{ m}^3)}{(0.08206 \text{ L atm/mol K} * 273 \text{ K})} = 0.000489 \text{ mol}$[/tex]

The molar mass of NH3 is 17.03 g/mol, so the mass of NH3 present in the solution is:

mass NH3 = n * molar mass

= 0.000489 mol * 17.03 g/mol

= 0.00833 g

To calculate the mass percent concentration, we divide the mass of NH3 by the total mass of the solution (which is the mass of NH3 plus the mass of water):

mass percent concentration = [tex]\frac{mass,NH_3}{total,mass} \times 100%$[/tex]

The mass of water is equal to its volume times its density, which is approximately 1 g/cm3:

mass water = [tex]100\text{ cm}^3 * 1\text{ g/cm}^3 = 100\text{ g}$[/tex]

Therefore, the total mass of the solution is:

total mass = mass NH3 + mass water = 0.00833 g + 100 g = 100.00833 g

Substituting these values, we get:

mass percent concentration = [tex]\frac{0.00833 \text{ g}}{100.00833 \text{ g}} \times 100%[/tex]

= 0.00833%

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A 0.682-gram sample of an unknown weak monoprotic organic acid, HA, was dissolved in sufficient water to make 50.0 mL of solution and was titrated with a 0.135 M NaOH solution. After the addition of 10.6 mL of base, a pH of 5.65 was recorded. The equivalence point was reached after the addition of 27.4 mL of the 0.135 M NaOH.
a. Calculate the number of moles of acid in the original sample.
b. Calculate the molar mass of the organic acid.
c. Calculate the molarity of the unreacted HA remaining in the solution at pH = 5.65.

Answers

a. The number of moles of acid in the original sample is 0.00369. b. The molar mass of the organic acid is 0.135  M. c. The molarity of the unreacted HA remaining in the solution at pH 5.65 is 0.045 M

Calculation:

a. The equivalence point was reached after the addition of 27.4 mL of the 0.135 M NaOH.a.

Moles of NaOH = M × V = 0.135 M × 27.4 mL = 0.00369 moles

Using the balanced equation, we find that the number of moles of HA is equal to the number of moles of NaOH at the equivalence point. HA + NaOH → NaA + HOH0. 00369 moles of NaOH are needed to react with 0.00369 moles of HA.

b. Molar mass of HA = (mass of HA) / (number of moles of HA) = 0.682 g / 0.00369 moles = 184.7 g/molc. Calculate the molarity of the unreacted HA remaining in the solution at pH = 5.65.The pH of the solution was 5.65 after 10.6 mL of NaOH were added.

c. To calculate the molarity of the remaining HA, we first need to find the pKa of the acid.

pH = pKa + log([A-]/[HA])5.65 = pKa + log([A-]/[HA]). We know that at the equivalence point, [A-] = [HA] / 2.

Therefore,[A-] = 0.00369 moles / 2 = 0.00185 moles[Ligand] = (moles of ligand) / (liters of solution). We need to find [HA] in moles/L, so we need to find [A-] in moles/L. We can use the molarity of the NaOH solution to do this. [NaOH] = 0.135 M

moles of NaOH = [NaOH] × (liters of solution)moles of NaOH = 0.135 M × 0.0106 L.

moles of NaOH = 0.00144 moles

moles of HA at pH = 5.65 = moles of HA initially - moles of NaOH added = 0.00369 moles - 0.00144 moles

= 0.00225 moles[HA] = 0.00225 moles / 0.050 L = 0.045 M

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The major product of the synthesis, 3-methoxyheptane, is produced by an SN2 mechanism. Complete the reaction mechanism below by adding curved arrows showing electron flow and the final product, including the correct stereochemistry, to demonstrate the formation of the major product (3-methoxyheptane).

Answers

To demonstrate the formation of 3-methoxyheptane through an SN2 mechanism, follow these steps:

1. Identify the nucleophile and electrophile: The nucleophile is the methoxide ion (CH3O-) and the electrophile is the alkyl halide, such as 1-chloroheptane (C7H15Cl).

2. Show the electron flow using curved arrows: Draw a curved arrow from the lone pair on the oxygen atom of the methoxide ion to the carbon atom bonded to the chlorine in 1-chloroheptane. This arrow represents the nucleophilic attack.

3. Show the leaving group departure: Draw another curved arrow from the carbon-chlorine bond in 1-chloroheptane to the chlorine atom. This arrow represents the departure of the chloride ion (Cl-) as the leaving group.

4. Draw the final product with the correct stereochemistry: As SN2 reactions lead to inversion of stereochemistry, if the starting 1-chloroheptane had an R configuration, the final product, 3-methoxyheptane, would have an S configuration (and vice versa). So, draw the final product with the methoxy group (OCH3) attached to the third carbon atom of the heptane chain, and the correct stereochemistry based on the starting material.

The resulting structure will be 3-methoxyheptane, with the appropriate stereochemistry.

consider the compounds cl2, hcl, f2, naf, and hf. which compound has a boiling point closest to that of argon? explain.

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The compound that has a boiling point closest to that of Argon is HF. This is because HF has the strongest intermolecular forces (hydrogen bonding) among the given compounds.

The boiling point of a compound depends on the strength of the intermolecular forces that exist between the molecules. The stronger the intermolecular forces, the higher the boiling point.

The weaker the intermolecular forces, the lower the boiling point. The boiling point of Argon is -186°C. Out of the given compounds, the boiling point of HF is the closest to the boiling point of Argon.

The boiling point of HF is -83.8°C. This is because HF has hydrogen bonding which is the strongest intermolecular force among the given compounds. The other compounds such as Cl2, F2, HCl, and NaF, have weaker intermolecular forces than HF. Therefore, they have a lower boiling point than HF.



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A lab technician adds 0.20 mol of NaF to 1.00 L of 0.35 M cadmium nitrate, Cd(NO3)2. Which of the following statements is correct? Ksp=6.44 x 10^(-3) for CdF2. A) The presence of NaF will raise the solubility of Cd(NO3)2B) The solubility of cadmium fluoride is increased by the presence of additional fluoride ions.C) One must know Ksp for cadmium nitrate to make meaningful predictions on this system. D) Cadmium fluoride precipitates until the solution is saturated. E) The solution is unsaturated and no precipitate forms. stel et shnt nan ha added to 1.00 L of

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When a lab technician adds 0.20 mol of NaF to 1.00 L of 0.35 M cadmium nitrate, Cd(NO3)2, the correct statement is that B) The solubility of cadmium fluoride is increased by the presence of additional fluoride ions.

How does the addition of anions affect the solubility of salts?

The solubility of salts is influenced by the presence of anions.

The solubility of salts is increased by the presence of anions in some cases. Anions reduce the solubility of salts in other cases. Cadmium nitrate (Cd(NO3)2) has a Ksp of 6.44 × 10−3, which must be compared to the ion product (IP) for Cd(NO3)2 in solution to decide whether precipitation will occur. Cd(NO3)2 is a soluble salt that ionizes according to the following equation:

Cd(NO3)2 → Cd2+ + 2 NO3−.

According to the solubility product rule, the IP for Cd(NO3)2 is determined as IP = [Cd2+][NO3−]^2. Because cadmium fluoride (CdF2) is less soluble than cadmium nitrate, it must be compared to the IP for CdF2 in solution to decide whether precipitation will occur. The ion product (IP) for CdF2 in solution can be calculated using the stoichiometry of the equilibrium between Cd2+ and F− ions: Cd2+(aq) + 2F−(aq) → CdF2(s).

Thus, IP = [Cd2+][F−]^2. As a result, the addition of fluoride ions to the Cd(NO3)2 solution in the form of NaF increases the solubility of cadmium fluoride because the concentration of F− ions is increased. As a result, option B is correct.

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if a sample containing 6.5 moles of nh3 is reacted with excess cuo, how many moles of each product can be made? n2

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The amount of N2 (Nitrogen) produced will be limited by the amount of NH3 (Ammonia) present. Thus, the maximum amount of N2 that can be produced is 1.625 moles (which is half of the 3.25 moles calculated above). Therefore, the answer is 1.625 moles of N2.

If a sample containing 6.5 moles of NH3 is reacted with excess CuO, 1.625 moles of N2 can be produced. There are two products that can be produced by the reaction of NH3 with excess CuO: N2 and H2O. The balanced equation for this reaction is as follows: 4NH3 + 3CuO → 2N2 + 3H2O + 3CuTo determine how many moles of each product can be made, we need to use the mole ratio between NH3 and the products. From the balanced equation, we can see that for every 4 moles of NH3, 2 moles of N2 can be produced. Therefore, for 6.5 moles of NH3, we can calculate the amount of N2 produced as follows:6.5 moles NH3 × (2 moles N2/4 moles NH3) = 3.25 moles N2However, we have to remember that the reaction is carried out with excess CuO. This means that all of the NH3 will be consumed, and there will be enough CuO (Copper oxide) to react with all of it. Therefore, the amount of N2 produced will be limited by the amount of NH3 present. Thus, the maximum amount of N2 that can be produced is 1.625 moles (which is half of the 3.25 moles calculated above). Therefore, the answer is 1.625 moles of N2.

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Which of the following are considerations that should be taken when choosing solvents for recrystallization?The desired compound should be significantly more soluble in one solvent than the other.The solvents should be more basic than the desired compound.The two solvents should have significantly different polarity.There may be more than 1 correct answer or no correct answers.

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When choosing solvents for recrystallization, the considerations that should be taken into account are: The desired compound should be significantly more soluble in one solvent than the other; the two solvents should have significantly different polarity.

Recrystallization is a method for purifying substances. It is based on the solubility of the material in the solvent. The material is dissolved in a solvent, then the solvent is removed, leaving the purified solid.

The solubility of the material in the solvent is a critical element in recrystallization. Solubility must be high enough to enable the material to dissolve, but low enough to allow the material to crystallize out of solution.

The desired compound should be significantly more soluble in one solvent than the other. If one solvent has high solubility for the compound while the other solvent has low solubility, the compound will dissolve in the high solubility solvent and remain in solution when the mixture is cooled.

The compound will precipitate out of the mixture when it reaches its saturation point, leaving behind impurities in solution.

The two solvents should have significantly different polarity. The compound should have low solubility in the solvent with lower polarity but high solubility in the solvent with higher polarity.

The high polarity solvent is used to dissolve the compound, while the low polarity solvent is used to wash away impurities. The solvent should be less reactive than the compound, non-toxic, and reasonably priced.

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what is the percent by weight (w/w%) of sugar in soda? assume the average mass of sugar in soda is 31.0 g and the total mass is 370.0 g.

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The percent by weight (w/w%) of sugar in soda, assuming the average mass of sugar in soda is 31.0 g and the total mass is 370.0 g, is 8.38%.

The mass percent composition of a compound is a measure of the ratio of the mass of each component to the total mass of the compound. It is denoted by w/w%.

The mass percentage of a component in a solution can be calculated using the following formula:

the mass percent of a component = (mass of the component ÷ total mass of solution) × 100

Assume the average mass of sugar in soda is 31.0 g and the total mass is 370.0 g.

To determine the weight percentage of sugar in soda, the mass percent composition formula can be used as follows:

mass percent of sugar = (mass of sugar ÷ total mass of soda) × 100

mass percent of sugar = (31.0 g ÷ 370.0 g) × 100

mass percent of sugar = 0.0838 × 100

mass percent of sugar = 8.38%

Therefore, the percent by weight (w/w%) of sugar in soda, assuming the average mass of sugar in soda is 31.0 g and the total mass is 370.0 g, is 8.38%.

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calculate the volume in ml of a 6 m solution of hcl stock solution required to make 250 ml of 50 mm hcl?

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The volume in ml of a 6 m solution of hcl stock solution required to make 250 ml of 50 mm hcl is: 20.8 ml.

To calculate the volume of a 6 M HCl stock solution required to make 250 ml of 50 mM HCl, use the following equation:

volume of stock solution (ml) = (desired concentration (mM) x volume of desired solution (ml)) / stock solution concentration (M).

Therefore, in this case, volume of stock solution (ml) = (50 mM x 250 ml) / 6 M = 20.8 ml. In other words, 20.8 ml of a 6 M HCl stock solution is required to make 250 ml of 50 mM HCl. This is because the number of moles (the amount of HCl molecules) in the solution must remain constant.

Increasing the volume of the solution by dilution means that the concentration (the amount of HCl molecules per ml of solution) must be decreased, and thus the amount of HCl stock solution must be increased.

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What is one way that the layers of the atmosphere help to maintain life on Earth?

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One way that the layers of the atmosphere help to maintain life on Earth is by absorbing and scattering harmful solar radiation, such as ultraviolet (UV) radiation.

The ozone layer, which is located in the stratosphere layer of the atmosphere, absorbs most of the Sun's harmful UV radiation, preventing it from reaching the Earth's surface where it can cause DNA damage and skin cancer. Additionally, the atmosphere helps regulate the Earth's temperature by trapping heat from the Sun through the greenhouse effect, which is essential for maintaining a stable and habitable climate. The atmosphere also contains oxygen, which is necessary for the survival of many living organisms.

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Given the solubility rules from the book, which of the following metal hydroxides should be soluble in water? LiOH CuOH AgOH. Cu(OH)2 TlOH. LiOH.

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The metal hydroxide that should be soluble in water among LiOH, CuOH, AgOH, Cu(OH)₂, and TlOH is LiOH.

1. LiOH: Lithium hydroxide (LiOH) is an alkali metal hydroxide, and alkali metal hydroxides are generally soluble in water. So, LiOH is soluble.

2. CuOH: Copper(I) hydroxide (CuOH) is a transition metal hydroxide, which are typically insoluble. Therefore, CuOH is not soluble.

3. AgOH: Silver hydroxide (AgOH) is also a transition metal hydroxide and is insoluble in water.

4. Cu(OH)₂: Copper(II) hydroxide (Cu(OH)₂) is another transition metal hydroxide and is insoluble in water.

5. TlOH: Thallium hydroxide (TlOH) is also a transition metal hydroxide, and like most transition metal hydroxides, it is insoluble in water.

In conclusion, among the given metal hydroxides, LiOH is soluble in water.

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A face-centered cubic unit cell is the repeating unit in which type of crystal packing:__________

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A face-centered cubic unit cell is the repeating unit in which type of crystal packing: cubic closest-packed, option B.

Solids can be thought of as having a structure similar to that of a piece of wallpaper in three dimensions. Wallpaper has a recurring pattern that is consistent and runs from edge to edge. Similar repeating patterns may be found in crystals, however in this case, the patterns span three dimensions from one edge of the solid to the other.

By describing the dimensions, form, and content of the most basic repeating unit in the pattern, we may accurately describe a piece of wallpaper. The smallest repeating unit's dimensions, composition, and arrangement on top of one another to form the crystal may be used to characterise a three-dimensional crystal.

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Complete question:

A face-centered cubic unit cell is the repeating unit in which type of crystal packing A) hexagonal close-packing B)cubic close-packed C)body centered D)simple E)all of the above

When Pt metal is used as a catalyst for the previous reaction, we see that the mechanism changes and the reaction is much faster. The activation energy is found to be 98.4 kJ mol-1 with the catalyst at room temperature. How much would you have to raise the temperature to get the catalyzed reaction to run 100 times faster than it does at room temperature with the catalyst? Please answer in °C.

Answers

The temperature should be raised by 28.15°C to run 100 times faster than it does at room temperature with the catalyst.

How to find temperature of a catalytic reaction?

To determine the temperature increase needed to make the catalyzed reaction run 100 times faster, we can use the Arrhenius equation:

[tex]k_{2}[/tex]/[tex]k_{1}[/tex] = e^(-Ea/R * (1/[tex]T_{2}[/tex] - 1/[tex]T_{1}[/tex])

Where [tex]k_{1}[/tex] and [tex]k_{2}[/tex] are the rate constants at temperatures [tex]T_{1}[/tex] and [tex]T_{2}[/tex], Ea is the activation energy (98.4 kJ mol-1), and R is the gas constant (8.314 J [tex]K^{-1}[/tex] [tex]mol^{-1}[/tex]).

Since we want the reaction to be 100 times faster, k2/k1 = 100. Now we can rearrange the equation and solve for [tex]T_{2}[/tex]:

1/[tex]T_{2}[/tex] - 1/[tex]T_{1}[/tex] = -R * ln(100)/Ea

Assuming room temperature ([tex]T_{1}[/tex]) is 298 K (25°C), we can plug in the values:

1/[tex]T_{2}[/tex] - 1/298 = -8.314 * ln(100)/98,400

1/[tex]T_{2}[/tex] = 1/298 + (8.314 * ln(100)/98,400)

[tex]T_{2}[/tex] = 1 / (1/298 + (8.314 * ln(100)/98,400))

Now, calculate the value of [tex]T_{2}[/tex]:

[tex]T_{2}[/tex] ≈ 326.3 K

To convert [tex]T_{2}[/tex] to °C, subtract 273.15:

[tex]T_{2}[/tex] = 326.3 - 273.15 ≈ 53.15°C

Therefore, you would need to raise the temperature by approximately 28.15°C (53.15 - 25) to make the catalyzed reaction run 100 times faster.

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How many chlorine atoms are there in 4 molecules of HCl?

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Answer: Hydrogen chloride is a diatomic molecule, consisting of a hydrogen atom H and a chlorine atom Cl connected by a polar covalent bond.

partial older osteons can be found between complete newer osteons. these partial osteons are referred to as

Answers

Partial, older osteons are cylindrical structures that are found between newer, more complete osteons. These structures, also known as fragments,

consist of concentric layers of lamellae surrounding a central canal, or Haversian canal.

The lamellae and the Haversian canal are formed during the process of osteon remodeling, which involves the removal of old osteons and their replacement with new ones.

The fragments of old osteons that remain in the matrix between new osteons are referred to as “intermediate,” “intermediate osteons,” or “partial osteons.”

They can be distinguished from the newer, complete osteons by their decreased size and lack of a central Haversian canal.

Partial osteons are important for a number of reasons. They help maintain the structural integrity of the bone, provide additional strength and stability, and increase the bone’s resistance to compressive and tensile stresses.

Partial osteons also act as an area of interface between two different age groups of osteons, allowing them to resist shear forces.

Finally, the presence of partial osteons in the bone matrix may increase the rate of healing after fracture or trauma.

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